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We present a theoretical model of the "isostructural" \gamma-\alpha phase transition in Ce which is based on quadrupolar interactions due to coupled charge density fluctuations of 4f electrons and of conduction electrons. Conduction…

Strongly Correlated Electrons · Physics 2009-10-31 A. V. Nikolaev , K. H. Michel

As a possible mechanism of the $\gamma-\alpha$ phase transition in pristine cerium a change of the electronic density from a disordered state with symmetry Fm-3m to an ordered state Pa-3 has been proposed. Here we include on-site and inter-…

Strongly Correlated Electrons · Physics 2009-11-07 A. V. Nikolaev , K. H. Michel

Lattice effects in a cerium based clathrate compound Ce_3Pd_20Ge_6 with a cubic Cr_23C_6-type structure have been investigated by ultrasonic and thermal expansion measurements. Elastic softenings of (C_11-C_12)/2 and C_44 proportional to…

An elastic anomaly, observed in the heavy Fermi liquid state of Ce alloys (for example, CeCu_6 and CeTe), is analyzed by using the infinite-U Anderson lattice model. Four atomic energy levels are assumed for f-electrons. Two of them are…

Condensed Matter · Physics 2007-05-23 Kikuo Harigaya , G. A. Gehring

Using a small amount of radioactive 111Cd atoms implanted in cerium lattice to probe the hyperfine electric quadrupole interaction, we have detected a quadrupole electron charge density component in alpha-Ce, which is absent in gamma-Ce.…

We report on the most complete investigation to date of the 4f-electron properties at the gamma-alpha transition in elemental Ce by resonant inelastic x-ray scattering (RIXS). The Ce 2p3d-RIXS spectra were measured directly in the bulk…

Strongly Correlated Electrons · Physics 2016-08-16 Jean-Pascal Rueff , Jean-Paul Itié , M. Taguchi , C. F. Hague , J. -M. Mariot , R. Delaunay , J. -P. Kappler , N. Jaouen

The element Ce exhibits an isostructural $\gamma-\alpha$ phase transition with a 15\% volume change at room temperature. The phase boundary ends in a critical point at 1.5 GPa and 480 K. We describe a model for the equation of state of Ce…

Materials Science · Physics 2018-08-01 C. W. Greeff , S. D. Crockett , K. G. Honnell

The temperature and pressure dependence of the thermal displacements and lattice parameters were obtained across the $\gamma \to \alpha$ phase transition of Ce using high-pressure, high-resolution neutron and synchrotron x-ray powder…

Strongly Correlated Electrons · Physics 2009-11-10 I. -K. Jeong , T. W. Darling , M. J. Graf , Th. Proffen , R. H. Heffner , Yongjae Lee , T. Vogt , J. D. Jorgensen

The elastic anomaly observed in the coherent Kondo state of Ce heavy fermion compounds is analyzed by using the Anderson lattice model simulating the energy level scheme of CeTe. The $\Gamma_7$ doublets and $\Gamma_8$ quartets of the 4f…

Condensed Matter · Physics 2007-05-23 Kikuo Harigaya , G. A. Gehring

A typical f-electron Kondo lattice system Ce exhibits the well-known isostructural transition, the so-called gamma-alpha transition, accompanied by an enormous volume collapse. Most interestingly, we have discovered that a topological-phase…

Strongly Correlated Electrons · Physics 2019-12-04 Junwon Kim , Dongchoon Ryu , Chang-Jong Kang , Kyoo Kim , Hongchul Choi , T. -S. Nam , B. I. Min

Under pressure cesium undergoes a transition from a high-pressure fcc phase (Cs-II) to a collapsed fcc phase (Cs-III) near 4.2GPa. At 4.4GPa there follows a transition to the tetragonal Cs-IV phase. In order to investigate the lattice…

Materials Science · Physics 2009-10-31 Y. Kong , O. Jepsen

The alkali-doped fulleride Cs$_{3}$C$_{60}$, crystallized in the space group Fm$\overline 3$m or Pm$\overline 3$n, exhibits unconventional $s$-wave superconductivity under pressure with a maximum $T_c\sim 38$ K. Recently, a new…

Superconductivity · Physics 2024-03-08 Changming Yue , Yusuke Nomura , Kosmas Prassides , Philipp Werner

An elastic anomaly, observed in the heavy fermi liquid state of Ce alloys (for example, CeCu$_6$ and CeTe), is analyzed by using the infinite-$U$ Anderson lattice model. The four atomic energy levels are assumed for f-electrons. Two of them…

High Energy Physics - Lattice · Physics 2007-05-23 Kikuo Harigaya , G. A. Gehring

An elastic anomaly, observed in the heavy fermi liquid state of Ce alloys (for example, CeCu$_6$ and CeTe), is analyzed by using the infinite-$U$ Anderson lattice model. The four atomic energy levels are assumed for f-electrons. Two of them…

Condensed Matter · Physics 2007-05-23 Kikuo Harigaya , G. A. Gehring

In the present paper we generalised a phenomenological model developed in \cite{gomo:2005} for the description of magnetostructural phase transitions and related peculiarities of elastic properties in solid oxygen under high pressure and/or…

Materials Science · Physics 2007-05-23 H. V. Gomonay , V. M. Loktev

We investigate a novel higher-order topological behavior in elastic lattices characterized by nonsymmorphic symmetries. In the theoretical spring-mass lattice, altering the vertex mass allows for fine-tuning of the topological features…

Applied Physics · Physics 2024-12-18 Yijie Liu , Yuyang Chen , Zhaoyang Guo , Zhi-Kang Lin , Di Zhou , Feng Li , Ying Wu

We report an ultrasonic investigation of the elastic moduli on a single crystal of hexagonal YMnO_3 as a function of temperature. Stiffening anomalies in the antiferromagnetic N\'eel state below T_N = 72.4 K are observed on all the four…

Strongly Correlated Electrons · Physics 2007-08-07 Mario Poirier , Francis Laliberte , Loreynne Pinsard , Alexandre Revcolevschi

The prototypical phase change material GeTe shows an enigmatic phase transition at Tc ca. 650 K from rhombohedral (R3m) to cubic (Fm-3m) symmetry. While local probes see little change in bonding, in contrast, average structure probes imply…

Materials Science · Physics 2015-07-01 Jessica M. Hudspeth , Tapan Chatterji , Simon J. L. Billinge , Simon A. J. Kimber

The size-dependent phase stability of gamma-Al2O3 was studied by large-scale molecular dynamics simulations over a wide temperature range from 300 to 900 K. For the gamma-Al2O3 crystal, a bulk transformation to alpha-Al2O3 by an FCC-to-HCP…

The elastic properties of a filled skutterudite PrOs_4Sb_{12} with a heavy Fermion superconductivity at T_C=1.85 K have been investigated. The elastic softening of (C_{11}-C_{12})/2 and C_{44} with lowering temperature down to T_C indicates…

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