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The structural and magnetic properties of YVO3, NdVO3 and TbVO3 were investigated by single-crystal and powder neutron diffraction. YVO3 shows a structural phase transition at 200 K from an orthorhombic structure with the space group Pbnm…

Strongly Correlated Electrons · Physics 2009-11-11 M. Reehuis , C. Ulrich , P. Pattison , B. Ouladdiaf , M. C. Rheinstadter , M. Ohl , L. P. Regnault , M. Miyasaka , Y. Tokura , B. Keimer

We have carried out systematic temperature-dependent neutron diffraction measurements in conjunction with dielectric spectroscopy from 6 to 300 K for sodium niobate based compounds (1-x) NaNbO3 -xBaTiO3 (NNBTx). The dielectric constant is…

Materials Science · Physics 2018-05-23 S. K. Mishra , Mrinal Jauhari , R. Mittal , P. S. R. Krishna , V. R. Reddy , S. L. Chaplot

The results of a single-crystal X-ray-diffraction study of the evolution of crystal structures of VI3 with temperature with emphasis on phase transitions are presented. Some related specific-heat and magnetization data are included. The…

The local structure of V$_{2}$O$_{3}$, an archetypal strongly correlated electron system that displays a metal-insulator transition around 160 K, has been investigated via pair distribution function (PDF) analysis of neutron and x-ray total…

Strongly Correlated Electrons · Physics 2021-11-30 Ethan R. A. Fletcher , Kentaro Higashi , Yoav Kalcheim , Hiroshi Kageyama , Benjamin A. Frandsen

We have grown a YCrO$_3$ single crystal by the floating-zone method and studied its temperature-dependent crystalline structure and magnetization by X-ray powder diffraction and PPMS DynaCool measurements. All diffraction patterns were well…

Strongly Correlated Electrons · Physics 2024-03-08 Qian Zhao , Yinghao Zhu , Si Wu , Junchao Xia , Pengfei Zhou , Kaitong Sun , Hai-Feng Li

We report evidence for phase coexistence of orbital orderings of different symmetry in SmVO$_3$ by high resolution X-Ray powder diffraction. The phase coexistence is triggered by an antiferromagnetic ordering of the vanadium spins near…

Strongly Correlated Electrons · Physics 2009-11-11 M. H. Sage , G. R. Blake , G. J. Nieuwenhuys , T. T. M. Palstra

We report a temperature-dependent neutron diffraction (ND) study on polycrystalline monoclinic BaIrO$_3$ which is famous for charge density wave (CDW) and weak ferromagnetic phase transitions at T$_C$$\sim$180 K simultaneously. A Rietveld…

Strongly Correlated Electrons · Physics 2023-08-17 Bin Chang , Jinwon Jeong , Han-Jin Noh , Seongsu Lee

We report on the crystallographic information such as lattice parameters, atomic positions, bond lengths and angles, and local crystalline distortion size and mode of single-crystal YCrO$_3$ compound by a high-resolution synchrotron X-ray…

Materials Science · Physics 2024-03-08 Qian Zhao , Si Wu , Yinghao Zhu , Junchao Xia , Hai-Feng Li

We report a comprehensive neutron diffraction study of the crystal structure and magnetic order in a series of single-crystal and powder samples of SrFeO$_{3-\delta}$ in the vacancy range $0 \leq \delta \leq 0.23$. The data provide detailed…

Strongly Correlated Electrons · Physics 2015-06-05 M. Reehuis , C. Ulrich , A. Maljuk , Ch. Niedermayer , B. Ouladdiaf , A. Hoser , T. Hofmann , B. Keimer

Optical and magneto-optical properties of YVO$_3$ single crystal were studied in FIR, visible, and UV regions. Two structural phase transitions at 75 K and 200 K were observed and established to be of the first and second order,…

Evidence has been found for a change in the ordered occupation of the vanadium d-orbitals at the 77K phase transition in YVO3, manifested by a change in the type of Jahn-Teller distortion. The orbital ordering above 77K is not destroyed at…

Strongly Correlated Electrons · Physics 2009-11-07 G. R. Blake , T. T. M. Palstra , Y. Ren , A. A. Nugroho , A. A. Menovsky

The structural phase transformations of 0.7Pb(Mg1/3Nb2/3)O3-0.3PbTiO3 (PMN-30%PT) have been studied using x-ray diffraction (XRD) and neutron scattering as a function of temperature and electric field. We observe the phase transformational…

Materials Science · Physics 2009-11-10 Feiming Bai , Naigang Wang , Jiefang Li , D. Viehland , P. M. Gehring , Guangyong Xu , G. Shirane

Highly-strained BiFeO3 exhibits a "tetragonal-like, monoclinic" crystal structure found only in epitaxial films (with an out-of-plane lattice parameter exceeding the in-plane value by >20%). Previous work has shown that this phase is…

Materials Science · Physics 2011-08-17 Wolter Siemons , Michael D. Biegalski , Joong Hee Nam , Hans M. Christen

Synchrotron x-ray powder diffraction measurements have been performed on unpoled ceramic samples of (1-x)PbMg(1/3)Nb(2/3)O3-xPbTiO3 (PMN-xPT) with 30%<= x<= 39% as a function of temperature around the morphotropic phase boundary (MPB),…

Materials Science · Physics 2009-11-07 B. Noheda , D. E. Cox , G. Shirane , Z. -G. Ye , J. Gao

The crystallographic and magnetic properties of the cleavable 4d3 transition metal compound a-MoCl3 are reported, with a focus on the behavior above room temperature. Crystals were grown by chemical vapor transport and characterized using…

Neutron scattering studies on a single crystal of the highly-correlated electron system, La1-xSrxMnO3 with x~0.3, have been carried out elucidating both the spin and lattice dynamics of this metallic ferromagnet. We report a large measured…

Condensed Matter · Physics 2009-10-28 Michael C. Martin , G. Shirane , Y. Endoh , K. Hirota , Y. Moritomo , Y. Tokura

The crystal structure and the magnetism of BaMn$_2$O$_3$ have been studied by thermodynamic and by diffraction techniques using large single crystals and powders. BaMn$_2$O$_3$ is a realization of a $S = 5/2$ spin ladder as the magnetic…

Strongly Correlated Electrons · Physics 2015-05-20 M. Valldor , O. Heyer , A. C. Komarek , A. Senyshyn , M. Braden , T. Lorenz

Synchrotron X-ray total scattering studies of structural changes in rutile VO2 at the metal-insulator transition temperature of 340 K reveal that monoclinic and tetragonal phases of VO2 coexist in equilibrium, as expected for a first-order…

Materials Science · Physics 2010-08-10 Serena A. Corr , Daniel P. Shoemaker , Brent C. Melot , Ram Seshadri

Magnetization measurements and time-of-flight neutron powder-diffraction studies on the high-temperature (300--980 K) magnetism and crystal structure (321--1200 K) of a pulverized YCrO$_3$ single crystal have been performed.…

Strongly Correlated Electrons · Physics 2021-11-04 Yinghao Zhu , Si Wu , Bao Tu , Shangjian Jin , Ashfia Huq , Joerg Persson , Haoshi Gao , Defang Ouyang , Zhubing He , Dao-Xin Yao , Zikang Tang , Hai-Feng Li

We report the results of magnetization, heat capacity and neutron scattering studies of LaVO3 single crystals. From the neutron diffraction studies, it was found that the compound is magnetically ordered with a C-type antiferromagnetic spin…

Strongly Correlated Electrons · Physics 2009-11-13 L. D. Tung , A. Ivanov , J. Schefer , M. R. Lees , G. Balakrishnan , D. McK Paul
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