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The electronic structure of epitaxial films on LaCoO3(LCO) has been studied within first principle electronic structure calculations. A spin state transition is found to take place as a function of lattice strain which freezes in the…

Strongly Correlated Electrons · Physics 2009-01-05 Kapil Gupta , Priya Mahadevan

The origin of insulating ferromagnetism in epitaxial LaCoO3 films under tensile strain remains elusive despite extensive research efforts have been devoted. Surprisingly, the spin state of its Co ions, the main parameter of its…

Epitaxial strain in transition-metal oxides can induce dramatic changes in electronic and magnetic properties. A recent study on the epitaxially strained SrCoO$_3$ thin films revealed persistent ferromagnetism even across a metal-insulator…

Using density functional theory within the LSDA + U method, we investigate the effect of strain on the spin state and magnetic ordering in perovskite lanthanum cobaltite, LaCoO3. We show that, while strain-induced changes in lattice…

Materials Science · Physics 2009-02-18 James M. Rondinelli , Nicola A. Spaldin

LaCoO3 thin films grown under epitaxial tensile strain exhibit a robust ferromagnetic insulating state that is absent in the bulk. Despite many studies, both experimental and computational, the microscopic origin of this phenomenon is not…

Materials Science · Physics 2026-04-08 Ali Barooni , Murod Mirzhalilov , Mohit Randeria , Patrick M. Woodward , Maryam Ghazisaeidi

The origin of strain-induced ferromagnetism, which is robust regardless of the type and degree of strain in LaCoO3 (LCO) thin films, is enigmatic despite intensive research efforts over the past decade. Here, by combining scanning…

Epitaxial strain provides important pathways to control the magnetic and electronic states in transition metal oxides. However, the large strain is usually accompanied by a strong reduction of the oxygen vacancy formation energy, which…

The spin states of Co$^{3+}$ ions in perovskite-type LaCoO$_3$, governed by complex interplay between the electron-lattice interactions and the strong electron correlations, still remain controversial due to the lack of experimental…

Strongly Correlated Electrons · Physics 2018-05-23 Y. Yokoyama , Y. Yamasaki , M. Taguchi , Y. Hirata , K. Takubo , J. Miyawaki , Y. Harada , D. Asakura , J. Fujioka , M. Nakamura , H. Daimon , M. Kawasaki , Y. Tokura , H. Wadati

We report on the effect of epitaxial strain on magnetic and optical properties of perovskite LaCrO3 (LCO) single crystal thin films. Epitaxial LCO thin films are grown by pulsed laser deposition on proper choice of substrates to impose…

Ferromagnetic insulators play a crucial role in the development of low-dissipation quantum magnetic devices for spintronics. Epitaxial LaCoO3 thin film is a prominent ferromagnetic insulator, in which the robust ferromagnetic ordering…

Materials Science · Physics 2022-06-17 Dongwon Shin , Sangmoon Yoon , Sehwan Song , Sungkyun Park , Ho Nyung Lee , Woo Seok Choi

Epitaxial thin films of LaCoO_{3} (E-LCO) exhibit ferromagnetic order with a transition temperature T_c = 85 K, while polycrystalline thin LaCoO_{3} films (P-LCO) remain paramagnetic. The temperature-dependent spin-state structure for both…

Strongly Correlated Electrons · Physics 2009-11-13 C. Pinta , D. Fuchs , M. Merz , M. Wissinger , E. Arac , A. Samartsev , P. Nagel , S. Schuppler

The effect of high tensile strain and low dimensionality on the magnetic and electronic properties of CaMnO$_3$ ultrathin films, epitaxially grown on SrTiO$_3$ substrates, are experimentally studied and theoretically analyzed. By means of…

Materials Science · Physics 2020-09-02 A. López Pedroso , M. A. Barral , M. E. Graf , A. M. Llois , M. H. Aguirre , L. B. Steren , S. Di Napoli

The strain dependent functional properties of epitaxial transition metal oxide films can be significantly modified via substrate selection. However, large lattice mismatches preclude dislocation-free epitaxial growth on ferroelectric…

We investigated the crystal and electronic structures of ferroelectric Bi4Ti3O12 (BiT) single crystalline thin films site-specifically substituted with LaCoO3 (LCO). The epitaxial films were grown by pulsed laser epitaxy on NdGaO3 and…

Materials Science · Physics 2015-05-13 Woo Seok Choi , Ho Nyung Lee

We demonstrate control of helimagnetic order in biaxially strained SrFeO3 thin films using neutron diffraction and resonant soft x-ray scattering. SrFeO3, a negative charge-transfer oxide, exhibits a complex magnetic phase diagram that…

The impact of epitaxial strain on the structural, electronic, and thermoelectric properties of p-type transparent Sr-doped LaCrO3 thin films has been investigated. For this purpose, high-quality fully strained La0.75Sr0.25CrO3 (LSCO)…

We study ferromagnetic ordering and microscopic inhomogeneity in tensile strained LaCoO$_3$ using numerical simulations. We argue that both phenomena originate from effective superexchange interactions between atoms in the high-spin (HS)…

Strongly Correlated Electrons · Physics 2020-06-03 Andrii Sotnikov , Kyo-Hoon Ahn , Jan Kuneš

We have investigated the Co-doping dependence of the structural, transport, and magnetic properties of \epsilon-FeCoSi epilayers grown by molecular beam epitaxy on silicon (111) substrates. Low energy electron diffraction, atomic force…

Materials Science · Physics 2015-06-16 P. Sinha , N. A. Porter , C. H. Marrows

Magnetism in lanthanum cobaltite (LCO, LaCoO$_3$) appears to be strongly dependent on strain, defects, and nanostructuring. LCO on strontium titanate (STO, SrTiO$_3$) is a ferromagnet with an interesting strain relaxation mechanism that…

Materials Science · Physics 2021-10-13 Kayahan Saritas , Jaron T. Krogel , Satoshi Okamoto , Ho-Nyung Lee , Fernando A. Reboredo

Using spectroscopic ellipsometry, we studied the optical conductivity of LaCoO$_3$ with various degrees of strain. The optical response of the compressively strained \lco\ film is qualitatively similar to the one of the unstrained LaCoO$_3$…

Strongly Correlated Electrons · Physics 2025-03-13 F. Abadizaman , M. Kiaba , A. Dubroka
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