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We have investigated the structural sequence of the high-pressure phases of silicon and germanium. We have focussed on the cd->beta-tin->Imma->sh phase transitions. We have used the plane-wave pseudopotential approach to the…

Materials Science · Physics 2009-11-10 Katalin Gaal-Nagy , Pasquale Pavone , Dieter Strauch

The superconducting high-entropy alloys (HEAs) recently attract considerable attention due to their exciting properties, such as the robustness of superconductivity against atomic disorder and extremely high-pressure. The well-studied…

Superconductivity · Physics 2021-07-21 Yuta Harayama , Jiro Kitagawa

Three dimensional topological Dirac semi-metals represent a novel state of quantum matter with exotic electronic properties, in which a pair of Dirac points with the linear dispersion along all momentum directions exist in the bulk. Herein,…

Materials Science · Physics 2016-07-06 Wendong Cao , Peizhe Tang , Shou-Cheng Zhang , Wenhui Duan , Angel Rubio

It is shown that the superconducting intermetallic compound MgB2 possesses a narrow, partly filled "superconducting band" with Wannier functions of special symmetry in its band structure. This result corroborates previous observations about…

Superconductivity · Physics 2011-03-03 Ekkehard Krüger

Based on a previously proposed thermodynamic analysis, we study the relative stabilities of five Si phases under uniaxial compression using ab initio methods. The five phases are diamond, beta-tin, sh, sc, and hcp structures. The possible…

Materials Science · Physics 2009-11-07 C. Cheng

While achieving high Curie temperatures (above room temperature) in diluted magnetic semiconductors remains a challenge in the case of well controlled homogeneous alloys, several systems characterized by a strongly inhomogeneous…

Crystal structures of $\textrm{CLi}_4$ compounds are explored through \emph{ab} \emph{initio} evolutionary methodology. Phase transition from metal to semimetal and semiconductor, and eventually to insulator with increasing pressure are…

Materials Science · Physics 2016-04-27 Xilian Jin , Xiao-Jia Chen , Huadi Zhang , Quan Zhuang , Kuo Bao , Dawei Zhou , Qiang Zhou , Zhi He , Bingbing Liu , Tian Cui

LiB, a predicted layered compound analogous to the MgB$_2$ superconductor, has been recently synthesized via cold compression and quenched to ambient pressure, yet its superconducting properties have not been measured. According to prior…

$\alpha$-(BEDT-TTF)$_2$I$_3$ is a prominent example of charge ordering among organic conductors. In this work we explore the details of transport within the charge-ordered as well as semimetallic phase at ambient pressure. In the…

The compressed hydrogen-rich compounds have received extensive attention as promising candidates for room temperature superconductivity, however, the high pressure required to stabilize such materials hinders their wide practical…

Superconductivity · Physics 2023-11-14 Wendi Zhao , Defang Duan , Decheng An , Qiwen Jiang , Zhengtao Liu , Tiancheng Ma , Zihao Huo , Jianhui Du , Tian Cui

A metastable phase of NbN with superconducting Tc=16.4 K was reported recently by Treece and collaborators. The reported structure of the thin film sample deviates from the rocksalt (B1) NbN structure with 25% ordered vacancies on each…

mtrl-th · Physics 2009-10-28 E. C. Ethridge , S. C. Erwin , W. E. Pickett

Fine grained polycrystalline samples of MgB(2) superconductor were synthesized from the elements to contain < 5 % of impurity phases, according to X-ray powder diffractometry. The superconductive transition was sharp with a midpoint Tc =…

Superconductivity · Physics 2007-05-23 J. R. Thompson , M. Paranthaman , D. K. Christen , K. D. Sorge , H. J. Kim , J. G. Ossandon

Density-functional-theory (DFT) calculations have been performed on the Li-Si and Li-Ge systems. Lithiated Si and Ge, including their metastable phases, play an important technological r\^ole as Li-ion battery (LIB) anodes. The calculations…

Materials Science · Physics 2015-06-18 Andrew J. Morris , C. P. Grey , C. J Pickard

Germanium-Tin is emerging as a material exhibiting excellent photonic properties. Here we demonstrate optical initialization and readout of spins in this intriguing group IV semiconductor alloy and report on spin quantum beats between…

We investigate the superconducting ternary lithium borohydride phase diagram at pressures of 0 and 200$\,$GPa using methods for evolutionary crystal structure prediction and linear-response calculations for the electron-phonon coupling. Our…

Superconductivity · Physics 2017-12-20 Christian Kokail , Lilia Boeri , Wolfgang von der Linden

The extensive applications of cubic silicon in flexible transistors and infrared detectors are much hindered by its intrinsic properties. Metastable silicon phases, such as Si-III, IV and XII prepared using extreme pressure method, provide…

Materials Science · Physics 2025-03-07 Yubing Du , Guoshuai Du , Zhixi Zhu , Jiaohui Yan , Jiayin Li , Tiansong Zhang , Lina Yang , Ke Jin , Yabin Chen

A dirty BCS superconductor with magnetic impurities is studied. Asymptotic solution of the thermodynamics of such superconductor with spin $1/2$ and $7/2$ magnetic impurities, is found. To this end, the system's free energy $f(H, \beta)$ is…

Superconductivity · Physics 2015-05-19 Dawid Borycki , Jan Maćkowiak

Search for new high-temperature superconductors and insight into their superconducting mechanism are of fundamental importance in condensed matter physics. The discovery of near-room temperature superconductivity at more than a million…

Mn-based transition metal Zintl compounds in the 14-1-11 phase are known to host complex atomic and magnetic structures owing to their intricate crystal structure. Among them, Ba14MnBi11 stands out as one of the least understood compounds,…

Materials Science · Physics 2024-07-24 Po-Hao Chang , Igor I. Mazin

We did extensive research for the typical nanolaminate Mn+1AXn (n=1, 2, 3) ceramics focusing on the structural stability, the phase transition pressure of Ti2GaN (160 GPa) is far higher than that of Zr2GaN (92 GPa), meaning the strong M…

Materials Science · Physics 2020-12-23 Ben-Yang Li , Fang Chen , Heng-Na Xiong , Ling Tang , Ju-Xiang Shao , Ze-Jin Yang
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