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Fragmentation branching ratios of electronically excited molecular species are of first importance for the modeling of gas phase interstellar chemistry. Despite experimental and theoretical efforts that have been done during the last two…

We modelled \HH\ and CO formation incorporating the fractionation and selective photodissociation affecting CO when \AV\ $\la2$mag. UV absorption measurements typically have N(\cotw)/N(\coth) $\approx 65$ that are reproduced with the…

Astrophysics of Galaxies · Physics 2017-02-01 Harvey S. Liszt

Absolute photodetachment cross sections of two anions of astrophysical importance CN- and C3N- were measured to be (1.18 +- (0.03)_stat (0.17)_sys) * 10^-17 cm^2 and (1.43 +- (0.14)_stat (0.37)_sys) * 10^-17 cm^2 respectively at the…

Solar and Stellar Astrophysics · Physics 2015-06-16 S. S. Kumar , D. Hauser , R. Jindra , T. Best , S. Roucka , W. D. Geppert , T. J. Millar , R. Wester

The optical and electronic properties of 2D semiconductors are intrinsically linked via the strong interactions between optically excited bound species and free carriers. Here we use near-field scanning microwave microscopy (SMM) to image…

Aims. Following the recent detection of 36ArH+ in the Crab nebula spectrum, we have computed the photodissociation rate of ArH+ in order to constrain the physical processes at work in this environment. Methods. Photodissociation cross…

Astrophysics of Galaxies · Physics 2016-11-02 E. Roueff , A. B. Alekseyev , J. Le Bourlot

Two-dimensional (2D) layered metal dichalcogenides constitute a promising class of materials for photodetector applications due to their excellent optoelectronic properties. The most common photodetectors, which work on the principle of…

The multiphoton ionization rate of molecules depends on the alignment of the molecular axis with respect to the ionizing laser polarization. By studying molecular frame photo-electron angular distributions from N$_2$, O$_2$ and benzene, we…

Chemical Physics · Physics 2015-06-15 C T L Smeenk , L Arissian , A V Sokolov , M Spanner , K F Lee , A Staudte , D M Villeneuve , P B Corkum

The interaction of polycyclic aromatic hydrocarbons (PAHs) with vacuum ultraviolet (VUV) photons triggers the emission of the well-known aromatic infrared bands (AIBs) but other mechanisms such as fragmentation can be involved in this…

Astrophysics of Galaxies · Physics 2021-08-12 Alexandre Marciniak , Christine Joblin , Giacomo Mulas , Venkat Rao Mundlapati , Anthony Bonnamy

The presence of methyl alcohol or methanol (CH$_3$OH) in several astrophysical environments has been characterized by its high abundance that depends on both the production rate and the destruction rate. In the present work, the…

Astrophysics · Physics 2008-11-26 S. Pilling , R. Neves , A. C. F. Santos , H. M. Boechat-Roberty

Photoisomerization, i.e., a change of molecular structure after absorption of a photon, is one of the most fundamental photochemical processes. It can perform desirable functionality, e.g., as the primary photochemical event in human…

Mesoscale and Nanoscale Physics · Physics 2017-01-10 Javier Galego , Francisco J. Garcia-Vidal , Johannes Feist

Aims: For the first time we investigate the role of the grain surface chemistry in the Horsehead Photo-dissociation region (PDR). Methods: We performed deep observations of several H2CO rotational lines toward the PDR and its associated…

Astrophysics of Galaxies · Physics 2015-05-30 V. Guzmán , J. Pety , J. R. Goicoechea , M. Gerin , E. Roueff

The influence of strong internal forces on photon-assisted scattering and on the displacement mechanism of magnetoconductivity oscillations in a two-dimensional (2D) electron gas is theoretically studied. The theory is applied to the highly…

Mesoscale and Nanoscale Physics · Physics 2015-05-25 Yuriy P. Monarkha

Recently, "photovoltaic photographs" were proposed as a creative application of photovoltaic technologies, relevant in fields such as architecture or the automotive industry. In this application an image is created by light-induced…

Quantum interference between multiple pathways in molecular photodissociation often results in angular momentum polarization of atomic products and this can give deep insight into fundamental physical processes. For dissociation of diatomic…

Chemical Physics · Physics 2022-04-26 Chaya Weeraratna , Arthur G. Suits , Oleg S. Vasyutinskii

The mid-infrared (MIR) spectra of dense photodissociation regions (PDRs) are typically dominated by emission from polycyclic aromatic hydrocarbons (PAHs) and the lowest pure rotational states of molecular hydrogen (H2); two species which…

Astrophysics of Galaxies · Physics 2011-02-09 Brian T. Fleming , Kevin France , Roxana E. Lupu , Stephan R. McCandliss

Oxygen is the most abundant element on the Sun after Hydrogen and Helium. The intensity spectrum of resonance lines of neutral Oxygen namely O {\sc i} (1302, 1305 and 1306 \AA\,) has been studied in the literature for chromospheric…

Solar and Stellar Astrophysics · Physics 2015-06-22 L. S. Anusha , K. N. Nagendra , H. Uitenbroek

Emitted photons stemming from the radiative recombination of electron-hole pairs carry chemical potential in radiative energy converters. This luminescent effect can substantially alter the local net photogeneration in near-field…

Study of the near-UV photodissociation dynamics for monolayer (ML) quantities of CH$_3$I on thin films of a series of fluorobenzenes and benzene (1--25ML) grown on a Cu(100) substrate finds that in addition to gas-phase-like neutral…

Chemical Physics · Physics 2024-03-20 E. T. Jensen

A two dimensional hydrochemical hybrid code, KM2, is constructed to deal with astrophysical problems that would require coupled hydrodynamical and chemical evolution. The code assumes axisymmetry in cylindrical coordinate system, and…

Instrumentation and Methods for Astrophysics · Physics 2015-08-06 Kazutaka Motoyama , Oscar Morata , Hsien Shang , Ruben Krasnopolsky , Tatsuhiko Hasegawa

Hybrid photonic nanostructures allow the engineering of novel interesting states of light. One recent example is topological photonic crystals where a nontrivial Berry phase of the photonic band structure gives rise to topologically…

Quantum Physics · Physics 2014-12-17 Matouš Ringel , Mikhail Pletyukhov , Vladimir Gritsev