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X-ray analysis of ferroelectric thin layers of Ba1/2Sr1/2TiO3 with different thickness reveals the presence of internal strain gradients across the film thickness and allows us to propose a functional form for the internal strain profile.…

Materials Science · Physics 2009-11-10 G. Catalan , B. Noheda , J. McAneney , L. Sinnamon , J. M. Gregg

Strain engineering is a powerful mean for tuning the various functionalities of ABO3 perovskite oxide thin films. Rare-earth orthoferrite RFeO3 materials such as NdFeO3 (NFO) are of prime interest because of their intriguing magnetic…

To distinguish between the effects of strain and magnetism on the superconductivity in $c$-axis La$_{2/3}$Ca$_{1/3}$MnO$_3$/YBa$_2$Cu$_3$O$_{7-\delta}$ (LCMO/YBCO) heterostructures, we study perovskite/YBCO/perovskite thin films using…

Superconductivity · Physics 2017-10-31 H. Zhang , A. Nguyen , T. Gredig , J. Y. T. Wei

In orthorhombic perovskite oxides (RMO$_3$), substituting R$^{3+}$ rare-earth cations tailors the spin, orbital, and charge degrees of freedom of the central M$^{3+}$ transition metal cations through lattice distortions. In turn, these…

The origin of the $3 \times 1$ reconstruction observed in epitaxial LaCoO$_{3}$ films on SrTiO$_3(001)$ is assessed by using first-principles calculations including a Coulomb repulsion term. We compile a phase diagram as a function of the…

Materials Science · Physics 2020-07-15 Benjamin Geisler , Rossitza Pentcheva

NiFe$_2$O$_4$ thin films with varying thickness were grown on SrTiO$_3$(001) by reactive molecular beam epitaxy. Soft and hard x-ray photoelectron spectroscopy measurements reveal a homogeneous cation distribution throughout the whole film…

Materials Science · Physics 2020-07-01 J. Rodewald , J. Thien , K. Ruwisch , F. Bertram , K. Kuepper , J. Wollschläger

Transition metal oxides are a platform for exploring strain-engineered intriguing physical properties and developing spintronic or flexible electronic functionalities owing to strong coupling of spin, charge and lattice degrees of freedom.…

The interrelation between the epitaxial strain and oxygen deficiency in La0.7Ca0.3MnO3-{\delta} thin films was studied in terms of structural and functional properties. The films with a thickness of 1000{\AA} were prepared using a PLD…

Materials Science · Physics 2015-06-23 K. Kawashima , G. Logvenov , G. Christiani , H. -U. Habermeier

Present study reveals that the free energy landscape of the La5/8-yPryCa3/8MnO3 (LPCMO) system could be modified by elastic strain interaction in the epitaxial thin films. Epitaxial LPCMO thin films of various thicknesses are grown on…

Strongly Correlated Electrons · Physics 2013-09-25 Dileep K. Mishra , V. G. Sathe , R. Rawat , V. Ganesan , Ravi Kumar , T. K. Sharma

Perovskite oxides hetero-structures are host to a large number of interesting phenomena such as ferroelectricity and 2D-superconductivity. Ferroelectric perovskite oxides have been of significant interest due to their possible use in…

In orthoferrites the rare-earth (R) ion has a big impact on structural and magnetic properties in particular the ionic size influences the octahedral tilt and the R3+- Fe3+ interaction modifies properties like the spin reorientation. Growth…

We present a study of the lattice response to the compressive and tensile biaxial stress in La0.67Sr0.33MnO3 (LSMO) and SrRuO3 (SRO) thin films grown on a variety of single crystal substrates: SrTiO3, DyScO3, NdGaO3 and (La,Sr)(Al,Ta)O3.…

Materials Science · Physics 2015-05-20 A. Vailionis , H. Boschker , W. Siemons , E. P. Houwman , D. H. A. Blank , G. Rijnders , G. Koster

Rare earth perovskite oxides constitute a wide family of materials presenting functional proper- ties strongly coupled to their crystalline structure. Here, we report on the experimental results on epitaxial PrVO3 deposited on SrTiO3 single…

Complex oxide thin films and heterostructures offer a wide range of properties originating from the intrinsic coupling between lattice strain and magnetic/electronic ordering. This article reviews experimental, phenomenological, and…

Strongly Correlated Electrons · Physics 2023-10-20 Surendra Singh

The magnetization of ferromagnetic LaCoO3 films grown epitaxially on piezoelectric substrates has been found to systematically decrease with the reduction of tensile strain. The magnetization change induced by the reversible strain…

Strongly Correlated Electrons · Physics 2009-11-13 A. Herklotz , A. D. Rata , L. Schultz , K. Doerr

Transition-metal oxides with an ABO$_3$ perovskite structure exhibit strongly entangled structural and electronic degrees of freedom and thus, one expects to unveil exotic phases and properties by acting on the lattice through various…

La1-xCaxMnO3 (x = 0.3; LCMO) films of different thickness were sputter-deposited on SrTiO3(100) (STO) single crystal substrates with and without YBa2Cu3O7-d (YBCO) as template layer. The electric and magnetic properties and the…

Materials Science · Physics 2007-05-23 Z. Q. Yang , R. Hendrikx , Y. Qin , H. W. Zandbergen , J. Aarts

Realization of novel functionalities by tuning magnetic interactions in rare earth perovskite oxide thin films opens up exciting technological prospects. Strain-induced tuning of magnetic interactions in rare earth cobaltates and nickelates…

The authors investigated the structure and properties of GdBaCo$_{2}$O$_{5.5+\delta}$ thin films epitaxially grown on SrTiO$_{3}$ (001) single crystal substrates. The thin films were found to have a notable remnant magnetization above room…

Strongly Correlated Electrons · Physics 2009-01-13 G. Y. Wang , X. Y. Zhou , R. K. Zheng , Y. M. Hu , H. L. W. Chan , Y. Wang

The ability to manipulate oxygen anion defects rather than metal cations in complex oxides can facilitate creating new functionalities critical for emerging energy and device technologies. However, the difficulty in activating oxygen at…

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