Related papers: Thermodynamic curvature from the critical point to…
We evaluate the thermodynamic curvature $R$ for fluid argon, hydrogen, carbon dioxide, and water. For these fluids, $R$ is mostly negative, but we also find significant regimes of positive $R$, which we interpret as indicating solid-like…
I give a relatively broad survey of thermodynamic curvature $R$, one spanning results in fluids and solids, spin systems, and black hole thermodynamics. $R$ results from the thermodynamic information metric giving thermodynamic…
The phase diagram (pressure versus temperature) of the pure fluid is typically envisioned as being featureless apart from the presence of the liquid-vapor coexistence curve terminating at the critical point. However, a number of recent…
Thermodynamics unavoidably contains fluctuation theory, expressible in terms of a unique thermodynamic information metric. This metric produces an invariant thermodynamic Riemannian curvature scalar $R$ which, in fluid and spin systems,…
Liquid water has anomalous liquid properties, such as its density maximum at 4\degree C. An attempt at theoretical explanation proposes a liquid-liquid phase transition line in the supercooled liquid state, with coexisting low-density (LDL)…
The thermodynamic Ricci curvature scalar $R$ has been applied in a number of contexts, mostly for systems characterized by 2D thermodynamic geometries. Calculations of $R$ in thermodynamic geometries of dimension three or greater have been…
Using computer simulations and a thermodynamically self consistent integral equation we investigate the phase behaviour and thermodynamic anomalies of a fluid composed of spherical particles interacting via a two-scale ramp potential (a…
Differential geometry is powerful tool to analyze the vapor-liquid critical point on the surface of the thermodynamic equation of state. The existence of usual condition of the critical point $\left( \partial p/\partial V\right) _{T}=0$…
Fluids in which the interparticle potential has a hard core, is attractive at moderate separations, and repulsive at greater separations are known to exhibit novel phase behavior, including stable inhomogeneous phases. Here we report a…
We examine the dependence of a thermodynamic potential of a fluid on the geometry of its container. If motion invariance, continuity, and additivity of the potential are fulfilled, only four morphometric measures are needed to describe…
For a fluid of convex hard particles, characterized by a length scale $\sigma_\text{min}$ and an anisotropy parameter $\epsilon$, we develop a formalism allowing one to relate thermodynamic quantities to the body's shape. In a first step…
The three-dimensional Gaussian core model (GCM) for soft-matter systems has repulsive interparticle interaction potential $\phi (r) = \varepsilon\, {\rm exp}\left[ -(r/\sigma)^{2} \right]$, with $r$ the distance between a pair of atoms, and…
The liquid-vapour phase transition near a weakly attractive surface is studied by simulations of the coexistence curves of water in hydrophobic pores. There is a pronounced gradual density depletion of the liquid phase near the surface…
In this paper, we examine the thermodynamic geometry of four-dimensional quasi-topological black holes by computing the Ruppeiner scalar curvature R which serves as an empirical tool to describe the nature of interactions among black hole…
We consider fluids where the attractive interaction at distances slightly larger than the particle size is dominated at larger distances by a repulsive contribution. A previous investigation of the effects of the competition between…
Microscopic models of realistic thermodynamic systems usually involve a number of parameters, not all of equal macroscopic relevance. We examine a decorated $(1+3)$ Ising spin chain containing two microscopic parameters: a "stiff" $K$…
With the use of thermodynamics and general equilibrium conditions only, we study the entropy of a fluid in the vicinity of the critical point of the liquid-vapor phase transition. By assuming a general form for the coexistence curve in the…
Gravity-driven convection of fluid at parameters near its thermodynamic critical point inside a porous layer heated from below (Rayleigh-Darcy convection) is studied. The fluid having the temperature slightly above the critical one is…
The thermodynamic behavior of a fluid near a vapor-liquid and, hence, asymmetric critical point is discussed within a general ``complete'' scaling theory incorporating pressure mixing in the nonlinear scaling fields as well as corrections…
The phase coexistence is illuminated with geometric views of the thermodynamic variables, according to Gibbs' choices. Quantities and relations between them are obtained. The existence of the edge of regression with tangents coincident with…