Related papers: Lightly stuffed pyrochlore structure of single-cry…
Large single crystals of the pyrochlore Pr2Hf2O7 have been successfully grown by the floating zone technique using an optical furnace equipped with high power Xenon arc lamps. Structural investigations have been carried out by both…
Pyrochlore erbium titanate samples in the form of powders (with nominal compositions of Er2Ti2+xO7) and bulk single crystals were prepared to elucidate the effect of synthesis and growth conditions on their composition, structure, and…
A series of Yb2Ti2O7 doped samples demonstrates the effects of off-stoichiometry on Yb2Ti2O7's structure, properties, and magnetic ground state via x-ray diffraction, specific heat, and magnetization measurements. A stoichiometric single…
We have investigated the effect of synthesis and growth conditions on the magnetic, structural, and compositional properties of pyrochlore oxide holmium titanate and demonstrate a method for growing high quality stoichiometric single…
We present an interpretation of zero field diffuse neutron scattering and of high field magnetisation data at very low temperature in the frustrated pyrochlore system Tb2Ti2O7. This material has antiferromagnetic exchange interactions and…
The Ho2Ti2O7, Er2Ti2O7 and Yb2Ti2O7 pyrochlores were studied by synchrotron X-ray diffraction to determine whether the (002) peak, forbidden in the pyrochlore space group Fd-3m but observed in single crystal neutron scattering measurements,…
There are reasons to believe that the ground state of the magnetic rare earth pyrochlore Yb$_2$Ti$_2$O$_7$ is on the boundary between competing ground states. We have carried out $\mathrm{\textit{ab initio}}$ density functional calculations…
Ba3Yb2Zn5O11 is unique among breathing pyrochlore compounds for being in the nearly decoupled limit where inter-tetrahedron interactions are weak, hosting isolated clusters or "molecular magnet" like tetrahedra of magnetic ytterbium (Yb3+)…
This study reports atomic-scale characterization of structural defects in Yb2Ti2O7, a pyrochlore oxide whose subtle magnetic interactions is prone to small perturbations. Due to discrepancies in the reported magnetic ground states, it has…
Pyrochlore $\rm Pr^{3+}_{2+x}Zr^{4+}_{2-x}O_{7-x/2}$ samples in the form of both powders $(-0.02 \le x \le 0.02)$ and bulk single crystals have been studied to elucidate the dependence of their magnetic, compositional and structural…
The pyrochlore magnet $\rm Yb_2Ti_2O_7$ has been proposed as a quantum spin ice candidate, a spin liquid state expected to display emergent quantum electrodynamics with gauge photons among its elementary excitations. However, $\rm…
Although materials that exhibit nearest-neighbor-only antiferromagnetic interactions and geometrical frustration theoretically should not magnetically order in the absence of disorder, few such systems have been observed experimentally. One…
High resolution X-ray powder-diffraction experiments on a well-characterized polycrystalline sample of the spin liquid Tb2Ti2O7 reveal that it shows normal positive thermal-expansion above 4 K, which does not agree with the intriguing…
The rare earth pyrochlore magnet Yb2Ti2O7 is among a handful of materials that apparently exhibit no long range order down to the lowest explored temperatures and well below the Curie-Weiss temperature. Paramagnetic neutron scattering on a…
We report a systematic study on the crystal growth of the rare-earth titanates $R_2$Ti$_2$O$_7$ ($R$ = Gd, Tb, Dy, Ho, Y, Er, Yb and Lu) and Y-doped Tb$_{2-x}$Y$_x$Ti$_2$O$_7$ ($x$ = 0.2 and 1) using an optical floating-zone method.…
We report structural and magnetic properties studies of large high quality single-crystals of the frustrated magnet, Nd$_2$Zr$_2$O$_7$. Powder x-ray diffraction analysis confirms that Nd$_2$Zr$_2$O$_7$ adopts the pyrochlore structure.…
We report on the growth of Y2Ti2O7 single crystals by optical floating zone technique. X-ray diffraction and Raman spectroscopy studies confirm the structural quality of the crystal. The UV-Vis optical studies reveal that the grown crystals…
Static and dynamical properties of the magnetic moment system of pyrochlore compound Tb2Ti2O7 with strong magnetic frustration, have been investigated down to the temperature T=0.4 K by neutron scattering on a single crystal sample. The…
We report a structural and thermodynamic study of the "stuffed spin ice" material Ho2TiO5 (i.e., Ho2(Ti1.33Ho0.67)O6.67), comparing samples synthesized through two different routes. Neutron powder diffraction and electron diffraction reveal…
The pyrochlore insulator Yb2Ti2O7 has attracted the attention of experimentalists and theoreticians alike for about 15 years. Conflicting neutron diffraction data on the possible existence of magnetic Bragg reflections at low temperature…