Related papers: Upper limit for the D2H+ ortho-to-para ratio in th…

The millimeter-wave rotational emission lines (4(04)-3(03) and 5(05)-4(04)) of protonated carbon dioxide, HCO2+(HOCO+), has been detected toward the low-mass class 0 protostar IRAS 04368+2557 in L1527 with the IRAM 30 m telescope. This is…

The Atacama Pathfinder Experiment (APEX) 12m telescope was used to observe the N=1-0, J=0-1 ground state transitions of OH+ at 909.1588 GHz with the CHAMP+ heterodyne array receiver. Two blended hyperfine structure transitions were detected…

Using a broadband, high spectral resolution survey toward Orion KL acquired with Herschel/HIFI as part of the HEXOS key program, we derive the abundances of H$_2$O and HDO in the different spatial/velocity components associated with this…

HOCO$^+$ is a polar molecule that represents a useful proxy for its parent molecule CO$_2$, which is not directly observable in the cold interstellar medium. This cation has been detected towards several lines of sight, including massive…

We report on a search for Interstellar CH2D+. Four transitions occur in easily accessible portions of the spectrum; we report on emission at the frequencies of these transitions toward high column density star-forming regions. While the…

The gas kinetic temperature in the centres of starless, high-density cores is predicted to fall as low as 5-6 K. The aim of this study was to determine the kinetic temperature distribution in the low-mass prestellar core Oph D where…

The formation of CH+ in the interstellar medium has long been an outstanding problem in chemical models. In order to probe the physical conditions of the ISM in which CH+ forms, we propose the use of CH3+ observations. The pathway to…

The H3+ and H2D+ ions are important probes of the physical and chemical conditions in regions of the interstellar medium where new stars are forming. This paper reviews how observations of these species and of heavier ions such as HCO+ and…

We present experimental results obtained from photoionization and photodissociation processes of abundant interstellar CH$_3$-X type organic molecules like methanol (CH$_3$OH), methylamine (CH$_3$NH$_2$) and acetonitrile (CH$_3$CN) as…

We present a new method for the simultaneous calculation of the cosmic ray ionization rate, zeta(H2), and the ionization fraction, chi(e), in dense molecular clouds. A simple network of chemical reactions dominant in the creation and…

We determine the D/H ratio in the interstellar medium toward the DO white dwarf PG0038+199 using spectra from the Far Ultraviolet Spectroscopic Explorer (FUSE), with ground-based support from Keck HIRES. We employ curve of growth, apparent…

This paper explores the sensitivity of line profiles of H2D+, HCO+ and N2H+, observed towards the center of L1544, to various kinematic and chemical parameters. The total width of the H2D+ line can be matched by a static model and by models…

The interpretation of water line emission from existing observations and future HIFI/Herschel data requires a detailed knowledge of collisional rate coefficients. Among all relevant collisional mechanisms, the rotational (de)excitation of…

We have used archival far-ultraviolet spectra from observations made by HST/STIS and FUSE to determine the column densities and rotational excitation temperatures for CO and H2, respectively, along the lines of sight to 23 Galactic O and B…

We present a (sub)millimeter line survey of the methanol maser outflow located in the massive star-forming region DR21(OH) carried out with the Submillimeter Array (SMA) at 217/227 GHz and 337/347 GHz. We find transitions from several…

We perform a complete census of molecular ions with an abundance larger than 1e-10 in the protostellar shock L1157-B1 by means of an unbiased high-sensitivity survey obtained with the IRAM-30m and Herschel/HIFI. By means of an LVG radiative…

Clouds of high infrared extinction are promising sites of massive star/cluster formation. A large number of cloud cores discovered in recent years allows investigation of possible evolutionary sequence among cores in early phases. We have…

We report the detection in TMC-1 of the protonated form of C3S. The discovery of the cation HC3S+ was carried through the observation of four harmonically related lines in the Q band using the Yebes 40m radiotelescope, and is supported by…

The ketenyl radical, HCCO, has recently been detected in the ISM for the first time. Further astronomical detections of HCCO will help us understand its gas-grain chemistry, and subsequently revise the oxygen-bearing chemistry towards dark…

Protostars interact with their surroundings through jets and winds impacting on the envelope and creating shocks, but the nature of these shocks is still poorly understood. Our aim is to survey far-infrared molecular line emission from a…