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A simple and computationally efficient scheme to calculate approximate imaginary-frequency dependent polarizability, hence asymptotic van der Waals coefficient, within density functional theory is proposed. The dynamical dipolar…

Materials Science · Physics 2009-04-20 Huy-Viet Nguyen , Stefano de Gironcoli

We study the classical thermal component of Casimir, or van der Waals, forces between point particles with highly anharmonic dipole Hamiltonians when they are subjected to an external electric field. Using a model for which the individual…

Mesoscale and Nanoscale Physics · Physics 2017-02-01 Heino Soo , David Dean , Matthias Krüger

Based on a microscopic model, we use a functional integral approach to evaluate the quantum interaction energy between two neutral atoms. Each atom is coupled to the electromagnetic (EM) field via a dipole term, generated by an electron…

Quantum Physics · Physics 2023-07-19 C. D. Fosco , G. Hansen

We employ the closed-shell perturbed relativistic coupled-cluster (RCC) theory developed by us earlier [Phys. Rev. A {\bf 77}, 062516 (2008)] to evaluate the ground state static electric dipole polarizabilities (\alpha s) of several atomic…

Atomic Physics · Physics 2013-12-09 Yashpal Singh , B. K. Sahoo , B. P. Das

In this article we address the general approach for calculating dynamical dipole polarizabilities of small quantum systems, based on a sum-over-states formula involving in principle the entire energy spectrum of the system. We complement…

Quantum Physics · Physics 2017-07-10 R. Vexiau , D. Borsalino , M. Lepers , A. Orbán , M. Aymar , O. Dulieu , N. Bouloufa-Maafa

This paper builds on two previous works, Lindgren et al. J. Comp. Phys. 371, 712-731 (2018) and Quan et al. arXiv:1807.05384 (2018), to devise a new method to solve the problem of calculating electrostatic interactions in a system composed…

Soft Condensed Matter · Physics 2019-02-20 Eric B. Lindgren , Chaoyu Quan , Benjamin Stamm

A solid ionic conductor with cation conductivity in the interelectrode region is studied. Due to their large size, the anions are considered fixed and form a homogeneous neutralizing electric background. The model can be used to describe…

Statistical Mechanics · Physics 2022-07-04 I. Kravtsiv , G. Bokun , M. Holovko , N. Prokopchuk , D. di Caprio

We present first steps toward understanding the ultracold scattering properties of polar molecules in strong electric field-seeking states. We have found that the elastic cross section displays a quasi-regular set of potential resonances as…

Atomic Physics · Physics 2009-11-11 Christopher Ticknor , John L. Bohn

Mobile charge in an electrolytic solution can in principle be represented as the divergence of ionic polarization. After adding explicit solvent polarization a finite volume of electrolyte can then be treated as a composite non-uniform…

Soft Condensed Matter · Physics 2021-03-03 Michiel Sprik

Structural properties of a finite number ($N = 2 - 20$) of point charges (classical electrons) confined laterally in a two-dimensional two-minima potential are calculated as a function of the distance ($d$) between the minima. The particles…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 M. Marlo , M. Alatalo , A. Harju , R. M. Nieminen

We propose a very sensitive method for measuring the electric dipole moment of the electron using polar molecules embedded in a cryogenic solid matrix of inert-gas atoms. The polar molecules can be oriented in the $\hat{\rm{z}}$ direction…

Atomic Physics · Physics 2018-01-29 A. C. Vutha , M. Horbatsch , E. A. Hessels

The electric and magnetic fields are investigated on the basis of quantum vacuum. The analysis of the electromagnetic energy and force indicates that an electric field is a polarized distribution of the vacuum virtual dipoles, and that a…

General Physics · Physics 2009-08-22 Xing-Hao Ye

We derive van der Waals-London and Casimir forces by calculating the eigenmodes of the electromagnetic field interacting with two semi-infinite bodies (two halves of space) with parallel surfaces separated by distance d. We adopt simple…

Mesoscale and Nanoscale Physics · Physics 2009-11-17 M. Apostol , G. Vaman

A general formalism is used to express the long-range potential energies in inverse powers of the separation distance between two like atomic or molecular systems with $P$ symmetries. The long-range molecular interaction coefficients are…

Atomic Physics · Physics 2007-08-01 J. -Y. Zhang , Z. -C. Yan , D. Vrinceanu , J. F. Babb , H. R. Sadeghpour

We calculate pair potential curves for interacting Rydberg atoms in a constant electric field and use them to determine the effective $C_3$ dipole-dipole and $C_6$ van der Waals coefficients. We compare the $C_3$ and $C_6$ with experiments…

The dynamic electric dipole polarizability function for the magnesium atom is formed by assembling the atomic electric dipole oscillator strength distribution from combinations of theoretical and experimental data for resonance oscillator…

Atomic Physics · Physics 2015-08-28 James F. Babb

The ground-state permanent dipole moments (PDMs) and molecular dipole polarizabilities (DPs) of open-shell alkaline-earth monofluorides, and atomic DPs of alkaline-earth- and fluorine atoms are reported at the Kramers-restricted…

Atomic Physics · Physics 2019-05-22 Renu Bala , H. S. Nataraj , Malaya K. Nayak

Novel equations for the electric dipole polarizability $\alpha_{_{E1}}$ of low-lying excited states in atomic nuclei -- and the related $(-2)$ moment of the total photo-absorption cross section, $\sigma_{_{-2}}$ -- are inferred in terms of…

Nuclear Theory · Physics 2024-03-12 José Nicolás Orce , Cebo Ngwetsheni

The isotropic and anisotropic coefficients $C^{l,m}_n$ of the long-range spherical expansion $\sim 1/R^n$ ($R$ -- the intermolecular distance) of the dispersion and inductions intermolecular energies are calculated using the first…

Chemical Physics · Physics 2023-04-04 Leonid Shirkov , Michał Tomza

In this work, we have studied the permanent electric dipole moments of singly charged aluminium monohalides in their electronic ground state, X$^2\Sigma$, using Kramers-restricted relativistic configuration interaction method. We report our…

Atomic Physics · Physics 2023-05-31 R. Bala , V. S. Prasannaa , B. P. Das