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Using the entropy $S$ as a reaction coordinate, we determine the free energy barrier associated with the formation of a liquid droplet from a supersaturated vapor for atomic and molecular fluids. For this purpose, we develop the $\mu VT-S$…

Statistical Mechanics · Physics 2021-08-25 Caroline Desgranges , Jerome Delhommelle

Nucleation is an out-of-equilibrium process, which can be strongly affected by the presence of external fields. In this letter, we report a simple extension of classical nucleation theory to systems submitted to an homogeneous shear flow.…

Statistical Mechanics · Physics 2013-06-17 Anatolii V. Mokshin , Bulat N. Galimzyanov , Jean-Louis Barrat

Contact freezing is a mode of atmospheric ice nucleation in which a collision between a dry ice nucleating particle (INP) and a water droplet results in considerably faster heterogeneous nucleation. The molecular mechanism of such…

Soft Condensed Matter · Physics 2021-01-29 Sarwar Hussain , Amir Haji-Akbari

The freezing/melting transition is at the heart of many natural and industrial processes. In the classical picture, the transition proceeds via the nucleation of the new phase, which has to overcome a barrier associated to the free energy…

Soft Condensed Matter · Physics 2024-08-28 Patrice Porion , Joël Puibasset

We investigate nuclear matter at finite temperature and density, including the formation of light clusters up to the alpha particle The novel feature of this work is to include the formation of clusters as well as their dissolution due to…

Nuclear Theory · Physics 2010-04-06 S. Typel , G. Röpke , T. Klähn , D. Blaschke , H. H. Wolter

We apply a recently introduced model for an independent-atom-like calculation of ion-impact electron transfer and ionization cross sections to proton collisions from water, neon, and carbon clusters. The model is based on a geometrical…

Atomic and Molecular Clusters · Physics 2018-12-20 Hans Jürgen Lüdde , Marko Horbatsch , Tom Kirchner

Having discovered a dimension mistake in two key formulas of the Classical Nucleation Theory (CNT) but wishing to remain in the style of this theory, we propose to approach nucleation on the basis of the Zeldovich unsteady rate formula,…

Statistical Mechanics · Physics 2018-03-12 Laurent-Charles Valdès , Frédéric Affouard

Clustering plays an important role in the structure of nuclei, especially for light nuclei in the $p$-shell. In nuclear cluster models these degrees of freedom are introduced explicitly. In the Resonating Group Method or in the Generator…

Nuclear Theory · Physics 2016-12-09 Hans Feldmeier , Thomas Neff

The classical theory of grain nucleation suffers from both theoretical and predictive deficiencies. We strive to alleviate these deficiencies in our understanding of dust formation and growth by utilizing an atomistic model of nucleation.…

Solar and Stellar Astrophysics · Physics 2016-11-04 Christopher Mauney , Davide Lazzati

The avoidance of water freezing is the holy grail in the cryopreservation of biological samples, food, and organs. Fast cooling rates are used to beat ice nucleation and avoid cell damage. This strategy can be enhanced by applying high…

A particular quantum phase transition (QPT) is studied at excited energies of light nuclei within the Semimicroscopic Algebraic Cluster Model (SACM), using a combination of catastrophe theory and a direct minimization of the potential. A…

Understanding the substructure of atomic nuclei, particularly the clustering of nucleons inside them, is essential for comprehending nuclear dynamics. Various cluster configurations can emerge depending on excitation energy, the number and…

I present a cluster Monte Carlo algorithm that gives direct access to the interface free energy of Ising models. The basic idea is to simulate an ensemble that consists of both configurations with periodic and with antiperiodic boundary…

High Energy Physics - Lattice · Physics 2009-10-22 Martin Hasenbusch

We systematically study the symmetry energy effects of the transition density $n_{\rm t}$ and the transition pressure $P_{\rm t}$ around the crust-core interface of a neutron star in the framework of the dynamical and the thermodynamical…

Nuclear Theory · Physics 2019-01-23 L. Tsaloukidis , Ch. Margaritis , Ch. C. Moustakidis

Nucleation, the birth of a stable cluster from disorder, is inherently stochastic. Yet up to date, there are no quantitative studies on NaCl nucleation that accounts for its stochastic nature. Here, we report the first stochastic treatment…

Crystal nucleation studies using hard-sphere and Lennard-Jones models have shown that the pressure within the nucleus is lower than that in the surrounding liquid. Here, we use the mechanical route to obtain it for an ice nucleus in…

Soft Condensed Matter · Physics 2025-11-26 Pablo Montero de Hijes , Kaihang Shi , Carlos Vega , Christoph Dellago

Crystallization and vitrification of tetrahedral liquids are important both from a fundamental and a technological point of view. Here, we study via extensive umbrella sampling Monte Carlo computer simulations the nucleation barriers for a…

Soft Condensed Matter · Physics 2015-05-28 Ivan Saika-Voivod , Flavio Romano , Francesco Sciortino

Capillarity approximation is used to study the free-energy landscape of nucleation when an intermediate metastable phase exists. The critical nucleus that corresponds to the saddle point of the free-energy landscape as well as the whole…

Materials Science · Physics 2015-05-27 Masao Iwamatsu

We study the nucleation of nearly-hard charged colloidal particles. We use Monte Carlo simulations in combination with free-energy calculations to accurately predict the phase diagrams of these particles and map them via the freezing…

Soft Condensed Matter · Physics 2024-06-12 Marjolein de Jager , Laura Filion

Heterogeneous nucleation of a new bulk phase on a flat substrate can be associated with the surface phase transition called wetting transition. When this bulk heterogeneous nucleation occurs on a completely-wettable flat substrate with a…

Soft Condensed Matter · Physics 2015-05-28 Masao Iwamatsu
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