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Patchy particles are a class of colloids with functionalized surfaces. Through surface functionalization, the strength and directionality of the colloidal interactions are tunable allowing control over coordination of the particle.…

Soft Condensed Matter · Physics 2013-10-21 Cristóvão Dias , Nuno Araújo , Margarida Telo da Gama

Colloidal particles are considered ideal building blocks to produce materials with enhanced physical properties. The state-of-the-art techniques for synthesizing these particles provide control over shape, size, and directionality of the…

Soft Condensed Matter · Physics 2016-12-21 N. A. M. Araújo , C. S. Dias , M. M. Telo da Gama

Colloids that attractively bond to only a few neighbors (e.g., patchy particles) can form equilibrium gels with distinctive dynamic properties that are stable in time. Here, we use a coarse-grained model to explore the dynamics of linked…

Soft Condensed Matter · Physics 2022-11-09 Taejin Kwon , Tanner A. Wilcoxson , Delia J. Milliron , Thomas M. Truskett

We study the irreversible adsorption of spherical $2AnB$ patchy colloids (with two $A$-patches on the poles and $n$ $B$-patches along the equator) on a substrate. In particular, we consider dissimilar $AA$, $AB$, and $BB$ binding…

Soft Condensed Matter · Physics 2013-10-21 C. S. Dias , N. A. M. Araújo , M. M. Telo da Gama

The rapid progress in precisely designing the surface decoration of patchy colloidal particles offers a new, yet unexperienced freedom to create building entities for larger, more complex structures in soft matter systems. However, it is…

Soft Condensed Matter · Physics 2012-06-14 G. Doppelbauer , E. G. Noya , E. Bianchi , G. Kahl

We investigate numerically the role of spatial arrangement of the patches on the irreversible adsorption of patchy colloids on a substrate. We consider spherical three-patch colloids and study the dependence of the kinetics on the opening…

Soft Condensed Matter · Physics 2014-10-01 C. S. Dias , N. A. M. Araújo , M. M. Telo da Gama

Patchy colloidal model with three and four equivalent patches, confined in the attractive random porous media, undergo re-entrant gas-liquid phase separation with the possibility for the liquid phase density to approach zero. This unusual…

Soft Condensed Matter · Physics 2022-05-11 Taras Hvozd , Yurij V. Kalyuzhnyi , Vojko Vlachy , Peter T. Cummings

Patchy particles are considered to be a good model for protein aggregation. We calculate the equilibrium phase diagram of two-patch colloidal particles undergoing aggregation along with isotropic potential. This investigation demonstrates…

Soft Condensed Matter · Physics 2020-06-24 Isha Malhotra , Sujin B. Babu

In this paper, we develop a thermodynamic perturbation theory to describe the self-assembly of patchy colloids which exhibit both patch-patch attractions as well as patch / non-patch attractions. That is, patches attract other patches as…

Soft Condensed Matter · Physics 2017-09-14 Bennett D. Marshall

We investigate numerically the irreversible aggregation of patchy spherical colloids on a flat substrate. We consider $n$-patch particles and characterize the dependence of the irreversible aggregation kinetics on $n$. For all values of…

Soft Condensed Matter · Physics 2014-09-30 C. S. Dias , N. A. M. Araújo , M. M. Telo da Gama

A new theory is developed to describe the equilibrium adsorption and self-assembly of patchy colloids in microchannels. The adsorption theory is developed in classical density functional theory, with the adsorbed phase and fluid phase…

Soft Condensed Matter · Physics 2016-08-24 Bennett D. Marshall

Inverse patchy colloids are nano- to micro-scale particles with a surface divided into differently charged regions. This class of colloids combines directional, selective bonding with a relatively simple particle design: owing to the…

Soft Condensed Matter · Physics 2021-01-22 Emanuela Bianchi , Peter D. J. van Oostrum , Christos N. Likos , Gerhard Kahl

We study the ordered equilibrium structures of patchy particles where the patches are located on the surface of the colloid such that they form a regular tetrahedron. Using optimization techniques based on ideas of evolutionary algorithms…

Soft Condensed Matter · Physics 2015-06-05 G. Doppelbauer , E. G. Noya , E. Bianchi , G. Kahl

Open structures can display a number of unusual properties, including a negative Poisson's ratio, negative thermal expansion, and holographic elasticity, and have many interesting applications in engineering. However, it is a grand…

Soft Condensed Matter · Physics 2015-10-14 D. Zeb Rocklin , Xiaoming Mao

Patchy colloidal platelets with convex, non-spherical shapes have been realized with different materials at length scales ranging from nanometers to microns. While the assembly of these hard shapes tends to maximize edge-to-edge contacts,…

Soft Condensed Matter · Physics 2020-04-22 Carina Karner , Christoph Dellago , Emanuela Bianchi

Attractive colloidal gels exhibit solid-like behavior at vanishingly small fractions of solids, owing to ramified space-spanning networks that form due to particle-particle interactions. These networks give the gel its rigidity, and as the…

We study the irreversible adsorption of patchy particles on substrates in the limit of advective mass transport. Recent numerical results show that the interface roughening depends strongly on the particle attributes, such as, patch-patch…

Statistical Mechanics · Physics 2015-05-20 N. A. M. Araújo , C. S. Dias , M. M. Telo da Gama

We report on the self-assembly of inverse patchy colloids (IPC) using Monte Carlo simulations in two-dimensions. The IPC model considered in this work corresponds to either bipolar colloids or colloids decorated with complementary DNA on…

Soft Condensed Matter · Physics 2017-05-16 Remya Ann Mathews K , Ethayaraja Mani

Patchy particles have proven to be a prominent model for studying the self-assembly behavior of various systems, ranging from finite clusters to bulk crystal assemblies, and from synthetic colloidal particles to viruses. The patchy particle…

Soft Condensed Matter · Physics 2025-10-13 Gregory Snyder , Chrisy Xiyu Du

Patchy colloids are promising candidates for building blocks in directed self-assembly. To be successful the surface patterns need to both be simple enough to be synthesized, while feature-rich enough to cause the colloids to self-assemble…

Soft Condensed Matter · Physics 2014-05-13 Erik Edlund , Oskar Lindgren , Martin Nilsson Jacobi
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