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In this work, we study structural and vibrational properties of multilayer graphene using density-functional theory (DFT) with van der Waals (vdW) functionals. Initially, we analyze how different vdW functionals compare by evaluating the…

Mesoscale and Nanoscale Physics · Physics 2019-11-05 Rafael R. Del Grande , Marcos G. Menezes , Rodrigo B. Capaz

Surface properties of mixtures of charged platelike colloids and salt in contact with a charged planar wall are studied within density functional theory. The particles are modeled by hard cuboids with their edges constrained to be parallel…

Soft Condensed Matter · Physics 2011-09-14 Markus Bier , Ludger Harnau , S. Dietrich

Two-dimensional (2D) metallic states induced by oxygen vacancies at oxide surfaces and interfaces provide new opportunities for the development of advanced applications, but the ability to control the behavior of these states is still…

We describe a test particle approach based on dynamical density functional theory (DDFT) for studying the correlated time evolution of the particles that constitute a fluid. Our theory provides a means of calculating the van Hove…

Soft Condensed Matter · Physics 2011-03-17 Paul Hopkins , Andrea Fortini , Andrew Archer , Matthias Schmidt

We grew highly textured phase pure VO2 thin films on c-plane Al2O3 substrates with different oxygen partial pressure. X-ray absorption and photoemission spectroscopy confirm the identical valence state of vanadium ions despite the different…

Materials Science · Physics 2015-06-09 Salinporn Kittiwatanakul , Jude Laverock , Dave Newby , Kevin E. Smith , Stuart A. Wolf , Jiwei Lu

We report on the low-energy electronic structure of Tantalum ditelluride (1$T'$-TaTe$_2$), one of the charge density wave (CDW) materials from the group V transition metal dichalcogenides using angle-resolved photoemission spectroscopy…

The correlated electronic structure of the submonolayer surface systems Sn/Si(111) and Sn/Ge(111) is investigated by density-functional theory (DFT) and its combination with explicit many-body methods. Namely, the dynamical mean-field…

Materials Science · Physics 2015-03-13 Sergej Schuwalow , Daniel Grieger , Frank Lechermann

We resolve issues that have plagued reliable prediction of relative phase stability for solid-solutions and compounds. Due to its commercially important phase diagram, we showcase Al-Li system because historically density-functional theory…

Materials Science · Physics 2013-12-25 Aftab Alam , D. D. Johnson

The metal-organic framework (MOF) MFU-4l containing Co(II) centers and Cl- ligands has recently shown promising redox activity. Aiming for further improved MOF catalysts for oxidation processes employing molecular oxygen we present a…

Materials Science · Physics 2013-11-27 Jelena Jelic , Dmytro Denysenko , Dirk Volkmer , Karsten Reuter

We study the dynamics of colloidal suspensions of hard spheres that are subject to Brownian motion in the overdamped limit. We obtain the time evolution of the self and distinct parts of the van Hove function by means of dynamical density…

Soft Condensed Matter · Physics 2018-01-16 Daniel Stopper , Kevin Marolt , Hendrik Hansen-Goos , Roland Roth

We present a dynamic density functional theory (dDFT) which takes into accou nt the advection of the particles by a flowing solvent. For potential flows we can use the same closure as in the absence of solvent flow. The structure of the…

Soft Condensed Matter · Physics 2009-11-13 Markus Rauscher , Alvaro Dominguez , Matthias Krueger , Florencia Penna

We calculate density profiles of a simple model fluid in contact with a planar surface using density functional theory (DFT), in particular for the case where there is a vapour layer intruding between the wall and the bulk liquid. We apply…

Soft Condensed Matter · Physics 2019-04-16 Hanyu Yin , David N. Sibley , Andrew J. Archer

Using density-functional theory, we predict that the oxidation of the Ru(0001) surface proceeds via the accumulation of sub-surface oxygen in two-dimensional islands between the first and second substrate layer. This leads locally to a…

The phase diagram of surface structures for the model catalyst RuO2(110) in contact with a gas environment of O2 and CO is calculated by density-functional theory and atomistic thermodynamics. Adsorption of the reactants is found to depend…

Materials Science · Physics 2009-11-10 Karsten Reuter , Matthias Scheffler

Results from first principles density functional theory (DFT) calculations and classical molecular dynamics (CMD) simulations are presented on moire-corrugation of graphene (gr). We find that the moire-corrugated graphene could be…

Materials Science · Physics 2014-03-11 P. Süle

By investigating the crystalline structure of ground-state orthorhombic SrRuO$_3$, we present a benchmark study of some of the most popular density functional theory (DFT) approaches from the local density approximation (LDA),…

Materials Science · Physics 2016-08-03 Š. Masys , V. Jonauskas

An extensive theoretical investigation of the nonpolar (10$\bar{1}$0) and (11$\bar{2}$0) surfaces as well as the polar zinc terminated (0001)--Zn and oxygen terminated (000$\bar{1}$)--O surfaces of ZnO is presented. Particular attention is…

Materials Science · Physics 2009-11-07 B. Meyer , Dominik Marx

Density Functional Theory (DFT) is a robust framework for modeling interacting many-body systems, including the equation of state (EoS) of dense matter. Many models, however, rely on energy functionals based on assumptions that have not…

Nuclear Theory · Physics 2025-06-06 Udita Shukla , Pok Man Lo

Metal-oxide-metal devices based on amorphous VOx are shown to exhibit one of two distinct negative differential resistance (NDR) characteristics depending on the maximum current employed for electroforming. For low compliance currents they…

Applied Physics · Physics 2021-02-03 Sanjoy Kumar Nandi , Sujan Kumar Das , Caleb Estherby , Angus Gentle , Robert G. Elliman

Surface strain often controls properties of the material including charge transport and chemical reactivity. Localized surface strain is measured with atomic resolution on (111) ceria nanoparticle surfaces using environmental transmission…

Materials Science · Physics 2023-05-19 Piyush Haluai , Tara M. Boland , Ethan L. Lawrence , Peter A. Crozier