Related papers: Hyper-aging Dynamics of Nano-clay Suspension
We report Brownian dynamics simulation of the out-of-equilibrium dynamics (aging) in a colloidal suspension composed of rigid charged disks, one possible model for Laponite, a synthetic clay deeply investigated in the last few years by…
We study the rotational diffusion of aging Laponite suspensions for a wide range of concentrations using depolarized dynamic light scattering. The measured orientational correlation functions undergo an ergodic to non-ergodic transition…
Dilute Laponite suspensions in water at low salt concentration form repulsive colloidal glasses which display physical aging. This phenomenon is still not completely understood and in particular, little is known about the connection between…
Cellulose nanocrystals (CNCs) are rodlike biosourced colloidal particles used as key building blocks in a growing number of materials with innovative mechanical or optical properties. While CNCs form stable suspensions at low volume…
The settling dynamics of falling spheres inside a Laponite suspension is studied. Laponite is a colloidal synthetic clay that shows physical aging in aqueous suspension due to the spontaneous evolution of inter-particle electrostatic…
Hypothesis: Aging in colloidal suspensions manifests as a reduction in kinetic freedom of the colloids. In aqueous suspensions of charged colloids, the role of inter-particle electrostatics interactions on the aging dynamics is well…
The aging dynamics of a colloidal glass has been studied by multiangle Dynamic Light Scattering, Neutron Spin Echo, X-ray Photon Correlation Spectroscopy and Molecular Dynamics simulations. The two relaxation processes, microscopic (fast)…
Soft glassy materials are out of thermodynamic equilibrium and show time dependent slowing down of the relaxation dynamics. Under such situation these materials follow Boltzmann superposition principle only in the effective time domain,…
Many dense magnetic nanoparticle systems exhibit slow dynamics which is qualitatively indistinguishable from that observed in atomic spin glasses and its origin is attributed to dipole interactions among particle moments (or superspins).…
We report on zero field cooled magnetization relaxation experiments on a concen- trated frozen ferrofluid exhibiting a low temperature superspin glass transition. With a method initially developed for spin glasses, we investigate the field…
We employ small-angle X-ray and dynamic light scattering to investigate the microscopic structure and dynamics of dense suspensions of ultra-low crosslinked (ULC) poly(N-isopropylacrylamide) (PNIPAM) microgels. By probing the supercooled…
In this work the ageing dynamics of soft solids of aqueous suspension of laponite has been investigated under the oscillatory stress field. We observed that at small stresses elastic and viscous moduli showed a steady rise with the elastic…
Evolution of the energy landscape during physical aging of glassy materials can be understood from the frequency and strain dependence of the shear modulus but the non-stationary nature of these systems frustrates investigation of their…
Aging in an attraction-driven colloidal glass is studied by computer simulations. The system is equilibrated without attraction and instantaneously ``quenched'', at constant colloid volume fraction, to one of two states beyond the glass…
Slow relaxation occurs in many physical and biological systems. `Creep' is an example from everyday life: when stretching a rubber band, for example, the recovery to its equilibrium length is not, as one might think, exponential: the…
The microscopic dynamics of spontaneously aged and rejuvenated glassy Laponite is investigated through X-ray photon correlation spectroscopy. Two different behaviours of the intensity autocorrelation functions are observed depending on the…
We employ parallel superposition rheology to study the dynamics of an aging colloidal glass in the presence of a mean field stress. Over a range of intermediate stresses, the loss modulus exceeds the storage modulus at short times but…
We study the effect of physical aging on the mechanical properties of a model polymer glass using molecular dynamics simulations. The creep compliance is determined simultaneously with the structural relaxation under a constant uniaxial…
Clay, the major ingredient of natural soils, is often used as a rheological modifier while formulating paints and coatings. When subjected to desiccation, colloidal clay suspensions and clayey soils crack due to the accumulation of…
Colloidal gels gradually evolve as their structures reorganize, a process known as aging. Understanding this behavior is essential for fundamental science and practical applications such as drug delivery and tissue engineering. This study…