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We study the termination problem for nondeterministic recursive probabilistic programs. First, we show that a ranking-supermartingales-based approach is both sound and complete for bounded terminiation (i.e., bounded expected termination…

Programming Languages · Computer Science 2017-01-12 Krishnendu Chatterjee , Hongfei Fu

The extension of the density functional theory (DFT) to include pairing correlations without formal violation of the particle-number conservation condition is described. This version of the theory can be considered as a foundation of the…

Nuclear Theory · Physics 2007-05-23 S. Krewald , V. B. Soubbotin , V. I. Tselyaev , X. Vinas

An important result in classical stochastic thermodynamics is the work fluctuation--dissipation relation (FDR), which states that the dissipated work done along a slow process is proportional to the resulting work fluctuations. Here we show…

Quantum Physics · Physics 2019-12-11 Harry J. D. Miller , Matteo Scandi , Janet Anders , Martí Perarnau-Llobet

It is known for quite some time that approximate density functional (ADF) theories fail disastrously when describing the dis-sociative symmetric radical cations R2+. Considering this dissociation limit, previous work has shown that…

Materials Science · Physics 2016-09-28 Ester Livshits , Roi Baer

An analytical theory is developed for radiationless transitions in molecules characterized by nonequilibrium populations of their vibrational modes. Several changes to the standard transition-state framework follow from nonequilibrium…

Chemical Physics · Physics 2019-03-27 Dmitry V. Matyushov

Approximation of scattered geometric data is often a task in many engineering problems. The Radial Basis Function (RBF) approximation is appropriate for large scattered (unordered) datasets in d-dimensional space. This method is useful for…

Graphics · Computer Science 2018-04-19 Zuzana Majdisova , Vaclav Skala

Density Functional Theory (DFT) allows for predicting all the chemical and physical properties of molecular systems from first principles by finding an approximate solution to the many-body Schr\"odinger equation. However, the cost of these…

Machine Learning · Computer Science 2025-06-03 Majdi Hassan , Cristian Gabellini , Hatem Helal , Dominique Beaini , Kirill Neklyudov

Approximation of scattered data is often a task in many engineering problems. The Radial Basis Function (RBF) approximation is appropriate for large scattered datasets in d-dimensional space. It is non-separable approximation, as it is…

Numerical Analysis · Mathematics 2018-06-13 Zuzana Majdisova , Vaclav Skala

The classical Density Functional Theory (DFT) is introduced as an application of entropic inference for inhomogeneous fluids at thermal equilibrium. It is shown that entropic inference reproduces the variational principle of DFT when…

Statistical Mechanics · Physics 2021-09-14 Ahmad Yousefi , Ariel Caticha

Aspects of Density Functional Resonance Theory (DFRT) [Phys. Rev. Lett. \textbf{107}, 163002 (2011)], a recently developed complex-scaled version of ground-state Density Functional Theory (DFT), are studied in detail. The asymptotic…

Quantum Physics · Physics 2015-06-04 Daniel L. Whitenack , Adam Wasserman

The paper is devoted to the study of the unconditional extremal problem for a fractional linear integral functional defined on a set of probability distributions. In contrast to results proved earlier, the integrands of the integral…

Optimization and Control · Mathematics 2019-06-14 Peter Shnurkov , Kseniia Adamova

We derive equations of motion for the reduced density matrix of a molecular system which undergoes energy transfer dynamics competing with fast internal conversion channels. Environmental degrees of freedom of such a system have no time to…

Chemical Physics · Physics 2017-05-24 Joachim Seibt , Tomas Mancal

In nonequilibrium steady states of Markov jump processes, we derive exact Fluctuation-Response Relations (FRRs) that express the covariance between any pair of currents in terms of static responses in a notably simple form, thus…

Statistical Mechanics · Physics 2025-04-17 Timur Aslyamov , Krzysztof Ptaszyński , Massimiliano Esposito

We reassess the problem of renormalization in finite temperature field theory (FTFT). A new point of view elucidates the relation between the ultraviolet divergences for T=0 and $T \not= 0$ theories and makes clear the reason why the…

High Energy Physics - Theory · Physics 2008-11-26 D. H. T. Franco , J. L. Acebal

There has been considerable recent study in "sub-diffusion" models that replace the standard parabolic equation model by a one with a fractional derivative in the time variable. There are many ways to look at this newer approach and one…

Analysis of PDEs · Mathematics 2019-04-08 William Rundell , Zhidong Zhang

Nuclear Density Functional Theory (DFT) plays a prominent role in the understanding of nuclear structure, being the approach with the widest range of applications. Hohenberg and Kohn theorems warrant the existence of a nuclear Energy…

Nuclear Theory · Physics 2020-03-03 G. Accorto , P. Brandolini , F. Marino , A. Porro , A. Scalesi , G. Colò , X. Roca-Maza , E. Vigezzi

We consider non-reversible perturbations of reversible diffusions that do not alter the invariant distribution and we ask whether there exists an optimal perturbation such that the rate of convergence to equilibrium is maximized. We solve…

Numerical Analysis · Mathematics 2015-06-12 Tony Lelièvre , Francis Nier , Grigorios A. Pavliotis

In modern scientific research, the objective is often to identify which variables are associated with an outcome among a large class of potential predictors. This goal can be achieved by selecting variables in a manner that controls the the…

Methodology · Statistics 2023-10-10 Yushu Shi , Michael Martens

We revisit the Gray-Wyner lossy source coding problem and derive the first-order asymptotic optimal rate-distortion-perception region when additional perception constraints are imposed on reproduced source sequences. The optimal trade-off…

Information Theory · Computer Science 2026-01-19 Yu Yang , Yingxin Zhang , Weijie Yuan , Lin Zhou

In this work we study the rate-distortion function (RDF) for lossy compression of asynchronously-sampled continuous-time (CT) wide-sense cyclostationary (WSCS) Gaussian processes with memory. As the case of synchronous sampling, i.e., when…

Information Theory · Computer Science 2024-05-27 Zikun Tan , Ron Dabora , H. Vincent Poor