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The Hohenberg-Kohn theorem of the density functional theory is extended by modifying the Levy constrained-search formulation. The new theorem allows us to choose arbitrary physical quantities as the basic variables which determine the…

Condensed Matter · Physics 2009-11-10 M. Higuchi , K. Higuchi

Density-functional theory requires an extra variable besides the electron density in order to properly incorporate magnetic-field effects. In a time-dependent setting, the gauge-invariant, total current density takes that role. A peculiar…

Chemical Physics · Physics 2024-10-22 Andre Laestadius , Markus Penz , Erik I. Tellgren

A density-functional theory is developed based on the Maxwell--Schr\"odinger equation with an internal magnetic field in addition to the external electromagnetic potentials. The basic variables of this theory are the electron density and…

Chemical Physics · Physics 2018-01-17 Erik Tellgren

Lieb's convex formulation of density-functional theory is presented in a pedagogical manner, emphasizing its connection to Hohenberg-Kohn theory and to Levy's constrained-search theory. The Hohenberg-Kohn and Lieb variation principles are…

Chemical Physics · Physics 2022-04-27 Trygve Helgaker , Andrew M. Teale

Current-carrying and superconducting systems can be treated within density-functional theory if suitable additional density variables (the current density and the superconducting order parameter, respectively) are included in the…

Materials Science · Physics 2009-11-07 K. Capelle , G. Vignale

Our recent theory (Ref. 1) enables us to choose arbitrary quantities as the basic variables of the density functional theory. In this paper we apply it to several cases. In the case where the occupation matrix of localized orbitals is…

Materials Science · Physics 2009-11-10 K. Higuchi , M. Higuchi

We review the progress that has been recently made in the application of time-dependent density functional theory to thermoelectric phenomena. As the field is very young, we emphasize open problems and fundamental issues. We begin by…

Mesoscale and Nanoscale Physics · Physics 2017-04-26 F. G. Eich , M. Di Ventra , G. Vignale

The principles of density-functional theory are studied for finite lattice systems represented by graphs. Surprisingly, the fundamental Hohenberg-Kohn theorem is found void in general, while many insights into the topological structure of…

Quantum Physics · Physics 2022-01-13 Markus Penz , Robert van Leeuwen

The relationship between the densities of ground-state wave functions (i.e., the minimizers of the Rayleigh--Ritz (RR) variation principle) and the ground-state densities in density-functional theory (i.e., the minimizers of the…

Chemical Physics · Physics 2015-06-26 Simen Kvaal , Trygve Helgaker

An overview of several recent developments in density functional theory for classical inhomogeneous liquids is given. We show how Levy's constrained search method can be used to derive the variational principle that underlies density…

Soft Condensed Matter · Physics 2013-01-01 M. Schmidt , M. Burgis , W. S. B. Dwandaru , G. Leithall , P. Hopkins

For a many-electron system, whether the particle density $\rho(\mathbf{r})$ and the total current density $\mathbf{j}(\mathbf{r})$ are sufficient to determine the one-body potential $V(\mathbf{r})$ and vector potential…

Quantum Physics · Physics 2015-04-01 Andre Laestadius , Michael Benedicks

Given a vector space of microscopic quantum observables, density functional theory is formulated on its dual space. A generalized Hohenberg-Kohn theorem and the existence of the universal energy functional in the dual space are proven. In…

Nuclear Theory · Physics 2009-09-25 G. Rosensteel , Ts. Dankova

Forty-five years after the point de d\'epart [1] of density functional theory, its applications in chemistry and the study of electronic structures keep steadily growing. However, the precise form of the energy functional in terms of the…

Chemical Physics · Physics 2019-10-29 Philippe Blanchard , José M. Gracia-Bondía , Joseph C. Várilly

The logical structure and the basic theorems of time-dependent current density functional theory (TDCDFT) are analyzed and reconsidered from the point of view of recently proposed time-dependent deformation functional theory (TDDefFT). It…

Strongly Correlated Electrons · Physics 2019-03-27 I. V. Tokatly

The Hohenberg-Kohn theorem of density-functional theory (DFT) is broadly considered the conceptual basis for a full characterization of an electronic system in its ground state by just the one-body particle density. In this Part~II of a…

We present the current-density functional theory for the superconductor immersed in the magnetic field. The order parameter of the superconducting state, transverse component of the paramagnetic current-density, and electron density are…

Superconductivity · Physics 2016-10-04 Katsuhiko Higuchi , Masahiko Higuchi

We construct a density-functional formalism adapted to uniform external magnetic fields that is intermediate between conventional Density Functional Theory and Current-Density Functional Theory (CDFT). In the intermediate theory, which we…

Chemical Physics · Physics 2018-02-14 Erik I. Tellgren , Andre Laestadius , Trygve Helgaker , Simen Kvaal , Andrew M. Teale

In this chapter we first review the Levy-Lieb functional, which gives the lowest kinetic and interaction energy that can be reached with all possible quantum states having a given density. We discuss two possible convex generalizations of…

Mathematical Physics · Physics 2023-09-19 Mathieu Lewin , Elliott H. Lieb , Robert Seiringer

In the framework of density functional theory a formalism to describe electronic transport in the steady state is proposed which uses the density on the junction and the {\em steady current} as basic variables. We prove that, in a finite…

Mesoscale and Nanoscale Physics · Physics 2016-01-12 G. Stefanucci , S. Kurth

A semi-relativistic density-functional theory that includes spin-orbit couplings and Zeeman fields on equal footing with the electromagnetic potentials, is an appealing framework to develop a unified first-principles computational approach…

Materials Science · Physics 2017-09-13 S. Pittalis , G. Vignale , F. G. Eich
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