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Following Hollins et al. [J. Phys.: Condens. Matter 29, 04LT01 (2017)], we invert the electronic ground state densities for various semiconducting and insulating solids calculated using several density functional approximations within the…

Chemical Physics · Physics 2025-11-05 Visagan Ravindran , Nikitas I. Gidopoulos , Stewart J. Clark

We report results from an efficient, robust, ab-initio method for self-consistent calculations of electronic and structural properties of Ge. Our non-relativistic calculations employed a generalized gradient approximation (GGA) potential…

Materials Science · Physics 2013-09-13 C. E. Ekuma , M. Jarrell , J. Moreno , G. L. Zhao , D. Bagayoko

The recent TASK meta-GGA density functional [Phys. Rev. Research, 1, 033082 (2019)] is constructed with an enhanced nonlocality in the generalized Kohn-Sham scheme, and therefore harbors great opportunities for band gap prediction. Although…

Materials Science · Physics 2021-06-30 Bimal Neupane , Hong Tang , Niraj K. Nepal , Santosh Adhikari , Adrienn Ruzsinszky

The structural, electronic, dielectric and vibrational properties of zinc-blende (ZB) InAs were studied within the framework of density functional theory (DFT) by employing local density approximation and norm-conserving pseudopotentials.…

Computational Physics · Physics 2021-02-03 Waqas Mahmood , Arfan Bukhtiar , Muhammad Haroon , Bing Dong

We report calculations of the electronic structure of CaB$_6$ using the weighted density approximation (WDA) to density functional theory. We find a semiconducting band structure with a sizable gap, in contrast to local density…

Strongly Correlated Electrons · Physics 2009-11-10 Z. Wu , D. J. Singh , R. E. Cohen

Employing the $G_0W_0$ approximation of Hedin's $GW$ approach one can obtain quasi-particle energies of extended systems and molecules with good accuracy. However, for many materials, semi-local exchange-correlation functionals are…

Materials Science · Physics 2016-12-21 Ronaldo Rodrigues Pela , Ute Werner , Dmitrii Nabok , Claudia Draxl

Using the hybrid exchange-correlation functional within the density-functional theory, we have systematically investigated the structural and electronic properties of MO (M = Be, Mg, Ca, Sr, Ba, Zn, Cd) in binary rocksalt (B1), zincblende…

Materials Science · Physics 2019-03-19 Jinying Yu , Mingke Zhang , Zihan Zhang , Shangwei Wang , Yelong Wu

We report density functional theory calculations on the crystal structure, elastic, lattice dynamics and electronic properties of iso-structural layered monoclinic alkali azides, LiN3 and NaN3. The effect of van der Waals interactions on…

Materials Science · Physics 2013-11-04 K. Ramesh Babu , G. Vaitheeswaran

An exchange-correlation energy functional beyond the local density approximation, based on the exchange-correlation kernel of the homogeneous electron gas and originally introduced by Kohn and Sham, is considered for electronic structure…

Condensed Matter · Physics 2016-08-31 Maurizia Palummo , Giovanni Onida , Rodolfo Del Sole

The structural and energetic properties of layered materials propose a challenge to density functional theory with common semilocal approximations to the exchange-correlation. By combining the most-widely used semilocal generalized gradient…

Materials Science · Physics 2017-02-22 Haowei Peng , John P. Perdew

The Kohn-Sham gaps of density functional theory (DFT) obtained in terms of local density approximation (LDA) or generalized gradient approximation (GGA) cannot be directly linked to the fundamental gaps of semiconductors, but in engineering…

Materials Science · Physics 2024-09-17 Hanli Cui , Shengxin Yang , Jun-Hui Yuan , Li-Heng Li , Fan Ye , Jinhai Huang , Kan-Hao Xue , Xiangshui Miao

We present a new paradigm for the design of exchange-correlation functionals in density-functional theory. Electron pairs are correlated explicitly by means of the recently developed second order Bethe-Goldstone equation (BGE2) approach.…

Materials Science · Physics 2018-10-19 Igor Ying Zhang , Patrick Rinke , John P. Perdew , Matthias Scheffler

An upper bound on the error probability of specific lattices, based on their distance-spectrum, is constructed. The derivation is accomplished using a simple alternative to the Minkowski-Hlawka mean-value theorem of the geometry of numbers.…

Information Theory · Computer Science 2013-01-03 Yuval Domb , Meir Feder

Energy band structures are calculated for the new superconductor MgB$_2$ and the related compounds by using the LDA and an FLAPW method. It is found that the strong three dimensional network in low-lying $\pi$ bands brings about two…

Superconductivity · Physics 2009-11-07 Hisatomo Harima

We report calculated, electronic and related properties of wurtzite and zinc blende gallium nitrides (w-GaN, zb-GaN). We employed a local density approximation (LDA) potential and the linear combination of atomic orbital (LCAO) formalism.…

Accurately modeling the electronic structure of materials is a persistent challenge to high-throughput screening. A promising means of balancing accuracy against computational cost are non-self-consistent calculations with hybrid…

Materials Science · Physics 2020-05-04 Jonathan M. Skelton , David S. D. Gunn , Sebastian Metz , Stephen C. Parker

Spin-filtered time-of-flight photoelectron momentum microscopy reveals a systematic variation of the band structure within a series of highly spin-polarized ferromagnetic Heusler compounds with increasing number of valence electrons…

Materials Science · Physics 2021-02-10 S. Chernov , C. Lidig , O. Fedchenko , M. Jourdan , G. Schönhense , H. J. Elmers

We present a metric-space approach to quantify the performance of density-functional approximations for interacting many-body systems and to explore the validity of the Hohenberg-Kohn-type theorem on fermionic lattices. This theorem…

Quantum Physics · Physics 2018-03-06 V. V. França , J. P. Coe , I. D'Amico

The band gaps of a few selected semiconductors/insulators are obtained from the self-consistent solution of the Hedin's equations. Two different schemes to include the vertex corrections are studied: (i) the vertex function of the…

Strongly Correlated Electrons · Physics 2017-05-17 Andrey L. Kutepov

For materials of varying band gap, we compare energy levels of atomically localized defects calculated within a semilocal and a hybrid density-functional scheme. Since the latter scheme partially relieves the band gap problem, our study…

Materials Science · Physics 2008-07-30 Audrius Alkauskas , Peter Broqvist , Alfredo Pasquarello