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Orbital-free density functional theory (OF-DFT) runs at low computational cost that scales linearly with the number of simulated atoms, making it suitable for large-scale material simulations. It is generally considered that OF-DFT strictly…

Materials Science · Physics 2022-04-05 Qiang Xu , Cheng Ma , Wenhui Mi , Yanchao Wang , Yanming Ma

The formalism of density functional theory (DFT) can be easily extended to the time dependent case (TDDFT). However, while in the static case the theory is well established and is expected to be, at least in principle, an exact approach for…

Condensed Matter · Physics 2007-05-23 Sandro Stringari

We present systematic quantitative description of the magnetoconductance of the split-gate quantum wires. Accounting for the exchange and correlation interactions within the spin density function theory (DFT) leads to the lifting of the…

Mesoscale and Nanoscale Physics · Physics 2009-05-26 I. V. Zozoulenko , S. Ihnatsenko

One of the central problems in quantum mechanics is to determine the ground state properties of a system of electrons interacting via the Coulomb potential. Since its introduction by Hohenberg, Kohn, and Sham, Density Functional Theory…

Quantum Physics · Physics 2010-09-28 Norbert Schuch , Frank Verstraete

Quantum mechanical methods based on the density functional theory (DFT) offer a realistic possibility of first-principles design of organic donor-acceptor systems and engineered band-gap materials. This promise is contingent upon the…

Chemical Physics · Physics 2013-12-03 Marcin Modrzejewski , Grzegorz Chałasiński , Małgorzata M. Szczęśniak

Dynamical Mean Field Theory (DMFT) is a successful method to compute the electronic structure of strongly correlated materials, especially when it is combined with density functional theory (DFT). Here, we present an open-source…

Strongly Correlated Electrons · Physics 2021-02-03 Vijay Singh , Uthpala Herath , Benny Wah , Xingyu Liao , Aldo H. Romero , Hyowon Park

We present a density-functional theory (DFT) approach to the study of the phase diagram of the maximum density droplet (MDD) in two-dimensional quantum dots in a magnetic field. Within the lowest Landau level (LLL) approximation, analytical…

Mesoscale and Nanoscale Physics · Physics 2009-10-30 M. Ferconi , G. Vignale

Static correlation is a difficult problem for density-functional theory (DFT) as it arises in cases of degenerate or quasi-degenerate states where a multideterminantal wave function provides the simplest reasonable first approximation to…

Chemical Physics · Physics 2024-01-01 Abraham Ponra , Carolyne Bakasa , Anne Justine Etindele , Mark E. Casida

We generalize the recently developped "internal" Density Functional Theory (DFT) and Kohn-Sham scheme to multicomponent systems. We obtain a general formalism, applicable for the description of multicomponent self-bound systems (as…

Quantum Physics · Physics 2015-03-19 Jeremie Messud

This article is a rough, quirky overview of both the history and present state of the art of density functional theory. The field is so huge that no attempt to be comprehensive is made. We focus on the underlying exact theory, the origin of…

Chemical Physics · Physics 2015-05-20 Aurora Pribram-Jones , David A. Gross , Kieron Burke

This chapter introduces thermal density functional theory, starting from the ground-state theory and assuming a background in quantum mechanics and statistical mechanics. We review the foundations of density functional theory (DFT) by…

Chemical Physics · Physics 2014-06-02 Aurora Pribram-Jones , Stefano Pittalis , E. K. U. Gross , Kieron Burke

Unlike covalent two-dimensional (2D) materials like graphene, 2D metals have non-layered structures due to their non-directional, metallic bonding. While experiments on 2D metals are still scarce and challenging, density-functional theory…

Materials Science · Physics 2023-01-06 Kameyab Raza Abidi , Pekka Koskinen

Density-functional theory is used to study the electronic structure of quantum dots in a magnetic field. New series of magic numbers are found for the total angular momentum of electrons. The empirical formula for the plateau width is…

Mesoscale and Nanoscale Physics · Physics 2022-09-13 A. A. Vasilchenko

We have formulated and implemented a fully charge-self-consistent density functional theory plus dynamical mean field theory methodology which enables an efficient calculation of the total energy of realistic correlated electron systems.…

Strongly Correlated Electrons · Physics 2015-06-22 Hyowon Park , Andrew J. Millis , Chris A. Marianetti

Ensemble density functional theory (EDFT) is a promising alternative to time-dependent density functional theory for computing electronic excitation energies. Using coordinate scaling, we prove several fundamental exact conditions in EDFT…

Strongly Correlated Electrons · Physics 2023-07-04 Thais R. Scott , John Kozlowski , Steven Crisostomo , Aurora Pribram-Jones , Kieron Burke

Calculating perturbation response properties of materials from first principles provides a vital link between theory and experiment, but is bottlenecked by the high computational cost. Here a general framework is proposed to perform density…

Computational Physics · Physics 2024-03-01 He Li , Zechen Tang , Jingheng Fu , Wen-Han Dong , Nianlong Zou , Xiaoxun Gong , Wenhui Duan , Yong Xu

Nowdays, modern microscopic approaches for fission are generally based on the framework of nuclear density functional theory (DFT), which has enabled a self-consistent treatment of both static and dynamic aspects of fission. The key issue…

Nuclear Theory · Physics 2023-09-08 Zeyu Li , Shengyuan Chen , Minghui Zhou , Yongjing Chen , Zhipan Li

Reliable calculations of the structure of heavy elements are crucial to address fundamental science questions such as the origin of the elements in the universe. Applications relevant for energy production, medicine, or national security…

We present in full detail a newly developed formalism enabling density functional perturbation theory (DFPT) calculations from a DFT+$U$ ground state. The implementation includes ultrasoft pseudopotentials and is valid for both insulating…

Strongly Correlated Electrons · Physics 2020-02-21 Andrea Floris , Iurii Timrov , Burak Himmetoglu , Nicola Marzari , Stefano de Gironcoli , Matteo Cococcioni

We present a comparative study of the spatial distribution of the spin density (SD) of the ground state of CuCl2 using Density Functional Theory (DFT), quantum Monte Carlo (QMC), and post-Hartree-Fock wavefunction theory (WFT). A number of…

Chemical Physics · Physics 2016-07-25 Michel Caffarel , Emmanuel Giner , Anthony Scemama , Alejandro Ramírez-Solís