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The shape of deposits obtained from drying drops containing colloidal particles matters for technologies such as inkjet printing, microelectronics and bioassay manufacturing. In this work, the formation of deposits during the drying of…
Typically, in quiescent conditions, attractive colloids at low volume fractions form fractal gels structured into two length scales: the colloidal and the fractal cluster scales. However when flow interfere with gelation colloidal fractal…
When a colloidal gel dries through evaporation, cracks are usually formed, which often reveal underlying processes at work during desiccation. Desiccating colloid droplets of few hundred $\mu l$ size show interesting effects of pattern…
Colloidal gels have strong industrial relevance as they can behave liquid- and solid-like. The latter allows them to support the buoyant weight against gravity. However, the system is intrinsically out-of-equilibrium, which means that the…
We propose simple model of colloidal sessile drop desiccation. The model describes correctly both evolution of the phase boundary between sol and gel inside such a drop and the final shape of the dried film (deposit). The model is based on…
Sorbents are promising materials for applications in atmospheric water harvesting, thermal energy storage, and passive cooling, thereby addressing central challenges related to water scarcity and the global energy transition. Recently,…
Small angle neutron and x-ray scattering methods are used to investigate the structure of dilute suspensions of two different ferrofluid systems dispersed in soft polyacrylamide hydrogels. It is found that the particles in the fluid are…
During directional solidification of the solvent in a colloidal suspension, the colloidal particles segregate from the growing solid, forming high-particle-density regions with structure on a hierarchy of length scales ranging from that of…
Aiming at fabrication of hybrid plasmonic-photonic crystals, gel-immobilized colloidal crystals made of a polystyrene colloidal suspension and an N-(Hydroxy methyl)acrylamid-based gel were immersed into an aqueous dispersion of gold…
In directionally-dried colloidal dispersions regular bands can appear behind the drying front, inclined at $\pm45^\circ$ to the drying line. Although these features have been noted to share visual similarities to shear bands in metal, no…
Colloid-polymer mixtures can undergo spinodal decomposition into colloid-rich and colloid-poor regions. Gelation results when interconnected colloid-rich regions solidify. We show that this occurs when these regions undergo a glass…
Using molecular dynamics computer simulations we investigate the structural and dynamical properties of a simple model for a colloidal gel at low volume fraction. We find that at low T the system is forming an open percolating cluster,…
We present a detailed numerical study of multi-component colloidal gels interacting sterically and obtained by arrested phase separation. Under deformation, we found that the interplay between the different intertwined networks is key.…
Micrometre sized colloidal particles can be viewed as large atoms with tailorable size, shape and interactions. These building blocks can assemble into extremely rich structures and phases, in which the thermal motions of particles can be…
When strained beyond the linear regime, soft colloidal glasses yield to steady-state plastic flow in a way that is similar to the deformation of conventional amorphous solids. Due to the much larger size of the colloidal particles with…
We report small-angle x-ray scattering (SAXS) experiments on aqueous dispersions of colloidal silica with a broad monomodal size distribution (polydispersity 18%, size 8 nm). Over a range of volume fractions the silica particles segregate…
Colloidal model systems allow for a flexible tuning of particle sizes, particle spacings and mutual interactions at constant temperature. Colloidal suspensions typically crystallize as soon as the interactions get sufficiently strong and…
Cyclodextrins (CD) are a family of oligosaccharides with a toroid shape, which exhibit a remarkable ability to include guest molecules in their internal cavity providing a hydrophobic environment for poorly soluble molecules. Recently new…
We report the results of an experimental investigation of segregation in a binary mixture of dry particles subjected to horizontal oscillatory excitation. The thin layer of particles was driven by the stick--slip frictional interaction with…
Drying of biologically-relevant sessile droplets, including passive systems (like DNA and proteins), as well as active microbial systems comprising bacteria and algae, have garnered considerable attention over the last decades. Distinct…