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We analyze the methodology and the performance of subsystem density functional theory (DFT) with meta-generalized gradient approximation (meta-GGA) exchange-correlation functionals for non-bonded systems. Meta-GGA functionals depend on the…

Other Condensed Matter · Physics 2015-05-05 S. Śmiga , E. Fabiano , S. Laricchia , L. A. Constantin , F. Della Sala

A widely used approximation to the exchange-correlation functional in density functional theory is the local density approximation (LDA), typically derived from the properties of the homogeneous electron gas (HEG). We previously introduced…

Other Condensed Matter · Physics 2018-06-27 Mike Entwistle , Michele Casula , Rex Godby

Complex potential transformations which add imaginary parts to chosen energy levels are given and qualitatively explained. Unexpected shape similarity of potential perturbations for real and imaginary E-shifts of bound states are exhibited.…

Quantum Physics · Physics 2007-05-23 V. M. Chabanov , B. N. Zakhariev

We study correlations of non-affine displacement during simple shear deformation of Cu-Zr bulk metallic glasses in molecular dynamics calculations. In the elastic regime, our calculations show exponential correlation with a decay length…

Soft Condensed Matter · Physics 2019-09-13 Richard Jana , Lars Pastewka

In this work, we establish that discontinuous Galerkin methods are capable of producing reliable approximations for a broad class of nonlinear variational problems. In particular, we demonstrate that these schemes provide essential…

Numerical Analysis · Mathematics 2025-01-22 Georgios Grekas , Konstantinos Koumatos , Charalambos Makridakis , Andreas Vikelis

We model the exchange-correlation (XC) energy density of the Si crystal and atom as calculated by variational Monte Carlo (VMC) methods with a gradient analysis beyond the local density approximation (LDA). We find the Laplacian of the…

Materials Science · Physics 2009-11-11 Antonio C. Cancio , M. Y. Chou

This study presents a fractional-order continuum mechanics approach that allows combining selected characteristics of nonlocal elasticity, typical of classical integral and gradient formulations, under a single frame-invariant framework.…

Numerical Analysis · Mathematics 2020-05-21 Sansit Patnaik , Sai Sidhardh , Fabio Semperlotti

In this paper we study a local and a non-local regularization of the system of nonlinear elastodynamics with a non-convex energy. We show that solutions of the non-local model converge to those of the local model in a certain regime. The…

Analysis of PDEs · Mathematics 2014-05-12 Jan Giesselmann

An analytical expression for the current through a single level quantum dot for arbitrary strength of the on-site electron-electron interaction is derived beyond standard mean-field theory. By describing the localised states in terms of…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 J. Fransson

A review of the approximations in any time-dependent density functional calculation of excitation energies is given. The single-pole approximation for the susceptibility is used to understand errors in popular approximations for the…

Materials Science · Physics 2007-05-23 Kieron Burke , Martin Petersilka , E. K. U. Gross

Based on the calculation of the quasiequilibrium statistical sum by means of the functional integration method, we obtained a nonequilibrium statistical operator for the electron subsystem of a semibounded metal in the framework of the…

Statistical Mechanics · Physics 2011-03-15 P. P. Kostrobij , B. M. Markovych , A. I. Vasylenko , M. V. Tokarchuk

Our theoretical examination of second and third harmonic generation from metal-based nanostructures predicts that nonlocal and quantum tunneling phenomena can significantly exceed expectations based solely on local, classical…

Approximations to the exact density functional for the exchange-correlation energy of a many-electron ground state can be constructed by satisfying constraints that are universal, i.e., valid for all electron densities. Gedanken densities…

Chemical Physics · Physics 2015-06-19 John P. Perdew , Adrienn Ruzsinszky , Jianwei Sun , Kieron Burke

We present data of transport measurements through a metallic nanobridge exhibiting diffusive electron transport. A logarithmic temperature dependence and a zero-bias anomaly in the differential conductance are observed, independent of…

Mesoscale and Nanoscale Physics · Physics 2020-04-20 H. B. Weber , R. Häussler , H. v. Löhneysen , J. Kroha

We propose global hybrid approximations of the exchange-correlation (XC) energy functional which reproduce well the modified fourth-order gradient expansion of the exchange energy in the semiclassical limit of many-electron neutral atoms…

Chemical Physics · Physics 2015-01-22 E. Fabiano , L. A. Constantin , P. Cortona , F. Della Sala

In density functional theory (DFT), exact constraints, fundamental mathematical properties of the exchange-correlation (XC) energy and its underlying XC hole, along with paradigm systems such as the uniform electron gas and the hydrogen…

Materials Science · Physics 2026-03-13 Yan Oueis , Akilan Ramasamy , James W. Furness , Jamin Kidd , Timo Lebeda , Jianwei Sun

A collisional model of a confined quasi-two-dimensional granular mixture is considered to analyze homogeneous steady states. The model includes an effective mechanism to transfer the kinetic energy injected by vibration in the vertical…

Statistical Mechanics · Physics 2020-12-30 Ricardo Brito , Rodrigo Soto , Vicente Garzó

We implement a Becke fuzzy cells type space partitioning scheme for the purposes of exchange-correlation within the GPAW projector augmented-wave method based density functional theory code. Space partitioning is needed in the situation…

Materials Science · Physics 2019-02-20 H. Levämäki , M. Kuisma , K. Kokko

We introduce a class of unconditionally energy stable, high order accurate schemes for gradient flows in a very general setting. The new schemes are a high order analogue of the minimizing movements approach for generating a time discrete…

Numerical Analysis · Mathematics 2020-02-11 Alexander Zaitzeff , Selim Esedoglu , Krishna Garikipati

A new variational method for studying the equilibrium states of an interacting particles system has been proposed. The statistical description of the system is realized by means of a density matrix. This method is used for description of…

General Physics · Physics 2014-12-19 Boris Bondarev