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Group-V elemental monolayers including phosphorene are emerging as promising 2D materials with semiconducting electronic properties. Here, we present the results of first principles calculations on stability, mechanical and electronic…

Computational Physics · Physics 2015-05-12 Gaoxue Wang , Ravindra Pandey , Shashi P. Karna

Bismuth antimony alloys (Bi$_x$Sb$_{1-x}$) provide a tuneable materials platform to study topological transport and spin-polarized surface states resulting from the nontrivial bulk electronic structure. In the two-dimensional limit, it is a…

Prediction and characterization of crystal structures of alloys are a key problem in materials research. Using high-throughput ab initio calculations we explore the low-temperature phase diagrams for the following systems: {Bi-In, Bi-Mg,…

Materials Science · Physics 2007-05-23 Stefano Curtarolo , Aleksey N. Kolmogorov , Franklin Hadley Cocks

Structural, thermal, resistive and magnetic properties of melt quenched Bi 0.88 Sb 0.12 alloys are reported. The samples are heated at three different temperatures, followed by rapid quenching in liquid nitrogen. Large temperature…

Materials Science · Physics 2015-12-21 K. Malik , Diptasikha Das , S. K. Neogi , A. K. Deb , Arup Dasgupta , S. Bandyopadhyay , Aritra Banerjee

This study presents a first principles investigation of the structural, thermodynamic, electronic, optical and thermoelectric properties of aluminum antimonide (AlSb) in its cubic (F-43m) and hexagonal (P63mc) phases. Both structures are…

Many promising building blocks of future electronic technology - including non-stoichiometric compounds, strongly correlated oxides, and strained or patterned films - are inhomogeneous on the nanometer length scale. Exploiting the…

Mesoscale and Nanoscale Physics · Physics 2013-11-08 Anjan Soumyanarayanan , Michael M. Yee , Yang He , Hsin Lin , Dillon R. Gardner , Arun Bansil , Young S. Lee , Jennifer E. Hoffman

Bismuth has been shown to be topological in its different allotropes and compounds, with one of the most notable examples being the Bi-Sb alloy, the first 3D topological insulator ever discovered. In this paper we explore two-dimensional…

Disordered Systems and Neural Networks · Physics 2024-10-22 A. J. Uría-Álvarez , J. J. Palacios

Anion substitution with bismuth (Bi) in III-V semiconductors is an effective method for experimental engineering of the band gap Eg at low Bi concentrations, in particular in gallium arsenide (GaAs). The inverse Bi-concentration dependence…

Pristine Antimony tungstate nanoparticles prepared via a simple hydrothermal process showcase interesting photocatalytic efficiency, degrading Methylene Blue (MB) completely in 180 min under visible light. In this study, the impact on…

A systematic theoretical study of two PbTe-based ternary alloys, Pb1-xCdxTe and Pb1-xMnxTe, is reported. First, using ab initio methods we study the stability of the crystal structure of CdTe - PbTe solid solutions, to predict the…

Materials Science · Physics 2013-05-30 Malgorzata Bukala , Piotr Sankowski , Ryszard Buczko , Perla Kacman

Antimony (Sb), an element with strong spin-orbit coupling, is predicted to undergo a topological phase transition from a topological semimetal to a topological insulator as its dimensionality approaches the two-dimensional limit, driven by…

In the present work, we report the synthesis of Pb-Bi alloy with enhanced Tc of up to 9K, which is higher than that of Pb. The alloy is synthesized via a solid-state reaction route in the vacuum-encapsulated quartz tube at 7000C in an…

Superconductivity · Physics 2024-07-02 N. K. Karn , Kapil Kumar , Naveen Kumar , Yogesh Kumar , M. M. Sharma , Jin Hu , V. P. S. Awana

Incorporation of bismuth (Bi) in dilute quantities in (In)GaAs has been shown to lead to unique electronic properties that can in principle be exploited for the design of high efficiency telecomm lasers. This motivates the development of…

Materials Science · Physics 2013-09-16 Christopher A. Broderick , Muhammad Usman , Eoin P. O'Reilly

The semimetal antimony (Sb) element doped into hydrogen has been performed theoretically to explored high-pressure crystal structure and superconductivity of antimony hydrides. The unexpected stoichiometry $\textrm{SbH}_\textrm{4}$ with…

Superconductivity · Physics 2015-06-24 Yanbin Ma , Defang Duan , Da Li , Yunxian Liu , Fubo Tian , Xiaoli Huang , Zhonglong Zhao , Hongyu Yu , Bingbing Liu , Tian Cui

Dilute concentrations of antimony (Sb) incorporation into GaN induce strong band-gap bowing and tunable room-temperature photoluminescence from the UV to the green spectral regions. However, the atomistic details of the incorporation of Sb…

Materials Science · Physics 2024-10-02 Yujie Liu , Ishtiaque Ahmed Navid , Zetian Mi , Emmanouil Kioupakis

Amorphous silicon materials and its alloys become extensively used in some technical applications involving large area of the microelectronic and optoelectronic devices. However, the amorphous-crystalline transition, segregation and…

Materials Science · Physics 2009-02-13 A. Csik , G. A. Langer , G. Erdelyi , D. L. Beke , Z. Erdelyi , K. Vad

Ba2ScSbO6 (BSS) has been synthesized in polycrystalline form by solid state reaction. Structural characterization of the compound was done through X-ray diffraction (XRD) followed by Riedvelt analysis of the XRD pattern. The crystal…

Materials Science · Physics 2016-06-22 Rajyavardhan Ray , A K Himanshu , Uday Kumar , Pintu Sen , J. Lahiri , S K Bandyopadhyay , T. P. Sinha

We develop an atomistic, nearest-neighbor sp3s* tight-binding Hamiltonian to investigate the electronic structure of dilute bismide alloys of GaP and GaAs. Using this model we calculate that the incorporation of dilute concentrations of Bi…

Materials Science · Physics 2011-12-12 Muhammad Usman , Christopher A. Broderick , Andrew Lindsay , Eoin P. O'Reilly

We report the discovery of superconductivity in binary alloy Sn$_{1-x}$Sb$_{x}$ with $x$ in the range of 0.43 to 0.6, which possesses a modulated rhombohedral structure due to the incommensurate ordering of Sn and Sb layers along the…

For a wide class of technologically relevant compound III-V and II-VI semiconductor materials AC and BC mixed crystals (alloys) of the type A(x)B(1-x)C can be realized. As the electronic properties like the bulk band gap vary continuously…

Materials Science · Physics 2015-06-03 Daniel Mourad , Gerd Czycholl