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The characteristic function of the work performed by an external time-dependent force on a Hamiltonian quantum system is identified with the time-ordered correlation function of the exponentiated system's Hamiltonian. A similar expression…

Statistical Mechanics · Physics 2009-11-13 Peter Talkner , Eric Lutz , Peter Hanggi

In the derivation of fluctuation relations, and in stochastic thermodynamics in general, it is tacitly assumed that we can measure the system perfectly, i.e., without measurement errors. We here demonstrate for a driven system immersed in a…

Statistical Mechanics · Physics 2016-11-30 C. W. Wächtler , P. Strasberg , T. Brandes

We study the work cost of processes in quantum fields without the need of projective measurements, which are always ill defined in quantum field theory. Inspired by interferometry schemes, we propose a work distribution that generalizes the…

Quantum Physics · Physics 2019-10-10 Alvaro Ortega , Emma McKay , Álvaro M. Alhambra , Eduardo Martin-Martinez

Most natural and engineered processes, such as biomolecular reactions, protein folding, and population dynamics, occur far from equilibrium and, therefore, cannot be treated within the framework of classical equilibrium thermodynamics. The…

Soft Condensed Matter · Physics 2016-01-07 Aykut Argun , Ali-Reza Moradi , Erçağ Pince , Gokhan Baris Bagci , Giovanni Volpe

This chapter reviews an information theoretic approach to deriving quantum fluctuation theorems. When a thermal system is driven from equilibrium, random quantities of work are required or produced: the Crooks equality is a classical…

Quantum Physics · Physics 2019-05-01 Z. Holmes

Due to their versatility in investigating phenomena in microscopic scales, optical tweezers have been an excellent platform for studying stochastic thermodynamics. In this context, this work presents experimental measurements of the…

Soft Condensed Matter · Physics 2022-09-15 Thalyta Tavares Martins , Lucas Prado Kamizaki , Sérgio Ricardo Muniz

We extend the Jarzynski equality, which is an exact identity between the equilibrium and nonequilibrium averages, to be useful to compute the value of the entropy difference by changing the Hamiltonian. To derive our result, we introduce…

Statistical Mechanics · Physics 2011-03-24 Hitoshi Katsuda , Masayuki Ohzeki

Adiabatic processes are important for studying the dynamics of a time-dependent system. Conventionally, the adiabatic processes can only be achieved by varying the system slowly. We speed up both classical and quantum adiabatic processes by…

Quantum Physics · Physics 2013-05-21 Jia-wen Deng , Qing-hai Wang , Jiangbin Gong

In a recent work, Jarzynski and Wojcik (2004 Phys. Rev. Lett. 92, 230602) have shown by using the properties of Hamiltonian dynamics and a statistical mechanical consideration that, through contact, heat exchange between two systems…

Statistical Mechanics · Physics 2008-05-29 Yuki Sughiyama , Sumiyoshi Abe

We study the non-equilibrium work in a pedagogical model of relativistic ideal gas. We obtain the exact work distribution and verify the Jarzynski's equality. In the non-relativistic limit, our results recover the non-relativistic results…

Statistical Mechanics · Physics 2025-11-21 Xianghang Zhang , Tingzhang Shi , H. T. Quan

We study nonequilibrium work relations for a space-dependent field with stochastic dynamics (Model A). Jarzynski's equality is obtained through symmetries of the dynamical action in the path integral representation. We derive a set of exact…

Statistical Mechanics · Physics 2011-02-18 Kirone Mallick , Moshe Moshe , Henri Orland

Recently, we presented a generalisation of the Jarzynski non-equilibrium work theorem for phase space mappings. The formalism shows that one can determine free energy differences from approximate trajectories obtained from molecular…

Statistical Mechanics · Physics 2009-11-13 Harald Oberhofer , Christoph Dellago , Stefan Boresch

We study the impact of work cost fluctuations on optimal protocols for the creation of correlations in quantum systems. We analyze several notions of work fluctuations to show that even in the simplest case of two free qubits, protocols…

Quantum Physics · Physics 2018-10-08 Emma McKay , Nayeli A. Rodriguez-Briones , Eduardo Martin-Martinez

The fluctuation-dissipation relation for the classical definition of work is extended to thermally isolated systems, in classical and quantum realms. From this, the optimal work variance is calculated, showing it achieves its minimum…

Statistical Mechanics · Physics 2023-11-01 Pierre Nazé

We study two non-equilibrium work fluctuation theorems, the Crooks' theorem and the Jarzynski equality, for a test system coupled to a spatially extended heat reservoir whose degrees of freedom are explicitly modeled. The sufficient…

Statistical Mechanics · Physics 2010-02-22 Punyabrata Pradhan , Yariv Kafri , Dov Levine

For a two-level quantum mechanical system, we derive microscopically the exact expression for the fluctuation of microscopic work in a multi-step non-equilibrium process, and we rigorously prove that in an isothermal process, the…

Statistical Mechanics · Physics 2008-08-19 H. T. Quan , S. Yang , C. P. Sun

Quantum work is usually determined from two projective measurements of the energy at the beginning and at the end of a thermodynamic process. However, this paradigm cannot be considered thermodynamically consistent as it does not account…

Quantum Physics · Physics 2016-07-13 Sebastian Deffner , Juan Pablo Paz , Wojciech H. Zurek

The equilibrium free energy landscape of an off-lattice model protein as a function of an internal (reaction) coordinate is reconstructed from out-of-equilibrium mechanical unfolding manipulations. This task is accomplished via two…

Statistical Mechanics · Physics 2007-10-17 Alberto Imparato , Stefano Luccioli , Alessandro Torcini

For a quantum system undergoing a unitary process work is commonly defined based on the Two Projective Measurement (TPM) protocol which measures the energies of the system before and after the process. However, it is well known that…

Quantum Physics · Physics 2017-11-22 P. Solinas , H. J. D. Miller , J. Anders

The optimal protocols for the irreversible work achieve their maximum usefulness if their work fluctuations are the smallest ones. In this work, for classical and isothermal processes subjected to finite-time and weak drivings, I show that…

Statistical Mechanics · Physics 2023-11-14 Pierre Nazé