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Although the rutile structure of TiO$_2$ is stable at high temperatures, the conventional quasiharmonic approximation predicts that several acoustic phonons decrease anomalously to zero frequency with thermal expansion, incorrectly…

Materials Science · Physics 2015-08-19 Tian Lan , C. W. Li , O. Hellman , D. Kim , J. A. Muñoz , H. Smith , D. L. Abernathy , B. Fultz

Lithium transition metal phospho-olivines are useful electrode materials, owing to their stability, high safety, low cost and cyclability. We report phonon studies using neutron inelastic scattering experiments, ab-initio density functional…

Materials Science · Physics 2014-08-19 Prabhatasree Goel , M. K. Gupta , R. Mittal , S. Rols , S. J. Patwe , S. N. Achary , A. K. Tyagi , S. L. Chaplot

The orthovanadates are useful as host matrices for immobilization of radioactive wastes. The thermodynamic stability of these materials is crucial for their applications in high pressure and temperatures environment. It is necessary to…

Materials Science · Physics 2019-05-01 R. Mittal , M. K. Gupta , Baltej Singh , L. Pintschovius , Yu D. Zavartsev , S. L. Chaplot

A high order series expansion is employed to study the thermodynamical properties of a S=1/2 chain coupled to dispersionless phonons. The results are obtained without truncating the phonon subspace since the series expansion is performed…

Strongly Correlated Electrons · Physics 2007-05-23 Alexander Bühler , Götz S. Uhrig , Jaan Oitmaa

Terahertz and far-infrared electric and magnetic responses of hexagonal piezomagnetic YMnO3 single crystals are investigated. Antiferromagnetic resonance is observed in the spectra of magnetic permeability mu_a [H(omega) oriented within the…

Materials Science · Physics 2012-02-13 C. Kadlec , V. Goian , K. Z. Rushchanskii , P. Kuzel , M. Lezaic , K. Kohn , R. V. Pisarev , S. Kamba

We present new relations for calculation of phonon polaritons, plasmons and plasmon polaritons frequencies, which differ from the standard relations. So, we study the frequency of phonon polaritons in a two dimensional lattice with…

Materials Science · Physics 2014-10-01 Voicu Dolocan , Andrei Dolocan , Voicu Octavian Dolocan

Chalcogenide perovskites offer superior thermal and aqueous stability as well as a benign elemental composition compared to organic halide perovskites for optoelectronic applications. In this study, the structural, electrical, elastic,…

Materials Science · Physics 2023-05-26 M. D. Kassa , N. G. Debelo , M. M. Woldemariam

Extensive inelastic neutron scattering measurements of phonons on a single crystal of CaFe2As2 allowed us to establish a fairly complete picture of phonon dispersions in the main symmetry directions. The phonon spectra were also calculated…

Phonon dynamics, charge response and the phonon density of states are calculated for the high-temperature superconductors HgBa$_{2}$CuO$_{4}$ and Bi$_{2}$Sr$_{2}$CuO$_{6}$ within a microscopic model for the electronic density response. The…

Superconductivity · Physics 2010-02-08 Thomas Bauer , Claus Falter

We report inelastic neutron scattering measurements of the phonon spectra in a pure powder sample of the multiferroic material BiFeO3. A high-temperature range was covered to unravel the changes in the phonon dynamics across the Neel (T_N ~…

Materials Science · Physics 2015-03-19 M. Zbiri , H. Schober , N. Choudhury , R. Mittal , S. L. Chaplot , S. J. Patwe , S. N. Achary , A. K. Tyagi

Strongly interacting phonons and orbital excitations are observed in the same energy range for CuSb$_2$O$_6$, unlocking a so-far unexplored type of electron-phonon interaction. An orbital wave at $\sim 550$ cm$^{-1}$ softens on warming and…

Strongly Correlated Electrons · Physics 2018-05-17 D. T. Maimone , A. B. Christian , J. J. Neumeier , E. Granado

We study theoretically the effect of the effective dimensionality of the phonon gas distribution on the heat exchange between electrons and phonons in layered nanostructures. If we denote the electrons temperature by $T_e$ and the phonons…

Mesoscale and Nanoscale Physics · Physics 2019-09-04 Dragos-Victor Anghel , Claudiu Caraiani , Yuri M. Galperin

The elastic, thermodynamic, and electronic properties of fluorite RuO_2 under high pressure are investigated by plane-wave pseudopotential density functional theory. The optimized lattice parameters, elastic constants, bulk modulus, and…

Materials Science · Physics 2017-08-23 Z. J. Yang , A. M. Guo , Y. D. Guo , J. Li , Z. Wang , Q. Liu , R. F. Linghu , X. D. Yang

Phonon frequencies at Gamma-point in non-magnetic rhombohedral phase of LaCoO3 were calculated using density functional theory (DFT) with hybrid exchange correlation functional PBE0. The calculations involved a comparison of results for two…

Materials Science · Physics 2015-05-19 Denis Gryaznov , Robert A. Evarestov , Joachim Maier

Single crystals of a ternary relaxor ferroelectric system, 0.29Pb(In1/2Nb1/2)O3-0.45Pb(Mg1/3Nb2/3)O3-0.26PbTiO3, have been studied using triple-axis based elastic and inelastic neutron scattering. Elastic diffuse scattering confirms the…

Materials Science · Physics 2022-08-10 Qian Li , Sergey Danilkin , Guochu Deng , Jian Wang , Zhengrong Li. Ray L. Withers , Zhuo Xu , Yun Liu

We report a Raman study of the effect of temperature on the self-energies of optical phonons in a number of transition metals with hexagonal-close-packed structure. Anisotropic softening of phonon energies and narrowing of phonon linewidths…

Materials Science · Physics 2017-01-04 Yu. S. Ponosov , S. V. Streltsov

Hyperbolic phonon polaritons (HPhPs) in orthorhombic-phase molybdenum trioxide ($\alpha$-MoO3) show in-plane hyperbolicity, great wavelength compression and ultra-long lifetime, therefore holding great potential in nanophotonic…

Materials Science · Physics 2020-11-25 Weikang Dong , Ruishi Qi , Tiansheng Liu , Yi Li , Ning Li , Ze Hua , Zirui Gao , Shuyuan Zhang , Kaihui Liu , Jiandong Guo , Peng Gao

To investigate the pressure-induced structural transitions of chromium dioxide (CrO$_{2}$), phonon dispersions and total energy band structures are calculated as a function of pressure. The first structural transition has been confirmed at…

Materials Science · Physics 2012-05-17 Sooran Kim , Kyoo Kim , Chang-Jong Kang , B. I. Min

We report inelastic neutron scattering measurements over 7-1251 K in CaMnO3 covering various phase transitions, and over 6-150 K in PrMnO3 covering the magnetic transition. The excitations around 20 meV in CaMnO3 and at 17 meV in PrMnO3 are…

Materials Science · Physics 2016-06-29 S. K. Mishra , M. K. Gupta , R. Mittal , A. I. Kolesnikov , S. L. Chaplot

By performing density functional theory (DFT) +$U$ calculations, we systematically study the electronic, mechanical, tensile, and thermodynamic properties of AmO$_{2}$. The experimentally observed antiferromagnetic insulating feature [J.…

Materials Science · Physics 2012-11-05 Yong Lu , Yu Yang , Fawei Zheng , Bao-Tian Wang , Ping Zhang
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