Related papers: Energy of natural interface modes
The onset of thermalization in a closed finite system of randomly interacting bosons, at the level of a single eigenstate, is discussed. The main interest is in the emergence of the Bose-Einstein distribution of single-particle occupation…
We present ab initio electronic structure calculations based on density functional theory for the thermoelectric properties of Bi$_2$Te$_3$ films. Conductivity and thermopower are computed in the diffusive limit of transport based on the…
The quest for ever higher information capacities has brought about a renaissance in multimode optical waveguide systems. This resurgence of interest has recently initiated a flurry of activities in nonlinear multimode fiber optics. The…
Relative permeability is commonly used to model immiscible fluid flow through porous materials. In this work we derive the relative permeability relationship from conservation of energy, assuming that the system to be non-ergodic at large…
In standard thermodynamics, internal energy is a state function, independent of process rates. We show that this structure breaks down in open quantum systems undergoing thermalization. Within Gorini-Kossakowski-Lindblad-Sudarshan (GKLS)…
The usual formulation of thermodynamics is based on the additivity of macroscopic systems. However, there are numerous examples of macroscopic systems that are not additive, due to the long-range character of the interaction among the…
Thermodynamic characteristics of the radiation of condensed combustion products presented in the form of agglomerates of metal-oxide nanoparticles demonstrate deviations from the classical Planck's law. We propose to interpret these…
We formulate the first law of global thermodynamics for stationary states of the binary ideal gas mixture subjected to heat flow. We map the non-uniform system onto the uniform one and show that the internal energy…
For the system with inhomogeneous distribution of macroscopic parameters we obtain thermodynamic relation which depends on the spatial point (coordinate). In our approach, to obtain such a relation we use the basic ideas of the method of…
Electrochemical energy systems rely on particulate porous electrodes to store or convert energies. While the three-dimensional porous structures were introduced to maximize the interfacial area for better overall performance of the system,…
A non-equilibrium thermodynamics model able to analyze the combined effect of diffusion and adsorption in porous materials is proposed. The model considers the coupled dynamics of the diffusive phase, described by a diffusion type equation,…
Particles bound to an interface interact because they deform its shape. The stresses that result are fully encoded in the geometry and described by a divergence-free surface stress tensor. This stress tensor can be used to express the force…
In this paper, a statistical physical derivation of thermodynamically consistent fluid mechanical equations is presented for non-isothermal viscous molecular fluids. The coarse-graining process is based on (i) the adiabatic expansion of the…
Relations between the thermodynamics and dynamics of supercooled liquids approaching a glass transition have been proposed over many years. The potential energy surface of model liquids has been increasingly studied since it provides a…
In this work, a thermodynamically consistent and conservative diffuse-interface model for gas-liquid-solid multiphase flows is proposed. In this model, a novel free energy for the gas-liquid-solid multiphase flows is established according…
We consider field theory formulation for directed polymers and interfaces in the presence of quenched disorder. We write a series representation for the averaged free energy, where all the integer moments of the partition function of the…
The properties of the interface between solid and melt are key to solidification and melting, as the interfacial free energy introduces a kinetic barrier to phase transitions. This makes solidification happen below the melting temperature,…
We analyze the equilibrium spatial distribution of surface temperatures of patterned surfaces. The surface is exposed to a constant external heat flux and has a fixed internal temperature that is coupled to the outside heat fluxes by finite…
Liquid-gas phase coexistence in a boundary-driven diffusive system is studied by analyzing fluctuating hydrodynamics of a density field defined on a one-dimensional lattice with a space interval $\Lambda$. When an interface width $\ell$ is…
Within the framework of relativistic quantum field theory, a novel method is established which allows to distinguish non-equilibrium states admitting locally a thermodynamic interpretation. The basic idea is to compare these states with…