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Related papers: A DFT+U study of Rh, Nb codoped rutile TiO2

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The structural, electronic, and optical properties of metal (Si, Ge, Sn, and Pb) mono- and co-doped anatase TiO$_{2}$ nanotubes are investigated, in order to elucidate their potential for photocatalytic applications. It is found that Si…

Mesoscale and Nanoscale Physics · Physics 2020-04-29 Mohamed M. Fadlallah , Ulrich Eckern

By means of first-principles density-functional theory (DFT) calculations, we perform a comparative analysis of the electronic and magnetic properties of transition metal-doped TiO$_2$. The electronic band gaps of Ti$_x$M$_{1-x}$O$_2$,…

Materials Science · Physics 2026-01-26 Vikash Mishra , Shashi Pandey , Swaroop Ganguly , Alok Shukla

Electronic structures and optical properties of C-N-codoped anatase TiO2 were calculated by using GGA+U method based on the density functional theory. The calculated results showed that the N-doped, C-doped, and C-N-codoped TiO2 produced 2p…

Materials Science · Physics 2015-08-10 Meili Guo , Jiulin Du

Doping is one of the most common strategies for improving the photocatalytic and solar energy conversion properties of TiO$_2$, hence an accurate theoretical description of the electronic and optical properties of doped TiO$_2$ is of both…

We studied the electronic and atomic structures of anatase TiO2 codoped with Cr and N using hybrid density functional theory calculations. Nonlocal screened Hartree-Fock exchange energy is partially mixed with traditional semilocal exchange…

Materials Science · Physics 2014-04-01 Veysel Celik , Ersen Mete

In this paper, I demonstrate a density functional theory plus dynamical mean field theory study on the electronic properties of doped $TiO_2$ rutile as well as another tetragonal phase anatase with oxygen vacancy. The density of states and…

Strongly Correlated Electrons · Physics 2021-12-24 S. Koley

We perform first-principles calculations to investigate the band structure, density of states, optical absorption, and the imaginary part of dielectric function of Cu, Ag, and Au-doped anatase TiO2 in 72 atoms systems. The electronic…

Materials Science · Physics 2015-08-10 Meili Guo , Jiulin Du

Electronic properties and atomic structures of W, N, S, W/N, and W/S dopings of anatase TiO_2 have been systematically investigated using the density functional theory (DFT). The exchange and correlation effects have been treated with Heyd,…

Strongly Correlated Electrons · Physics 2012-11-19 Veysel Çelik , Ersen Mete

It has been demonstrated in previous experimental and computational work that doping CeO2 with transition metals is an effective way of tuning its properties. However, each previous study on CeO2 doping has been limited to a single or a few…

Materials Science · Physics 2020-12-14 Zhao Liua , Hongyang Ma , Charles C. Sorrell , Pramod Koshy , Judy N. Hart

TiO$_2$ and SrTiO$_3$ are well known materials in the field of photocatalysis due to their exceptional electronic structure, high chemical stability, non-toxicity and low cost. However, owing to the wide band gap, these can be utilized only…

Materials Science · Physics 2020-09-25 Manish Kumar , Pooja Basera , Shikha Saini , Saswata Bhattacharya

In this work, electronic structure of several doped TiO$_2$ anatase systems is computed using DFT+$U$. Effective masses of charge carriers are also computed to quantify how the dopant atoms perturb the bands of the host anatase material.…

Materials Science · Physics 2022-08-19 Abhishek Raghav , Kenta Hongo , Ryo Maezono , Emila Panda

Tuning the valence state and electronic structure of catalytically active sites is crucial for improving Fenton and Fenton-like reactions, which rely on the efficient activation of the H2O2 molecule. Pure TiO2, however, has inadequate…

Substitutional doping with transition metals is carried out in the Lepidocrocite phase - the stable monolayer geometry of TiO$_2$, using density functional theory (DFT) methods. The doping is carried out at the differently coordinated O…

Materials Science · Physics 2024-10-14 Kati Asikainen , Matti Alatalo , Marko Huttula , S. Assa Aravindh

Rare earth doping is an effective way to convert chemically stable oxides into multifunctional materials with coupled electronic, optical, and magnetic properties. We present first principles calculations of pristine and Tm3+ doped Ca2SnO4…

Materials Science · Physics 2025-10-21 Shah Hussain , Sikander Azam , Umme Habiba , Qaiser Rafiq , Amin Ur Rahman , Hamada H. Amer , Yasir Saeed

We synthesized the pure and co-doped titanium dioxide (TiO$_2$) electrodes via spin coating. We examined the optical and electronic properties of as-prepared thin film electrodes with co-doping of transition metals and non-metals. The…

Applied Physics · Physics 2022-06-13 Manish K Vishwakarma , Monojit Bag , Puneet Jain

Titanium dioxide is one of the most widely investigated oxides. This is due to its broad range of applications, from catalysis to photocatalysis to photovoltaics. Despite this large interest, many of its bulk properties have been sparsely…

Materials Science · Physics 2010-03-12 L. Chiodo , J. M. García-Lastra , D. J. Mowbray , A. Iacomino , A. Rubio

The rutile TiO$_2$ (110) surface reduced by the bridging oxygen vacancy, bridging hydroxyl group or Ti interstitial atom has been investigated by calculating their electronic structures using the density functional theory plus U method. It…

Materials Science · Physics 2015-10-13 Daoyu Zhang , Minnan Yang , Shuai Dong

Density functional theory (DFT) and DFT corrected for on-site Coulomb interactions (DFT+U) calculations are presented on Aluminium doping in bulk TiO$_2$ and the anatase (101) surface. Particular attention is paid to the mobility of oxygen…

Materials Science · Physics 2014-03-24 Conn O'Rourke , David R. Bowler

This study investigates the novelty of the crystalline and electronic structure of (Mg,Ti)-doped ZnO and the co-doped Zn1-x-yMgxTiyO structures using Gaussian and plane-wave basis sets, as implemented in the CP2K code. The goal of…

Materials Science · Physics 2025-03-05 Sidi Ahmedbowba , Fehmi Khadri , Walid Ouerghui , Said Ridene

Doping Bi2Sr2Ca1Cu2O8+y with Co causes a superconductor-insulator transition. We study correlations between changes in the electrical resistivity RHOab(T) and the electronic bandstructure using identical single crystalline samples. For…

Condensed Matter · Physics 2009-10-22 C. Quitmann , P. Almeras , Jian Ma , R. J. Kelley , H. Berger , G. Margaritondo , M. Onellion
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