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Colloidal patchy particles with divalent attractive interaction can self-assemble into linear polymer chains. Their equilibrium properties in 2D and 3D are well described by Wertheim's thermodynamic perturbation theory which predicts a…

Soft Condensed Matter · Physics 2022-09-21 H. J. Jonas , P. Schall , P. G. Bolhuis

We explore the use of templated self-assembly to facilitate the formation of complex target structures made from patchy particles. First, we consider the templating of high-symmetry shell structures around a spherical core particle. We find…

Soft Condensed Matter · Physics 2013-06-25 Alexander J. Williamson , Alex W. Wilber , Jonathan P. K. Doye , Ard A. Louis

We report on a computer simulation and integral equation study of a simple model of patchy spheres, each of whose surfaces is decorated with two opposite attractive caps, as a function of the fraction $\chi$ of covered attractive surface.…

Soft Condensed Matter · Physics 2015-05-18 Achille Giacometti , Fred Lado , Julio Largo , Giorgio Pastore , Francesco Sciortino

Manipulating the way in which colloidal particles self-organise is a central challenge in the design of functional soft materials. Meeting this challenge requires the use of building blocks that interact with one another in a highly…

Soft Condensed Matter · Physics 2021-03-30 Joe G Donaldson , Peter Schall , Laura Rossi

Emergent behaviors occur in a vast array of systems across many scales, and are of fundamental physical importance because of the intrinsic difficulty in linking microscopic system properties to macroscopic behaviors. Here we study the…

Materials Science · Physics 2016-10-05 N. Khalid Ahmed , Greg van Anders , Elizabeth R. Chen , Sharon C. Glotzer

An extremely broad and important class of phenomena in nature involves the settling and aggregation of matter under gravitation in fluid systems. Some examples include: sedimenting marine snow particles in lakes and oceans (central to…

Fluid Dynamics · Physics 2019-05-21 Roberto Camassa , Daniel M. Harris , Robert Hunt , Zeliha Kilic , Richard M. McLaughlin

Partial pair-correlation functions of colloidal suspensions with continuous polydispersity can be challenging to characterize from optical microscopy or computer simulation data due to inadequate sampling. As a result, it is common to adopt…

Soft Condensed Matter · Physics 2011-10-12 Mark J. Pond , Jeffrey R. Errington , Thomas M. Truskett

The generation of nanoscale square and stripe patterns is of major technological importance since they are compatible with industry-standard electronic circuitry. Recently, a blend of diblock copolymer interacting via hydrogen-bonding was…

Soft Condensed Matter · Physics 2009-11-13 Carlos I. Mendoza , Erasmo Batta

We systematically investigate the self-assembly of anisotropic cone-shaped particles decorated by ring-like attractive patches. We demonstrate that the self-assembled clusters, which arise due to the conical particle's anisotropic shape…

Materials Science · Physics 2007-05-23 Ting Chen , Zhenli Zhang , Sharon C. Glotzer

In the present study we are performing simulation of simple model of two patch colloidal particles undergoing irreversible diffusion limited cluster aggregation using patchy Brownian cluster dynamics. In addition to the irreversible…

Soft Condensed Matter · Physics 2017-10-26 Isha Malhotra , Sujin B. Babu

A simple model for functionalized disordered porous media is proposed and the effects of confinement on self-association, percolation and phase behavior of a fluid of patchy particles are studied. The media is formed by a randomly…

Soft Condensed Matter · Physics 2025-03-12 Yurij V. Kalyuzhnyi , Taras Patsahan , Myroslav Holovko , Peter T. Cummings

Particles with directional interactions are promising building blocks for new functional materials and may serve as models for biological structures. Mutually attractive nanoparticles that are deformable due to flexible surface groups, for…

Soft Condensed Matter · Physics 2016-07-19 Chris H. J. Evers , Jurriaan A. Luiken , Peter G. Bolhuis , Willem K. Kegel

In this paper we explore the self-assembly patterns in a two dimensional colloidal system using extensive Langevin Dynamics simulations. The pair potential proposed to model the competitive interaction have a short range length scale…

Soft Condensed Matter · Physics 2018-01-01 José Rafael Bordin

Catalytically active colloids maintain non-equilibrium conditions in which they produce and deplete chemicals and hence effectively act as sources and sinks of molecules. While individual colloids that are symmetrically coated do not…

Soft Condensed Matter · Physics 2015-06-11 Rodrigo Soto , Ramin Golestanian

Understanding the relationship between colloidal building block shape and self-assembled material structure is important for the development of novel materials by self-assembly. In this regard, colloidal superballs are unique building…

Soft Condensed Matter · Physics 2021-12-16 Sarah N. Schyck , Janne-Mieke Meijer , Lucia Baldauf , Peter Schall , Andrei V. Petukhov , Laura Rossi

In geometrically frustrated assemblies local inter-subunit misfits propagate to intra-assembly strain gradients, giving rise to anomalous self-limiting assembly thermodynamics. Here, we use theory and coarse-grained simulation to study a…

Soft Condensed Matter · Physics 2024-03-05 Kyle T. Sullivan , Ryan C. Hayward , Gregory M. Grason

Motivated by observations of heterogeneous domain structure on the surface of cells, we consider a minimal model to describe the dynamics of phase separation on the surface of a spherical particle. Finite-size effects on the curved particle…

Soft Condensed Matter · Physics 2016-07-13 Matthias C. Bott , Joseph M. Brader

Using self-consistent field and density-functional theories, we first investigate colloidal self-assembling of colloid/polymer films confined between two soft surfaces grafted by polymers. With the increase of colloidal concentrations, the…

Soft Condensed Matter · Physics 2007-05-23 Chun-lai Ren , Yu-qiang Ma

Self-assembly of granular particles is of great interest in both applied and basic research. It is commonly observed that when randomly packed into a container, granular particles form disordered structures like glass. As the particles are…

Soft Condensed Matter · Physics 2025-01-20 Reza Amirifar , Kejun Dong , Aibing Yu

We study a system formed by soft colloidal spheres attracting each other via a square-well potential, using extensive Monte Carlo simulations of various nature. The softness is implemented through a reduction of the infinite part of the…

Soft Condensed Matter · Physics 2011-02-03 Riccardo Fantoni , Alexandr Malijevsky , Andres Santos , Achille Giacometti