Related papers: The different paths to entropy
Entropy concept was introduced by Clausius 160 years ago, and has been continually enriched, developed and interpreted by the researchers in many different scientific disciplines ever since. Thermodynamics and other scientific disciplines…
In this document we are interested in entropy. Entropy is multiple, the idea is to describe the definition proposed by the physicist Clausius. Indeed, Clausius exposes in 1865 the second principle of thermodynamics and also proposes the…
Even today, the concept of entropy is perceived by many as quite obscure. The main difficulty is analyzed as being fundamentally due to the subjectivity and anthropocentrism of the concept that prevent us to have a sufficient distance to…
The principal methods for the definition of thermodynamic entropy are discussed with special reference to those developed by Carath\'eodory, the Keenan School, Lieb and Yngvason, and the present authors. An improvement of the latter method…
The second half of this essay tells the story of the genesis and early development of the notion of black hole entropy, in the style of an after dinner talk (apart from a long technical footnote). The first half sketches the development of…
Entropy is a quantity which is of great importance in physics and chemistry. The concept comes out of thermodynamics, proposed by Rudolf Clausius in his analysis of Carnot cycle and linked by Ludwig Boltzmann to the number of specific ways…
Entropy is arguably one of the most powerful concepts to understand the world, from the behavior of molecules to the expansion of the universe, from how life emerges to how hybrid complex systems like cities come into being and continue…
Some general considerations on the notion of entropy in physics are presented. An attempt is made to clarify the question of the differentiation between physical entropy (the Clausius-Boltzmann one) and quantities called entropies…
This pedagogical comment highlights three misconceptions concerning the usefulness of the concept of negative temperature; being derived from the usual, often termed Boltzmann, definition of entropy. First, both the Boltzmann and Gibbs…
Boltzmann's struggle with a derivation of the Second Law of Thermodynamics is sketched. So is his first derivation of the connection between entropy and probability in 1877. Planck's derivation and quantum mechanical modifications of…
Thermodynamic entropy is determined by a heat measurement through the Clausius equality. The entropy then formalizes a fundamental limitation of operations by the second law of thermodynamics. The entropy is also expressed as the Shannon…
Entropy is a very useful concept from physics that tries to explain how a system behaves from a point of view of the thermodynamics. However, there are two ways to explain entropy, and it depends on if we are studying a microsystem or a…
In this article a definition of reversible processes in terms of differences in intensive Thermodynamics properties (Affinities) is proposed. This definition makes it possible to both define reversible processes before introducing the…
The Boltzmann and Gibbs approaches to statistical mechanics have very different definitions of equilibrium and entropy. The problems associated with this are discussed and it is suggested that they can be resolved, to produce a version of…
For a dynamical system far from equilibrium, one has to deal with empirical probabilities defined through time-averages, and the main problem is then how to formulate an appropriate statistical thermodynamics. The common answer is that the…
The science of thermodynamics was put together in the Nineteenth Century to describe large systems in equilibrium. One part of thermodynamics defines entropy for equilibrium systems and demands an ever-increasing entropy for non-equilibrium…
This paper is an introduction to the von Neumann entropy in a historic approach. Von Neumann's gedanken experiment is repeated, which led him to the formula of thermodynamic entropy of a statistical operator. In the analysis of his ideas we…
There are three ways to conceptualize entropy: entropy as an extensive thermodynamic quantity of physical systems (Clausius, Boltzmann, Gibbs), entropy as a measure for information production of ergodic sources (Shannon), and entropy as a…
The notion of group entropy is proposed. It enables to unify and generalize many different definitions of entropy known in the literature, as those of Boltzmann-Gibbs, Tsallis, Abe and Kaniadakis. Other new entropic functionals are…
I will argue, pace a great many of my contemporaries, that there's something right about Boltzmann's attempt to ground the second law of thermodynamics in a suitably amended deterministic time-reversal invariant classical dynamics, and that…