Related papers: Partial Pressures in Liquid Mixtures and Osmotic P…
The concept of the partial osmotic pressure of ions in an electrolyte solution is critically examined. In principle these can be defined by introducing a solvent-permeable wall and measuring the force per unit area which can certainly be…
Building on recent simulation work, it is demonstrated using molecular-dynamics (MD) simulations of two-component fluid mixtures that the chemical contribution to the Soret effect in two-component non-ideal fluid mixtures arises due to…
We derive a general closed expression for the local pressure exerted onto the corrugated walls of a channel confining a fluid medium. When the fluid medium is at equilibrium the local pressure is a functional of the shape of the walls. It…
The basic ingredients of osmotic pressure are a solvent fluid with a soluble molecular species which is restricted to a chamber by a boundary which is permeable to the solvent fluid but impermeable to the solute molecules. For macroscopic…
Pressure is the mechanical force per unit area that a confined system exerts on its container. In thermal equilibrium, it depends only on bulk properties (density, temperature, etc.) through an equation of state. Here we show that in a wide…
Equilibrium properties of dilute binary fluid mixtures are studied in two-phase states on the basis of a Helmholtz free energy including the gradient free energy. The solute partitioning between gas and liquid (Henry's law) and the surface…
The equilibrium relative humidity values for a number of the most commonly used precipitants in biological macromolecule crystallisation have been measured using a new humidity control device. A simple argument in statistical mechanics…
We extend Van't Hoff's law for the osmotic pressure to a suspension of active Brownian particles. The propelled particles exert a net reaction force on the solvent, and thereby either drive a measurable solvent flow from the connecting…
We show that in highly multimoded nonlinear photonic systems, the optical thermodynamic pressures emerging from different species of the optical field obey Dalton's law of partial pressures. In multimode settings, the optical thermodynamic…
For a two-phase (liquid-gas) two-component (water-hydrogen) system in porous media we discuss the formulation of the possible dissolution of hydrogen in the liquid phase. We show how Henry's law fits in a phase diagram. Then the problem is…
Experimental data were used to support a new concept of osmotic force and a new osmotic law that can explain the osmotic process without the difficulties encountered with van't Hoff osmotic pressure theory. Derived new osmotic formula with…
We introduce in this contribution the notion of partial Riemann problem. Recall that the Riemann problem describes a shock tube interaction between two given states ; the partial Riemann problem is a generalization of the previous concept…
We consider binary mixtures of fluids with components having different temperatures. A new dynamical pressure term is associated with the difference of temperatures between components even if fluid viscosities are null. The non-equilibrium…
We define the pressure of a porous medium in terms of the grand potential, and compute its value in a nano-confined or nano-porous medium, meaning a medium where thermodynamic equations need be adjusted for smallness. On the nano-scale, the…
This article presents a novel system of flow equations that models the pressure deficit of a reservoir considered as a triple continuous medium formed by the rock matrix, vugular medium and fracture. In non-conventional reservoirs, the…
Realistic equations of state valid in the whole state space of a multi-component mixture should satisfy at least three important constraints: (i) The Gibbs phase rule holds. (ii) At low densities, one can deduce a virial equation of state…
We study, from first principles, the pressure exerted by an active fluid of spherical particles on general boundaries in two dimensions. We show that, despite the non-uniform pressure along curved walls, an equation of state is recovered…
The well-known Wall theorem states a simple and precise relation among temperature, pressure and density of a fluid at contact with a confining hard wall in thermodynamic equilibrium. In this Letter we develop an extension of the Wall…
We report on generic relations between fractional flow and pressure in steady two-phase flow in porous media. The main result is a differential equation for fractional flow as a function of phase saturation. We infer this result from two…
We consider the surface pressure of a colloid-laden liquid interface. As micron-sized particles of suitable wettability can be irreversibly bound to the liquid interface on experimental timescales, we use the canonical ensemble to derive an…