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We derive an electron-vibration model Hamiltonian in a quantum chemical framework, and explore the extent to which such a Hamiltonian can capture key effects of nonadiabatic dynamics. The model Hamiltonian is a simple two-body operator, and…

Chemical Physics · Physics 2021-02-03 Thomas Dresselhaus , Callum B. A. Bungey , Peter J. Knowles , Frederick R. Manby

We consider quantum Hamiltonians of the form H(t)=H+V(t) where the spectrum of H is semibounded and discrete, and the eigenvalues behave as E_n~n^\alpha, with 0<\alpha<1. In particular, the gaps between successive eigenvalues decay as…

Mathematical Physics · Physics 2009-11-13 Pierre Duclos , Ondra Lev , Pavel Stovicek

We investigate the ground state energy of an electron coupled to a photon field. First, we regard the self-energy of a free electron, which we describe by the Pauli-Fierz Hamiltonian. We show that, in the case of small values of the…

Mathematical Physics · Physics 2016-11-23 Christian Hainzl

In this article, we consider fixed spin 1/2 particles interacting through the quantized electromagnetic field in a constant magnetic field. We give some asymptotic expansions for the ground state and the ground state energy of the…

Mathematical Physics · Physics 2016-03-29 Laurent Amour , Jean Nourrigat

The semirelativistic Hamiltonian H = \beta\sqrt{m^2 + p^2} + V(r), where V(r) is a central potential in R^3, is concave in p^2 and convex in p. This fact enables us to obtain complementary energy bounds for the discrete spectrum of H. By…

Mathematical Physics · Physics 2015-06-26 Richard L. Hall , Wolfgang Lucha , Franz F. Schoeberl

This paper extends work done to date on quantum computation by associating potentials with different types of computation steps. Quantum Turing machine Hamiltonians, generalized to include potentials, correspond to sums over tight binding…

Quantum Physics · Physics 2009-01-23 Paul Benioff

We introduce the notion of a "rigid" quantum system as a system with constant relative positions of its nuclei and constant relative distribution of the electrons with respect to the nuclei. In accordance with this definition, a molecule…

Mathematical Physics · Physics 2013-01-04 A. A. Kolpakov , A. G. Kolpakov

We formulate a set of conditions under which dynamics of a time-dependent quantum Hamiltonian are integrable. The main requirement is the existence of a nonabelian gauge field with zero curvature in the space of system parameters. Known…

Quantum Physics · Physics 2018-05-16 Nikolai A. Sinitsyn , Emil A. Yuzbashyan , Vladimir Y. Chernyak , Aniket Patra , Chen Sun

We study quantum chains whose Hamiltonians are perturbations by interactions of short range of a Hamiltonian that does not couple the degrees of freedom located at different sites of the chain and has a strictly positive energy gap above…

Mathematical Physics · Physics 2020-12-30 S. Del Vecchio , J. Fröhlich , A. Pizzo , S. Rossi

We investigate further the relationship between the entanglement spectrum of a composite many-body system and the energy spectrum of a subsystem making use of concepts of canonical thermodynamics. In many important cases the entanglement…

Statistical Mechanics · Physics 2014-10-07 John Schliemann

This paper addresses the question of whether Witten's proof of positive ADM energy for classical general relativity can be extended to give a proof of positive energy for a non-perturbative quantization of general relativity. To address…

General Relativity and Quantum Cosmology · Physics 2014-08-20 Lee Smolin

Two or more quantum systems are said to be in an entangled or non-factorisable state if their joint (supposedly pure) wave-function is not expressible as a product of individual wave functions but is instead a superposition of product…

Quantum Physics · Physics 2015-06-26 Thomas Durt

Described is n-level quantum system realized in the n-dimensional ''Hilbert'' space H with the scalar product G taken as a dynamical variable. The most general Lagrangian for the wave function and G is considered. Equations of motion and…

Mathematical Physics · Physics 2008-05-28 Vasyl Kovalchuk , Jan Jerzy Slawianowski

The vector bosons models including Standard Model (SM) are investigated in the framework of the Dirac Hamiltonian method with explicit resolving the Gauss constraints in order to eliminate variables with zero momenta and negative energy…

High Energy Physics - Theory · Physics 2007-05-23 B. M. Barbashov , L. A. Glinka , V. N. Pervushin , S. A. Shuvalov , A. F. Zakharov

We show that the Hamiltonian describing N nonrelativistic electrons with spin, interacting with the quantized radiation field and several fixed nuclei with total charge Z has a ground state when N <Z+1. The result holds for any value of the…

Mathematical Physics · Physics 2007-05-23 Elliott H. Lieb , Michael Loss

We compute the ground state energy of atoms and quantum dots with a large number N of electrons. Both systems are described by a non-relativistic Hamiltonian of electrons in a d-dimensional space. The electrons interact via the Coulomb…

Quantum Physics · Physics 2015-05-14 Hervé Kunz , Rico Rueedi

Interaction of a two-level atom with a single mode of electromagnetic field including Kerr nonlinearity for the field and intensity-dependent atom-field coupling is discussed. The Hamiltonian for the atom-field system is written in terms of…

Quantum Physics · Physics 2016-09-08 S. Sivakumar

We study the binding energies of spin-isospin saturated nuclei with nucleon number $8 \le A \le 100$ in semiclassical Monte Carlo many-body simulations. The model Hamiltonian consists of, (i) nucleon kinetic energy, (ii) a nucleon-nucleon…

Nuclear Theory · Physics 2008-11-26 M. Angeles Perez-Garcia , K. Tsushima , A. Valcarce

It is well known in classical mechanics that, the frequencies of a periodic system can be obtained rather easily through the action variable, without completely solving the equation of motion. The equivalent quantum action variable…

Quantum Physics · Physics 2008-02-03 R. S. Bhalla , A. K. Kapoor , P. K. Panigrahi

The motion of a system of particles under electromagnetic interaction is considered. Under the assumption that the force acting on an electric charge is given by the sum of the electromagnetic fields produced by any other charged particles…

General Physics · Physics 2007-05-23 O. Chavoya-Aceves