Related papers: Chirality in Block Copolymer Melts: Mesoscopic Hel…
The nature of the transition between worm-like and spherical micelles in block copolymer dispersions varies between systems. In some formulations, heating drives a transition from worms to spheres, while in other systems the same transition…
We develop a theory of point defects in cholesterics and textures in spherical droplets with normal anchoring. The local structure of chiral defects is described by singularity theory and a smectic-like gradient field establishing a nexus…
We study by simulation the physics of two colloidal particles in a cholesteric liquid crystal with tangential order parameter alignment at the particle surface. The effective force between the pair is attractive at short range and favors…
We consider the shear flow of well-aligned one-component smectic phases, such as thermotropic smectics and lamellar diblock copolymers, below the critical region. We show that, as a result of thermal fluctuations of the layers, parallel…
Recent progress in constructing supramolecular assemblies with hierarchical chirality offers new opportunities to investigate the chirality-induced spin selectivity (CISS) effect and its potential applications. In this work, we…
Soft spheres interacting via a hard core and range of attractive and repulsive "soft-shoulder" potentials self-assemble into clusters forming a variety of mesophases. We combine a mean field theory developed from a lattice model with a…
Particles in the shape of chiral dipoles show a preferential rotation in three dimensional homogeneous isotropic turbulence. A chiral dipole consists of a rod with two helices of opposite handedness, one at each end. We can use 3d printing…
The stability of micelles self-assembled from block copolymers can be altered by the degradation of the blocks. Slow degradation shifts the equilibrium size distribution of block copolymer micelles and change their properties.…
In soft matter, the polar orientational order of molecules can facilitate the coexistence of structural chirality and ferroelectricity. The ferroelectric nematic (NF) state, exhibited by achiral calamitic molecules with large dipole…
Most theoretical descriptions of lyotropic cholesteric liquid crystals to date focus on homogeneous systems in which the rod concentration, as opposed to the rod orientation, is uniform. In this work, we build upon the Onsager-Straley…
We investigate - with Monte Carlo computer simulations - the phase behaviour of dimeric colloidal molecules on periodic substrates with square symmetry. The molecules are formed in a two-dimensional suspension of like charged colloids…
We show that the stability (existence/absence) and interaction (repulsion/attraction) of chiral solitons in monoaxial chiral magnets can be varied by tilting the direction of magnetic field. We, thereby, elucidate that the condensation of…
In this paper we consider thin films of AB block copolymer melts confined between two parallel plates. The plates are identical and may have a preference for one of the monomer types over the other. The system is characterized by four…
Isoporous membranes made from diblock copolymers have numerous applications, including water treatment and protein separation, and are successfully produced at a laboratory scale under controlled conditions. However, achieving optimal…
In many biological materials with a hierarchical structure there is an intriguing and unique mechanism responsible for the 'propagation' of order from the molecular to the nano- or micro-scale level. Here we present a much simpler molecular…
We present a pedagogical review of the swelling thermodynamics and phase transitions of polymer gels. In particular, we discuss how features of the volume phase transition of the gel's osmotic equilibrium is analogous to other transitions…
We study the phase behaviour of a quasi-two dimensional cholesteric liquid crystal shell. We characterise the topological phases arising close to the isotropic-cholesteric transition, and show that they differ in a fundamental way from…
With the use of chiral organic cations in two-dimensional metal halide perovskites, chirality can be induced in the metal halide layers, which results in semiconductors with intriguing chiral optical and spin-selective transport properties.…
We study spin chirality for a spin-1/2 zigzag XY chain at low temperature by applying a low-temperature density-matrix renormalization group technique. We calculate temperature dependence of dynamical and static correlations of the…
We present Monte Carlo simulation results for square-well homopolymers at a series of bond lengths. Although the model contains only isotropic pairwise interactions, under appropriate conditions this system shows spontaneous chiral symmetry…