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An overview of several recent developments in density functional theory for classical inhomogeneous liquids is given. We show how Levy's constrained search method can be used to derive the variational principle that underlies density…

Soft Condensed Matter · Physics 2013-01-01 M. Schmidt , M. Burgis , W. S. B. Dwandaru , G. Leithall , P. Hopkins

Measures play an important role in the characterisation of various function spaces. In this paper, the structure of density measures will be investigated. These are elements of the dual of the space of essentially bounded func- tions. The…

Metric Geometry · Mathematics 2017-10-09 Moritz Schönherr , Friedemann Schuricht

We study both static and transport properties of model quantum dots, employing density functional theory as well as (numerically) exact methods. For the lattice model under consideration the accuracy of the local-density approximation…

Mesoscale and Nanoscale Physics · Physics 2011-04-11 S. Schenk , P. Schwab , M. Dzierzawa , U. Eckern

The molecular density functional theory of fluids provides an exact theory for computing solvation free energies in implicit solvents. One of the reasons it has not received nearly as much attention as quantum density functional theory for…

Statistical Mechanics · Physics 2019-02-04 David M. Rogers

We use the classical version of the density-functional theory in the weighted-density approximation to build up the entire phase diagram and the interface structure of a two-dimensional lattice-gas model which is known, from previous…

Statistical Mechanics · Physics 2011-10-25 S. Prestipino , P. V. Giaquinta

The one-particle reduced density-matrix (1-RDM) functional theory is a promising alternative to density-functional theory (DFT) that uses the 1-RDM rather than the electronic density as a basic variable. However, long-standing challenges…

Quantum Physics · Physics 2024-08-20 Matthieu Vladaj , Quentin Marécat , Bruno Senjean , Matthieu Saubanère

Calculating one-body density profiles in equilibrium via particle-based simulation methods involves counting of events of particle occurrences at (histogram-resolved) space points. Here we investigate an alternative method based on a…

Soft Condensed Matter · Physics 2018-11-07 Daniel de las Heras , Matthias Schmidt

By using a selective filtration argument, we prove that the satisfiability problem of the unimodal logic of density is in $EXPTIME$. By using a tableau-like approach, we prove that the satisfiability problem of the bimodal logic of weak…

Logic in Computer Science · Computer Science 2025-07-16 Philippe Balbiani , Olivier Gasquet

A practical electronic structure method in which a two-body functional is the fundamental variable is constructed. The basic formalism of our method is equivalent to Hartree-Fock density matrix functional theory [M. Levy in {\it Density…

Other Condensed Matter · Physics 2008-04-23 Balazs Hetenyi , Andreas W. Hauser

Shape-constrained functional data encompass a wide array of application fields, such as activity profiling, growth curves, healthcare and mortality. Most existing methods for general functional data analysis often ignore that such data are…

Methodology · Statistics 2024-08-13 Poorbita Kundu , Hans-Georg Müller

The density hypothesis on random times becomes now a standard in modeling of risks. One of the basic reasons to introduce the density hypothesis is the desire to have a computable credit risk model. However, recent work shows that merely an…

Probability · Mathematics 2014-02-04 Shiqi Song

Density functional theory is currently the most widely applied method in electronic structure theory. The Kohn-Sham method, based on a fictitious system of non-interacting particles, is the work horse of the theory. The particular form of…

Chemical Physics · Physics 2016-06-01 Hubertus J J van Dam

Density functional theory is discussed in the context of one-particle systems. We show that the ground state density $\rho_0(x)$ and energy $E_0$ are simply related to a family of external potential energy functions with ground state wave…

Quantum Physics · Physics 2009-11-10 H. L. Neal

We report tests of various density functionals for ferromagnetic, Fe, Co and Ni with a focus on characterizing the behavior of the so-called strongly constrained and appropriately normed (SCAN) functional. It is found that SCAN is closer in…

Strongly Correlated Electrons · Physics 2019-07-19 Y. Fu , D. J. Singh

The generalized constrained search formalism is used to address the issues concerning density-to-potential mapping for excited states in time-independent density-functional theory. The multiplicity of potentials for any given density and…

Materials Science · Physics 2015-06-09 Prasanjit Samal , Subrata Jana , Sourabh S. Chauhan

In this paper the relationship between the density functional theory of freezing and phase field modeling is examined. More specifically a connection is made between the correlation functions that enter density functional theory and the…

Materials Science · Physics 2007-05-23 K. R. Elder , Nikolas Provatas , Joel Berry , Peter Stefanovic , Martin Grant

We derive several tests for the presence of a periodic component in a time series of functions. We consider both the traditional setting in which the periodic functional signal is contaminated by functional white noise, and a more general…

Methodology · Statistics 2016-07-08 Siegfried Hörmann , Piotr Kokoszka , Gilles Nisol

A system of soft ellipsoid molecules confined between two planar walls is studied using classical Density Functional Theory (DFT). Both the isotropic and nematic phases are considered. The excess free energy is evaluated using two different…

Materials Science · Physics 2009-11-10 David Cheung , Friederike Schmid

Our recent theory (Ref. 1) enables us to choose arbitrary quantities as the basic variables of the density functional theory. In this paper we apply it to several cases. In the case where the occupation matrix of localized orbitals is…

Materials Science · Physics 2009-11-10 K. Higuchi , M. Higuchi

The Dynamic Density Functional (DDF) theory and standard Brownian dynamics simulations (BDS) are used to study the drifting effects of a colloidal particle in a polymer solution, both for ideal and interacting polymers. The structure of the…

Soft Condensed Matter · Physics 2009-11-10 F. Penna , J. Dzubiella , P. Tarazona