Related papers: Elemental nitrogen partitioning in dense interstel…
Context. Carbon, nitrogen, and oxygen are the most abundant elements throughout the universe, after hydrogen and helium. Studying these elements in low-metallicity stars can provide crucial information on the chemical composition in the…
Context. The formation of water on the dust grains in the interstellar medium may proceed with hydrogen peroxide (H2O2) as an intermediate. Recently gas-phase H2O2 has been detected in {\rho} Oph A with an abundance of ~1E-10 relative to…
Aim: To determine whether or not gas-phase chemical models with homogeneous and time-independent physical conditions explain the many observed molecular abundances in astrophysical sources, it is crucial to estimate the uncertainties in the…
Carbon containing molecules in cold molecular clouds show various levels of isotopic fractionation through multiple observations. To understand such effects, we have developed a new gas-grain chemical model with updated 13C fractionation…
Physical conditions in dense and cold regions of interstellar clouds favour the formation of ice mantles on the surfaces of interstellar grains. It is predicted that most of the gaseous species heavier than H2 or He will adsorb onto the…
High quality archival spectra of interstellar absorption from C I toward 9 stars, taken with the Goddard High Resolution Spectrograph on the Hubble Space Telescope, were analyzed. Our sample was supplemented by two sight lines, 23 Ori and…
The formation of CH+ in the interstellar medium has long been an outstanding problem in chemical models. In order to probe the physical conditions of the ISM in which CH+ forms, we propose the use of CH3+ observations. The pathway to…
Observations conducted using the Atacama Large Millimeter/submillimeter Array on the protoplanetary disk around TW Hya show the nitrogen fractionation of HCN molecules in HC$^{14}$N/HC$^{15}$N $\sim$120 at a radius of $\sim$20 AU. In this…
Neutral hydrogen clouds with high column density detected towards distant quasars are unique probes of elemental nucleosynthesis and chemical evolution in the low metallicity regime. They provide measurements for several elements at very…
We show that the excess of nitrogen emission observed in a large sample of Starburst Nucleus Galaxies (SBNGs) can only be explained at a given metallicity by an overabundance of nitrogen with respect to normal HII regions in the disks of…
Photodissociation of 14N2 and 14N15N occurs in interstellar clouds, circumstellar envelopes, protoplanetary discs, and other environments due to UV radiation from stellar sources and the presence of cosmic rays. This source of N atoms…
Using the Green Bank Telescope (GBT), we have obtained accurate measurements of the $^{14}$N/$^{15}$N isotopic ratio in ammonia in two nearby cold, dense molecular clouds, Barnard~1 and NGC 1333. The $^{14}$N/$^{15}$N ratio in Barnard~1,…
CO2 ice is one of the most abundant components in ice-coated interstellar ices besides H2O and CO, but the most favorable path to CO2 ice is still unclear. Molecular dynamics calculations on the ultraviolet photodissociation of different…
Low-energy cosmic rays are a fundamental source of ionization for molecular clouds, influencing their chemical, thermal and dynamical evolution. The purpose of this work is to explore the possibility that a low-energy component of…
Recent observational studies of the Galactic bulge by APOGEE have revealed that about 1% of the bulge stars have rather high nitrogen abundances ([N/Fe]>0.5). We here numerically investigate in what physical conditions these N-rich stars…
We investigate the molecular evolution and D/H abundance ratios that develop as star formation proceeds from a dense-cloud core to a protostellar core, by solving a gas-grain reaction network applied to a 1-D radiative hydrodynamic model…
Hydrogen sulfide (H$_2$S) is thought to be efficiently formed on grain surfaces through the successive hydrogenation of S atoms. Its non-detection so far in astronomical observations of icy dust mantles thus indicates that effective…
The formation of hydrides by gas-phase reactions between H2 and a heavy element atom is a very selective process. Reactions with ground-state neutral carbon, oxygen, nitrogen, and sulfur atoms are very endoergic and have high energy…
The quantity of NH3 produced on grain surfaces in the prestellar core is thought to be one of the determining factors regarding the chemical complexity achievable at later stages of stellar birth. In order to investigate how this quantity…
Although they are only minor constituents of the interstellar medium, halogen-containing molecules are of special interest because of their unique thermochemistry. Here, we present a theoretical study of the chemistry of interstellar…