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We consider the increase of the spatial variance of some inhomogeneous, non-equilibrium density (particles, energy, etc.) in a periodic quantum system of condensed matter-type. This is done for a certain class of initial quantum states…

Statistical Mechanics · Physics 2009-10-23 Robin Steinigeweg , Hannu Wichterich , Jochen Gemmer

We introduce a novel energy functional for ground-state electronic-structure calculations. Its fundamental variables are the natural spin-orbitals of the implied singlet many-body wave function and their joint occupation probabilities. The…

Chemical Physics · Physics 2015-06-23 Ralph Gebauer , Morrel H. Cohen , Roberto Car

Current-density-functional theory is used to perturbatively calculate single-particle energies of open-shell atoms prepared in a current-carrying state. We focus on the highest occupied such energy, because its negative is, in principle,…

Chemical Physics · Physics 2015-06-26 E. Orestes , A. B. F. da Silva , K. Capelle

We derive from first principles (without resorting to the replica trick) a density functional theory for fluids in quenched disordered matrices (QA-DFT). We show that the disorder-averaged free energy of the fluid is a functional of the…

Soft Condensed Matter · Physics 2007-07-18 Luis Lafuente , Jose A. Cuesta

The Hohenberg-Kohn (HK) theorems of bijectivity between the external scalar potential and the gauge invariant nondegenerate ground state density, and the consequent Euler variational principle for the density, are proved for arbitrary…

Strongly Correlated Electrons · Physics 2015-08-26 Xiao-Yin Pan , Viraht Sahni

An approach to generalize any kind of collinear functionals in density functional theory to non-collinear functionals is proposed. This approach, for the very first time, satisfies the correct collinear limit for any kind of functionals,…

Quantum Physics · Physics 2023-01-26 Zhichen Pu , Hao Li , Qiming Sun , Ning Zhang , Yong Zhang , Sihong Shao , Hong Jiang , Yiqin Gao , Yunlong Xiao

We show how kinetic theory, the statistics of classical particles obeying Newtonian dynamics, can be formulated as a field theory. The field theory can be organized to produce a self-consistent perturbation theory expansion in an effective…

Statistical Mechanics · Physics 2015-06-03 Shankar P. Das , Gene F. Mazenko

The optimized effective potential method is formulated as a convex minimization problem. This formulation does not require assumptions about $v$-representability nor functional differentiability. The formulation provides a natural framework…

Chemical Physics · Physics 2022-02-01 Erik I. Tellgren , Andre Laestadius , Markus Penz

Functional data that are nonnegative and have a constrained integral can be considered as samples of one-dimensional density functions. Such data are ubiquitous. Due to the inherent constraints, densities do not live in a vector space and,…

Statistics Theory · Mathematics 2016-01-13 Alexander Petersen , Hans-Georg Müller

Using the collective variables (CV) method the basic relations of statistical field theory of a multicomponent non-homogeneous fluids are reconsidered. The corresponding CV action depends on two sets of scalar fields - fields…

Soft Condensed Matter · Physics 2012-07-02 Oksana Patsahan , Ihor Mryglod , Jean-Michel Caillol

We extend ground-state density-functional theory to excited states and provide the theoretical formulation for the widely used $\Delta SCF$ method for calculating excited-state energies and densities. As the electron density alone is…

Chemical Physics · Physics 2024-03-08 Weitao Yang , Paul W. Ayers

Density-functional theory for superfluid systems is developed in the framework of the functional renormalization group based on the effective action formalism. We introduce the effective action for the particle-number and nonlocal pairing…

Nuclear Theory · Physics 2021-05-11 Takeru Yokota , Haruki Kasuya , Kenichi Yoshida , Teiji Kunihiro

In a recent PRL, Gonze et al claim that the density functional theory in Hohenberg-Kohn formulation is not valid for crystalline solids in a homogenious electric field. They introduce another theory, density-and-polarization functional…

Condensed Matter · Physics 2007-05-23 I. I. Mazin , R. E. Cohen

The Hohenberg-Kohn theorem and the Kohn-Sham equations, which are at the basis of the Density Functional Theory, are reformulated in terms of a particular many-body density, which is translational invariant and therefore is relevant for…

Nuclear Theory · Physics 2021-09-29 A. Kievsky , G. Orlandini , M. Gattobigio

Density functional theory together with the Kohn-Sham scheme represent an efficient framework to recover the ground state density and energy of a many-body quantum system from an auxiliary ``non-interacting'' system (one-body with a local…

Quantum Physics · Physics 2021-05-18 Jérémie Messud

The idea that the vacuum energy density $\rho_{\Lambda}$ could be time dependent is a most reasonable one in the expanding Universe; in fact, much more reasonable than just a rigid cosmological constant for the entire cosmic history. Being…

General Relativity and Quantum Cosmology · Physics 2015-07-08 Harald Fritzsch , Joan Sola

We discuss the foundations and extend the range of applicability of the widely used Kubo-Greenwood formula (KGF) for the electronic conductivity. The conductivity is derived from the current density, and only the probability amplitude…

Statistical Mechanics · Physics 2009-04-02 Ming-Liang Zhang , D. A. Drabold

The present study aims at further development of covariant energy density functionals (CEDFs) towards more accurate description of binding energies across the nuclear chart. For the first time, infinite basis corrections to binding energies…

Nuclear Theory · Physics 2025-07-29 B. Osei , A. V. Afanasjev , A. Taninah , A. Dalbah , U. C. Perera , V. A. Dzuba , V. V. Flambaum

This short communication develops a convex dual variational formulation for a large class of models in variational optimization. The results are established through basic tools of functional analysis, convex analysis and duality theory. The…

Optimization and Control · Mathematics 2022-04-01 Fabio Silva Botelho

In this paper we investigate the (Kohn-Sham) density-to-potential map in the case of spinless fermions in one spatial dimension, whose existence has been rigorously established by the first author in [arXiv:2504.05501 (2025)]. Here, we…

Mathematical Physics · Physics 2025-12-05 Thiago Carvalho Corso , Andre Laestadius
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