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Ultrashort light pulses can selectively excite charges, spins and phonons in materials, providing a powerful approach for manipulating their properties. Here we use femtosecond laser pulses to coherently manipulate the electron and phonon…

A theoretical analysis is carried out for the recently developed three-pulse photon echo spectroscopy employing dual frequency combs (DFC) as the light sources. In this method, the molecular sample interacts with three pulse trains derived…

Chemical Physics · Physics 2020-01-08 Jonggu Jeon , JunWoo Kim , Tai Hyun Yoon , Minhaeng Cho

During the first steps of photosynthesis, the energy of impinging solar photons is transformed into electronic excitation energy of the light-harvesting biomolecular complexes. The subsequent energy transfer to the reaction center is…

Recent theoretical studies in quantum spectroscopy have emphasized the potential of non-classical correlations in entangled photon pairs for selectively targeting specific nonlinear optical processes in nonlinear optical responses. However,…

Chemical Physics · Physics 2026-04-21 Yuta Fujihashi , Ozora Iso , Ryosuke Shimizu , Akihito Ishizaki

We investigate experimentally and theoretically the coherent and incoherent processes in open 3-level ladder systems in room temperature gases and identify in which regime electromagnetically induced transparency (EIT) occurs. The…

Atomic Physics · Physics 2013-12-02 A. Urvoy , C. Carr , R. Ritter , C. S. Adams , K. J. Weatherill , R. Löw

In this paper, we present a theoretical description to the quantum coherence and decoherence phenomena of energy transfer in photosynthesis observed in a recent experiment [see Science 316, 1462 (2007)]. As a successive two-color laser…

Quantum Physics · Physics 2010-01-28 Xian-Ting Liang , Wei-Min Zhang , Yi-Zhong Zhuo

We investigate how correlated fluctuations affect oscillatory features in rephasing and non-rephasing two-dimensional (2D) electronic spectra of a model dimer system. Based on a beating map analysis, we show that non-secular environmental…

Femtosecond coherent multidimensional spectroscopy is demonstrated for an ultracold gas. For this, a setup for phase modulation spectroscopy is used to probe the $3^2\mathrm{S}_{1/2} - 2^2\mathrm{P}_{1/2, 3/2}$ transition in an 800…

Atomic Physics · Physics 2023-01-16 Friedemann Landmesser , Tobias Sixt , Katrin Dulitz , Lukas Bruder , Frank Stienkemeier

Methods for reconstructing the spectral density of a vibrational environment from experimental data can yield key insights into the impact of the environment on molecular function. Although such experimental methods exist, they generally…

Chemical Physics · Physics 2025-09-11 Roosmarijn de Wit , Jonathan Keeling , Brendon W. Lovett , Alex W. Chin

We study theoretically inelastic spectrum of coherent backscattering of laser light by two atoms. For an intense laser field, there are frequency domains of not only constructive but also destructive (self-)interference of the inelastic…

Quantum Physics · Physics 2009-11-13 Vyacheslav Shatokhin

Functional nanomaterials, including 2D materials and their heterostructures are expected to impact fields ranging from catalysis, optoelectronics to nanophotonics. To realize their potential, novel experimental approaches need to be…

Mesoscale and Nanoscale Physics · Physics 2025-10-13 Cana Elgvin , Fredrik S. Hage , Khairi F. Elyas , Katja Höflich , Øystein Prytz , Christoph T. Koch , Hannah C. Nerl

Two-dimensional electronic spectroscopy (2DES) has enabled significant discoveries in both biological and synthetic energy-transducing systems. Although deriving chemical information from 2DES is a complex task, machine learning (ML) offers…

Chemical Physics · Physics 2025-03-21 Jonathan D. Schultz , Kelsey A. Parker , Bashir Sbaiti , David N. Beratan

We explain current controversies regarding the interpretation of the cross peaks in the fluorescence detected coherent 2D spectroscopy.

Chemical Physics · Physics 2019-12-20 Oliver Kühn , Tomas Mancal , Tõnu Pullerits

We analyze the light scattered by a single InAs quantum dot interacting with a resonant continuous-wave laser. High resolution spectra reveal clear distinctions between coherent and incoherent scattering, with the laser intensity spanning…

Mesoscale and Nanoscale Physics · Physics 2015-06-05 K. Konthasinghe , J. Walker , M. Peiris , C. K. Shih , Y. Yu , M. F. Li , J. F. He , L. J. Wang , H. Q. Ni , Z. C. Niu , A. Muller

Energy transfer between chromophores in photosynthesis proceeds with near unity quantum efficiency. Understanding the precise mechanisms of these processes is made difficult by the complexity of the electronic structure and interactions…

Chemical Physics · Physics 2015-03-03 Gethin H. Richards , Krystyna E. Wilk , Paul M. G. Curmi , Jeffrey A. Davis

Quasi-elastic scattering processes have long been thought of providing the most promising signal for a first experimental detection of quantum vacuum nonlinearity. A prominent example of such a process is vacuum birefringence. However,…

Optics · Physics 2023-10-09 Chantal Sundqvist , Felix Karbstein

In the last decades, the blossoming of experimental breakthroughs in the domain of electron energy loss spectroscopy (EELS) has triggered a variety of theoretical developments. Those have to deal with completely different situations, from…

Mesoscale and Nanoscale Physics · Physics 2021-02-10 Hugo Lourenço-Martins , Axel Lubk , Mathieu Kociak

Recent observations of coherence in photosynthetic complexes have led to the question of whether quantum effects can occur in vivo, not under femtosecond laser pulses but in incoherent sunlight and at steady state, and, if so, whether the…

Biological Physics · Physics 2013-01-15 Ivan Kassal , Joel Yuen-Zhou , Saleh Rahimi-Keshari

Electronic coherence is of utmost importance for the access and control of quantum-mechanical solid-state properties. Using a purely electronic observable, the photocurrent, we measure an electronic coherence time of 22 +/- 4 fs in…

Mesoscale and Nanoscale Physics · Physics 2021-12-08 Christian Heide , Timo Eckstein , Tobias Boolakee , Constanze Gerner , Heiko B. Weber , Ignacio Franco , Peter Hommelhoff

The photosystem II reaction center (PSII-RC) performs the primary energy conversion steps of oxygenic photosynthesis. While the PSII-RC has been studied extensively, the similar timescales of energy transfer and charge separation, and the…