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The magnetic properties of single-crystal EuTiO3 are suggestive of nanoscale disorder below its cubic-tetragonal phase transition. We demonstrate that electric field cooling acts to restore monocrystallinity, thus confirming that emergent…

Strongly Correlated Electrons · Physics 2013-03-06 A. P. Petrovic , Y. Kato , S. S. Sunku , T. Ito , P. Sengupta , L. Spalek , M. Shimuta , T. Katsufuji , C. D. Batista , S. Saxena , C. Panagopoulos

In this paper we study the size effects of the ferroelectric nanotube and nanowire phase diagrams and polar properties allowing for radial stress and depolarization field influence. The approximate analytical expression for the…

Materials Science · Physics 2009-05-09 Anna N. Morozovska , Maya D. Glinchuk , Eugene A. Eliseev

Magnetic, dielectric and calorimetric studies on 0.9BiFeO3-0.1BaTiO3 indicate strong magnetoelectric coupling. XRD studies reveal a very remarkable change in the rhombohedral distortion angle and a significant shift in the atomic positions…

Materials Science · Physics 2009-11-13 Anar Singh , Vibhav Pandey , R. K. Kotnala , Dhananjai Pandey

The design of novel multiferroic ABO$_3$ perovskites is complicated by the presence of necessary magnetic cations and ubiquitous antiferrodistortive modes, both of which suppress polar distortions. Using first-principles simulations, we…

Materials Science · Physics 2024-06-10 Cameron A. M. Scott , Nicholas C. Bristowe

Octahedral distortion plays a key role in engineering the physical properties of heterostructures composed of perovskite oxides. We observe a strong in-plane uniaxial magnetic anisotropy in a strain-enabled multiferroic EuTiO3 thin film…

Materials Science · Physics 2015-06-17 X. Ke , T. Birol , R. Misra , J. -H. Lee , B. J. Kirby , D. G. Schlom , C. J. Fennie , J. W. Freeland

Microscopic structural instabilities of EuTiO3 single crystal were investigated by synchrotron x-ray diffraction. Antiferrodistortive (AFD) oxygen octahedral rotational order was observed alongside Ti derived antiferroelectric (AFE)…

The coexistence and coupling of magnetic and ferroelectric orderings in single phase multiferroics has evinced enormous scientific interest as it involves breaking of time reversal and space inversion symmetries in the same material. The…

The magnetic structure of multiferroic Ni$_3$V$_2$O$_8$ has been investigated using non-resonant X-ray magnetic scattering. Incident circularly polarized X-rays combined with full polarization analysis of the scattered beam is shown to…

Strongly Correlated Electrons · Physics 2015-05-18 F. Fabrizi , H. C. Walker , L. Paolasini , F. de Bergevin , T. Fennell , N. Rogado , R. J. Cava , Th. Wolf , M. Kenzelmann , D. F. McMorrow

Two-dimensional (2D) multiferroics exhibit cross-control capacity between magnetic and electric responses in reduced spatial domain, making them well suited for next-generation nanoscale devices; however, progress has been slow in…

Materials Science · Physics 2020-05-15 Jing Shang , Chun Li , Aijun Du , Ting Liao , Yuantong Gu , Yandong Ma , Liangzhi Kou , Changfeng Chen

The perovskite oxide EuTiO3 (ETO) has attracted increased scientific interest due to its potential multiferroic properties and magnetic activity above and below its structural phase transition at TS=282K. Various experiments have indirectly…

Mutiferroics are a novel class of next generation multifunctional materials, which display simultaneous magnetic spin, electric dipole, and ferroelastic ordering, and have drawn increasing interest due to their multi-functionality for a…

Materials Science · Physics 2015-12-09 N. Ortega , Ashok Kumar , J. F. Scott , Ram S. Katiyar

Using the results of x-ray and neutron diffraction experiments, we show that the ferroelectric polarization, in ~22 nm particles of BiFeO3, exhibits a jump by ~30% around the magnetic transition point T_N (~635 K) and a suppression by ~7%…

Materials Science · Physics 2011-08-18 S. Goswami , Dipten Bhattacharya , P. Choudhury , B. Ouladdiaf , T. Chatterji

The electronic structure and magnetism in the sodium nickelate NaNiO_2 in the low-temperature phase is studied from density-functional calculations using the linear muffin-tin orbitals method. An antiferromagnetic solution with a magnetic…

Strongly Correlated Electrons · Physics 2009-11-10 H. Meskine , S. Satpathy

Composite materials comprised of ferroelectric nanoparticles in a dielectric matrix are being actively investigated for a variety of functional properties attractive for a wide range of novel electronic and energy harvesting devices.…

Mesoscale and Nanoscale Physics · Physics 2017-01-11 John Mangeri , Yomery Espinal , Andrea Jokisaari , S. Pamir Alpay , Serge Nakhmanson , Olle Heinonen

A series of manganites Tb1-xHoxMnO3 (0<=x<=0.6) with orthorhombic structure are synthesized and detailed investigations on their multiferroicity are performed. Successive magnetic transitions upon temperature variation are evidenced for all…

Strongly Correlated Electrons · Physics 2010-04-19 C. L. Lu , S. Dong , K. F. Wang , J. -M. Liu

Dielectric and magnetic properties of Eu0.5Ba0.25Sr0.25TiO3 are investigated between 10 K and 300 K in the frequency range from 10 Hz to 100 THz. A peak in permittivity revealed near 130 K and observed ferroelectric hysteresis loops prove…

Materials Science · Physics 2012-10-12 Veronica Goian , Stanislav Kamba , Premysl Vanek , Maxim Savinov , Christelle Kadlec , Jan Prokleska

We have successfully induced multiferroic behavior in the A-type antiferromagnet SmMnO3 by the substitution of Y at the Sm site. A magnetic transition develops at 24 K for Sm1-xYxMnO3 (x=0.4,0.5) which is not present in the parent compound.…

Strongly Correlated Electrons · Physics 2011-05-17 D. O'Flynn , C. V. Tomy , M. R. Lees , A. Daoud-Aladine , G. Balakrishnan

Bismuth ferrite is one of the most widely studied multiferroic materials because of its large ferroelectric polarisation coexisting with magnetic order at room temperature. Using density functional theory (DFT), we identify several…

Materials Science · Physics 2021-05-12 Bastien F. Grosso , Nicola A. Spaldin

This paper analyzes how the ferroelectric properties of cubic-like BiFeO$_3$ nanoparticles are affected by different terminations and charge distributions at the surface using ab-initio-based atomistic computational experiments. Our…

Materials Science · Physics 2025-01-03 Mauro A. P. Goncalves , Monica Graf , Marek Pasciak , Jiri Hlinka

The results of fabrication and characterization of atomic structure of nanocrystalline thin layers of Y2O3 in cubic and monoclinic phases is reported. Experimental data demonstrate crystalline ordering in nanocrystalline films with average…

Materials Science · Physics 2022-12-28 D. W. Boukhvalov , D. A. Zatsepin , Yu. A. Kuznetsova , N. V. Gavrilov , A. F. Zatsepin