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A review of electronic properties of insulating-, boron- and phosphorus-doped diamond is given. The main goal is, to show data in a wider context, to reveal trends and limitations with respect to carrier mobilities, conductivities, p- and…

Materials Science · Physics 2020-05-11 Christoph E. Nebel

Diamond has always been adored as a jewel. Even more fascinating is its outstanding physical properties; it is the hardest material known in the world with the highest thermal conductivity. Meanwhile, when we turn to its electrical…

Superconductivity · Physics 2007-05-23 Y. Takano , M. Nagao , K. Kobayashi , H. Umezawa , I. Sakaguchi , M. Tachiki , T. Hatano , H. Kawarada

The resistivity of polycrystalline chemical vapor deposition diamond sensors is studied in samples exposed to fluences relevant to the environment of the High Luminosity Large Hadron Collider. We measure the leakage current for a range of…

Instrumentation and Detectors · Physics 2013-10-11 Rui Wang , Martin Hoeferkamp , Sally Seidel

We report optical reflectivity study on pure and boron-doped diamond films grown by a hot-filament chemical vapor deposition method. The study reveals the formation of an impurity band close to the top of the valence band upon boron-doping.…

Superconductivity · Physics 2009-11-11 Dan Wu , Y. C. Ma , Z. L. Wang , Q. Luo , C. Z. Gu , N. L. Wang , C. Y. Li , X. Y. Lu , Z. S. Jin

Superconductivity was discovered in heavily boron-doped diamond thin films deposited by the microwave plasma assisted chemical vapor deposition (MPCVD) method. Advantages of the MPCVD deposited diamond are the controllability of boron…

Boron-doped diamond granular thin films are known to exhibit superconductivity with an optimal critical temperature of Tc = 7.2K. Here we report the measured complex surface impedance of Boron-doped diamond films in the microwave frequency…

Diamond, a wide band-gap semiconductor, can be engineered to exhibit superconductivity when doped heavily with boron. The phenomena has been demonstrated in samples grown by chemical vapour deposition where the boron concentration exceeds…

Boron implantation with in-situ dynamic annealing is used to produce highly conductive sub-surface layers in type IIa (100) diamond plates for the search of a superconducting phase transition. Here we demonstrate that high-fluence MeV…

Materials Science · Physics 2016-06-21 L. H. Willems van Beveren , R. Liu , H. Bowers , K. Ganesan , B. C. Johnson , J. C. McCallum , S. Prawer

Heavily-boron-doped diamond films become superconducting with critical temperatures $T_c$ well above 4 K. Here we first measure the reflectivity of such a film down to 5 cm$^{-1}$, by also using Coherent Synchrotron Radiation. We thus…

Superconductivity · Physics 2009-11-11 M. Ortolani , S. Lupi , L. Baldassarre , P. Calvani , U. Schade , Y. Takano , M. Nagao , T. Takenouchi , H. Kawarada

A novel diamond anvil cell suitable for electrical transport measurements under high pressure has been developed. A boron-doped metallic diamond film was deposited as an electrode onto a nano-polycrystalline diamond anvil using a microwave…

Superconductivity · Physics 2018-04-17 R. Matsumoto , Y. Sasama , M. Fujioka , T. Irifune , M. Tanaka , T. Yamaguchi , H. Takeya , Y. Takano

Surface electronic properties of undoped hydrogen terminated diamond covered with adsorbates or in electrolyte solutions are summarized. The formation of a conductive layer at the surface of diamond is discussed based on Hall effect,…

Materials Science · Physics 2020-05-11 Christoph E. Nebel

Homoepitaxial diamond layers doped with boron in the 10^20-10^21 /cm3 range are shown to be type II superconductors with sharp transitions (~0.2K) at temperatures increasing from 0 to 2.1 K with boron contents. The critical concentration…

We performed high-temperature luminescence studies of silicon-vacancy color centers obtained by ion implantation in single crystal diamond. We observed reduction of the integrated fluorescence upon increasing temperature, ascribable to a…

Hole doping can control the conductivity of diamond either through boron substitution, or carrier accumulation in a field-effect transistor. In this work, we combine the two methods to investigate the insulator-to-metal transition at the…

Materials Science · Physics 2020-07-07 Erik Piatti , Francesco Galanti , Giulia Pippione , Alberto Pasquarelli , Renato S. Gonnelli

Electrically-conducting diamond is a promising candidate for next-generation electronic, thermal and electrochemical applications. One of the major obstacles towards its exploitation is the strong degradation that some of its key physical…

Mesoscale and Nanoscale Physics · Physics 2019-11-28 Erik Piatti , Davide Romanin , Dario Daghero , Renato S. Gonnelli

We have investigated the low energy electronic state of a boron-doped diamond thin film by the ultrahigh resolution laser-excited photoemission spectroscopy. We observed a clear shift of the leading edge below 11 K indicative of a…

We consider superconductivity in boron (B) doped diamond using a simplified model for the valence band of diamond. We treat the effects of substitutional disorder of B ions by the coherent potential approximation (CPA) and those of the…

Superconductivity · Physics 2015-06-25 T. Shirakawa , S. Horiuchi , Y. Ohta , H. Fukuyama

We report the discovery of superconductivity in boron-doped diamond synthesized at high pressure (8-9 GPa) and temperature (2,500-2,800 K). Electrical resistivity, magnetic susceptibility, specific heat, and field-dependent resistance…

Superconductivity · Physics 2009-11-10 E. A. Ekimov , V. A. Sidorov , E. D. Bauer , N. N. Mel'nik , N. J. Curro , J. D. Thompson , S. M. Stishov

Boron-doped diamond crystals (BDD, C$_{1-x}$B$_{x}$) exhibit exceptional mechanical strength, electronic tunability, and resistance to radiation damage. This makes them promising materials for use in gamma-ray crystal-based light sources.…

Thermal conductivities $\Lambda $ of amorphous carbon thin films are measured in the temperatures range 80--400 K using the $3\omega $ method. Sample films range from soft a-C:H prepared by remote-plasma deposition ($\Lambda = 0.20$ W…

Materials Science · Physics 2009-10-31 Andrew J. Bullen , Keith E. O'Hara , David G. Cahill , Othon Monteiro , Achim von Keudell
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