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Vibrational and electronic absorption spectra calculated at the (time-dependent) density functional theory level for the bismuth carbide clusters Bi$_{n}$C$_{2n}$$^+$ ($3 \le n \le 9$) indicate significant differences in types of bonding…

Materials Science · Physics 2021-02-24 Diogo A. F. Almeida , Micael J. T. Oliveira , Bruce F. Milne

We have calculated the absorption characteristics of different hybrid systems consisting of Ag, Ag2 or Ag3 atomic clusters and poly(methacrylic acid) (PMAA) using the time-dependent density-functional theory. The polymer is found to have an…

Materials Science · Physics 2015-05-18 Laura Koponen , Lasse O. Tunturivuori , Martti J. Puska , Y. Hancock

Photoabsorption cross sections of small sodium cluster cations (Na$_n^+$, n=3,5,7 and 9) were calculated at various temperatures with the time-dependent local-density-approximation (TDLDA) in conjunction with ab initio molecular dynamics…

Atomic and Molecular Clusters · Physics 2016-09-08 M. Moseler , H. Hakkinen , Uzi Landman

The choice of Gaussian basis functions for computing the ground-state properties of molecules, and clusters, employing wave-function-based electron-correlated approaches, is a well-studied subject. However, the same cannot be said when it…

Chemical Physics · Physics 2023-01-09 Vikram Mahamiya , Pritam Bhattacharyya , Alok Shukla

B and N K-edge x-ray absorption spectroscopy measurements have been performed on three BN thin films grown on Si substrates using ion-assisted pulsed laser deposition. Comparison of the films' spectra to those of several single-phase BN…

Condensed Matter · Physics 2007-05-23 A. Chaiken , L. J. Terminello , J. Wong , G. L. Doll , T. Sato

We present ab initio absorption spectra of six three-dimensional semiconductors and insulators calculated using Gaussian-based periodic equation-of-motion coupled-cluster theory with single and double excitations (EOM-CCSD). The spectra are…

Chemical Physics · Physics 2021-07-13 Xiao Wang , Timothy C. Berkelbach

We present a theoretical study of three-photon electromagnetically induced absorption for a ladder-type three-level atomic system. A probe beam was tuned to the lower line and two counter-propagating, linearly polarized coupling beams were…

Atomic Physics · Physics 2015-08-03 Heung-Ryoul Noh , Han Seb Moon

Absorption spectra of closed-shell Na_2, Na_3+, Na_4, Na_5+, Na_6, Na_7+, and Na_8 clusters are calculated using a recently implemented conserving linear response method. In the framework of a quasiparticle approach, we determine…

Materials Science · Physics 2015-05-14 George Pal , Georgios Lefkidis , Hans Christian Schneider , Wolfgang Huebner

We present systematic and comprehensive correlated-electron calculations of the linear photoabsorption spectra of small neutral closed- and open-shell sodium clusters (Na_{n}, n=2-6), as well as closed-shell cation clusters (Na_{n}^{+},…

Atomic and Molecular Clusters · Physics 2017-05-25 Pradip Kumar Priya , Deepak Kumar Rai , Alok Shukla

We present a method for computing optical absorption spectra by means of a Bethe-Salpeter equation approach, which is based on a conserving linear response calculation for electron-hole coherences in the presence of an external…

Materials Science · Physics 2010-12-21 George Pal , Yaroslav Pavlyukh , Wolfgang Hübner , Hans Christian Schneider

We use linear response theory in order to compute the light absorption spectrum, in the terahertz band, of a polariton system composed by excitons in a quantum dot very strongly coupled to the lowest photon mode of a thin micropillar. In a…

Mesoscale and Nanoscale Physics · Physics 2013-10-08 Carlos Andres Vera-Ciro , Alain Delgado , Augusto Gonzalez

In this paper, we report large-scale configuration interaction (CI) calculations of linear optical absorption spectra of various isomers of magnesium clusters Mg$_{n}$ (n=2--5), corresponding to valence transitions. Geometry optimization of…

Atomic and Molecular Clusters · Physics 2017-11-28 Ravindra Shinde , Alok Shukla

Protonated water clusters are a common species of atmospheric molecular cluster-ion, produced by cosmic rays throughout the troposphere and stratosphere. Under clear-sky conditions or periods of increased atmospheric ionisation, such as…

Atmospheric and Oceanic Physics · Physics 2007-05-23 K. L. Aplin , R. A. McPheat

It is known that rare-gas or metal clusters absorb incident laser energy very efficiently. However, due to the intricate dependencies on all the laser and cluster parameters it is difficult to predict under which circumstances ionization…

Plasma Physics · Physics 2009-11-13 M. Kundu , D. Bauer

An analysis of the eigenstates of a symmetry-broken spin-boson Hamiltonian is performed by computing Bloch and Husimi projections. The eigenstate analysis is combined with the calculation of absorption bands of asymmetric dimer…

Quantum Physics · Physics 2012-04-20 Christiane Koch , Bernd Esser

We present a systematic study of the photo-absorption spectra of various Si$_{n}$H$_{m}$ clusters (n=1-10, m=1-14) using the time-dependent density functional theory (TDDFT). The method uses a real-time, real-space implementation of TDDFT…

Mesoscale and Nanoscale Physics · Physics 2012-02-29 Juzar Thingna , R. Prasad , S. Auluck

Using density-functional theory (DFT), we investigate the selectivity of adsorption of CO2 over N2 and CH4 on planar-type B clusters, based on our previous finding of strong chemisorption of CO2 on the B10-13 planar and quasiplanar…

Materials Science · Physics 2022-12-14 Alexandra B. Santos-Putungan , Natasa Stojic , Nadia Binggeli , Francis N. C. Paraan

Data in the 2090 A B region of HD 76932 have been obtained at high S/N using the HST GHRS echelle at a resolution of 90,000. This wavelength region has been previously identified as a likely candidate for observing the B11/B10 isotopic…

Astrophysics · Physics 2009-10-30 L. M. Rebull , D. K. Duncan , S. Johansson , J. Thorburn , B. Fields

With close pairs of quasars at different redshifts, a background quasar sightline can be used to study a foreground quasar's environment in absorption. We used a sample of 17 Lyman limit systems with column density N_HI > 10^19 cm^-2…

Astrophysics · Physics 2008-11-26 Joseph F. Hennawi , Jason X. Prochaska

An optical absorption spectrum constitutes one of the most fundamental material characteristics, with relevant applications ranging from material identification to energy harvesting and optoelectronics. However, the database of both…

Materials Science · Physics 2022-09-20 Ruo Xi Yang , Matthew K. Horton , Jason Munro , Kristin A. Persson