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Graphene nanoribbons are the counterpart of carbon nanotubes in graphene-based nanoelectronics. We investigate the electronic properties of chemically modified ribbons by means of density functional theory. We observe that chemical…

Materials Science · Physics 2009-09-29 F. Cervantes-Sodi , G. Csányi , S. Piscanec , A. C. Ferrari

The electronic structure of finite-length armchair carbon nanotubes has been studied using several ab-initio and semi-empirical quantum computational techniques. The additional confinement of the electrons along the tube axis leads to the…

Materials Science · Physics 2007-05-23 Alain Rochefort , Dennis R. Salahub , Phaedon Avouris

We have applied density-functional theory (DFT) based calculations to investigate the size and strain effects on the electronic properties, such as band structures, energy gaps, and effective masses of the electron and the hole, in Si…

Computational Physics · Physics 2010-10-11 Xihong Peng , Azar Alizadeh , Sanat K. Kumar , Saroj K. Nayak

A correlation is observed between the diameter (d) distribution of single walled carbon nanotubes and the percentages of metallic and semiconducting tubes in materials synthesized at low temperature (600 C) by plasma-assisted chemical vapor…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Yiming Li , Shu Peng , David Mann , Jien Cao , Ryan Tu , K. J. Cho , Hongjie Dai

Contrary to recent reports, we show that the electronic properties of phosphorene nanotubes are surprisingly rich and much more complex than previously assumed. We find that all phosphorene nanotubes exhibit an intricate direct-to-indirect…

Mesoscale and Nanoscale Physics · Physics 2018-03-07 Sarah I. Allec , Bryan M. Wong

The electronic structures of zig-zag and arm-chair single-walled carbon nanotubes interacting with a transitional-metal atomic nanowire of Ni have been determined. The Ni nanowire creates a large electron density of states (DOS)at the Fermi…

Superconductivity · Physics 2009-11-07 Nacir Tit , M. W. C. Dharma-wardana

We use the robust nearest-neighbour tight-binding approximation to study on the same footing interband dipole transitions in narrow-bandgap carbon nanotubes and graphene nanoribbons. It is demonstrated that curvature effects in metallic…

Mesoscale and Nanoscale Physics · Physics 2019-04-30 R. R. Hartmann , V. A. Saroka , M. E. Portnoi

We present a new mechanism of carbon nanotube superconductivity that originates from edge states which are specific to graphene. Using on-site and boundary deformation potentials which do not cause bulk superconductivity, we obtain an…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 K. Sasaki , J. Jiang , R. Saito , S. Onari , Y. Tanaka

Carboxylic functionalization (-COOH groups) of carbon nanotubes is known to improve their dispersion properties and increase the electrical conductivity of carbon-nanotube - polymer nanocomposites. We have studied experimentally the effects…

We study one dimensional (1D) carbon ribbons with the armchair edges and the zigzag carbon nanotubes and their counterparts with finite length (0D) in the framework of the H\"{u}ckel model. We prove that a 1D carbon ribbon is metallic if…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 A. V. Nikolaev , A. V. Bibikov , A. V. Avdeenkov , I. V. Bodrenko , E. V. Tkalya

The inclusion and encapsulation of terthiophene (T3) molecules inside zigzag single-walled carbon nanotubes (CNTs) is addressed by density functional calculations. We consider the T3 molecule inside five semiconducting CNTs with diameters…

Materials Science · Physics 2009-11-11 W. Orellana , S. O. Vasquez

Here we describe a computational study undertaken in an effort to elucidate the reaction mechanisms behind the experimentally observed oxidations and hydrations catalyzed by graphene oxide (GO). Using the oxidation of benzyl alcohol to…

Materials Science · Physics 2012-11-13 Danil W. Boukhvalov , Daniel R. Dreyer , Christopher W. Bielawski , Young-Woo Son

We investigate curvature effects on geometric parameters, energetics and electronic structure of zigzag nanotubes with fully optimized geometries from first-principle calculations. The calculated curvature energies, which are inversely…

Materials Science · Physics 2009-11-07 O. Gulseren , T. Yildirim , S. Ciraci

Armchair graphene nanoribbons with different proportions of edge oxygen atoms are investigated by using crystal orbital method based on density functional theory. All the nanoribbons are energetically favorable, although buckled edges are…

Materials Science · Physics 2014-11-07 Hongyu Ge , Guo Wang , Yi Liao

We perform analysis of the band structure, phonon dispersion, and electron-phonon interactions in three types of small-radius carbon nanotubes. We find that the (5,5) can be described well by the zone-folding method and the electron-phonon…

Superconductivity · Physics 2009-11-10 Ryan Barnett , Eugene Demler , Efthimios Kaxiras

We systematically investigate the relationships between structural and electronic effects of finite size zigzag or armchair carbon nanotubes of various diameters and lengths, starting from a molecular template of varying shape and diameter,…

The electronic properties of squashed arm-chair carbon nanotubes are modeled using constraint free density functional tight binding molecular dynamics simulations. Independent from CNT diameter, squashing path can be divided into {\it…

Computational Physics · Physics 2009-11-11 H. Mehrez , A. Svizhenko , M. P. Anantram , M. Elstner , T. Frauenheim

The temperature dependence of the band gap of semiconducting single-wall carbon nanotubes (SWNTs) is calculated by direct evaluation of electron-phonon couplings within a ``frozen-phonon'' scheme. An interesting diameter and chirality…

Materials Science · Physics 2009-11-10 Rodrigo B. Capaz , Catalin D. Spataru , Paul Tangney , Marvin L. Cohen , Steven G. Louie

We present {\it ab initio} calculations of the magnetic susceptibility and of the $^{13}$C chemical shift for carbon nanotubes, both isolated and in bundles. These calculations are performed using the recently proposed gauge-including…

Materials Science · Physics 2009-11-11 Miguel A. L. Marques , Mayeul d'Avezac , Francesco Mauri

Electron mobility due to electron-phonon interaction is investigated for fully fluorinated/hydrogenated zig-zag carbon nanotubes containing one-dimensional alternating chains of carbon atoms with $\pi$-bonds. The behavior of mobility…

Mesoscale and Nanoscale Physics · Physics 2025-12-03 V. L. Katkov , V. A. Osipov