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The mechanical properties of polymer knots under stretching in a bad or good solvent are investigated by applying a given force $F$ to a point of the knot while keeping another point fixed. The Monte Carlo sampling of the polymer…

Soft Condensed Matter · Physics 2015-12-15 Yani Zhao , Franco Ferrari

In the first part of this work a summary is provided of some recent experiments and theoretical results which are relevant in the research of systems of polymer rings in nontrivial topological conformations. Next, some advances in modeling…

Soft Condensed Matter · Physics 2014-02-04 Yani Zhao , Franco Ferrari

In this work the thermodynamic properties of short polymer knots (up to 120 segments) defined on a simple cubic lattice are studied with the help of the Wang-Landau Monte Carlo algorithm. The sampling process is performed using pivot…

Soft Condensed Matter · Physics 2015-06-16 Yani Zhao , Franco Ferrari

We investigate the thermal and structural properties of knotted diblock copolymer rings using a coarse-grained lattice model in an implicit solvent. The system is studied by means of the Wang--Landau Monte Carlo algorithm, allowing us to…

Soft Condensed Matter · Physics 2026-05-18 Neda Abbasi Taklimi , Franco Ferrari , Marcin R. Piątek , Luca Tubiana

The thermal properties of coarse grained knotted polymers containing two kinds of monomers $A$ and $B$ fluctuating in a solution are investigated on a simple cubic lattice using the Wang-Landau MC algorithm. These knots have a more complex…

Soft Condensed Matter · Physics 2022-09-07 Neda Abbasi Taklimi , Franco Ferrari , Marcin Radosław Piątek , Luca Tubiana

The statistical mechanics of single polymer knots is studied using Monte Carlo simulations. The polymers are considered on a cubic lattice and their conformations are randomly changed with the help of pivot transformations. After each…

Soft Condensed Matter · Physics 2015-06-12 Yani Zhao , Franco Ferrari

The statistical mechanics of a long knotted collapsed polymer is determined by a free-energy with a knot-dependent subleading term, which is linked to the length of the shortest polymer that can hold such knot. The only other parameter…

Statistical Mechanics · Physics 2014-12-01 Marco Baiesi , Enzo Orlandini , Attilio L. Stella

A coarse-grained computational model is used to investigate how the bending rigidity of a polymer under tension affects the formation of a trefoil knot. Thermodynamic integration techniques are applied to demonstrate that the free-energy…

Soft Condensed Matter · Physics 2012-11-13 Richard Matthews , Ard A. Louis , Christos N. Likos

The effect of topology on the collapse transition and instantaneous shape of an energy polydisperse polymer (a model heteropolymer) is studied by means of computer simulations. In particular, we consider three different chain topology,…

Soft Condensed Matter · Physics 2022-11-24 Thoudam Vilip Singh , Lenin S. Shagolsem

We use computer simulations to compare the dynamical behaviour of torus and even-twist knots in polymers under tension. The knots diffuse through a mechanism similar to reptation. Their friction coefficients grow linearly with average knot…

Soft Condensed Matter · Physics 2010-07-27 R. Matthews , A. A. Louis , J. M. Yeomans

Many experiments have been done to determine the relative strength of different knots, and these show that the break in a knotted rope almost invariably occurs at a point just outside the `entrance' to the knot. The influence of knots on…

Materials Science · Physics 2009-10-31 A. Marco Saitta , Paul D. Soper , E. Wasserman , Michael L. Klein

The interplay of topological constraints and Coulomb interactions in static and dynamic properties of charged polymers is investigated by numerical simulations and scaling arguments. In the absence of screening, the long-range interaction…

Statistical Mechanics · Physics 2009-11-07 Paul G. Dommersnes , Yacov Kantor , Mehran Kardar

For several decades, experimental and computational studies have been used to investigate the potential functional role of knots in protein structures. A property that has attracted considerable attention is thermal stability, i.e., the…

Biomolecules · Quantitative Biology 2026-03-13 João N. C. Especial , Beatriz P. Teixeira , Ana Nunes , Miguel Machuqueiro , Patrícia F. N. Faísca

The effects of entanglement in solutions and melts of unknotted ring polymers have been addressed by several theoretical and numerical studies. The system properties have been typically profiled as a function of ring contour length at fixed…

Soft Condensed Matter · Physics 2011-11-29 Angelo Rosa , Enzo Orlandini , Luca Tubiana , Cristian Micheletti

The effect of chain topology on the statics and dynamics of chain at the interface of two immiscible fluids is studied by means of molecular dynamics simulations. For three topologically different chains, namely, linear, ring, and…

Soft Condensed Matter · Physics 2024-08-01 Jenis Thongam , Lenin S. Shagolsem

Knotted proteins embed a physical (i.e., open) knot within their native structures. For decades, significant effort has been devoted to elucidating the functional role of knots in proteins, yet no consensus has been reached. Here, using…

Biomolecules · Quantitative Biology 2026-03-13 João NC Especial , Patrícia FN Faísca

An extensive study of single block copolymer knots containing two kinds of monomers $A$ and $B$ is presented. The knots are in a solution and their monomers are subjected to short range interactions that can be attractive or repulsive. In…

Soft Condensed Matter · Physics 2016-04-08 Franco Ferrari

A ring polymer in a confining space may exhibit at least two phases, namely an expanded (or solvent-rich phase) if its concentration is small, or a collapsed (or polymer-rich phase) when it is concentrated and compressed. These phases are…

Soft Condensed Matter · Physics 2026-03-24 EJ Janse van Rensburg , E Orlandini , MC Tesi

The interplay of topological constraints and persistence length of ring polymers in their own melt is investigated by means of dynamical Monte Carlo simulations of a three dimensional lattice model. We ask if the results are consistent with…

Statistical Mechanics · Physics 2009-10-31 M. Muller , J. P. Wittmer , M. E. Cates

Using a combination of the replica-exchange Monte Carlo algorithm and the multicanonical method, we investigate the influence of bending stiffness on the conformational phases of a bead-stick homopolymer model and present the pseudo-phase…

Soft Condensed Matter · Physics 2016-03-30 Martin Marenz , Wolfhard Janke
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