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One particle in a classical perfect gas is driven out of equilibrium by changing its mass over a short time interval. The work done on the driven particle depends on its collisions with the other particles in the gas. This model thus…

Statistical Mechanics · Physics 2014-04-22 T. G. Philbin , J. Anders

The interest in active matter stimulates the need to generalize thermodynamic description and relations to active matter systems, which are intrinsically out of equilibrium. One important example is the Jarzynski relation, which links the…

Statistical Mechanics · Physics 2023-05-31 Grzegorz Szamel

In conventional thermodynamics, it is widely acknowledged that the realization of an isothermal process for a system requires a quasi-static controlling protocol. Here we propose and design a strategy to realize a finite-rate isothermal…

Statistical Mechanics · Physics 2017-07-25 Geng Li , H. T. Quan , Z. C. Tu

The presence of multiplicative noise can alter measurements of forces acting on nanoscopic objects. Taking into account of multiplicative noise, we derive a series of non-equilibrium thermodynamical equalities as generalization of the…

Statistical Mechanics · Physics 2015-06-18 Ying Tang , Ruoshi Yuan , Ping Ao

Research on the out-of-equilibrium dynamics of quantum systems has so far produced important statements on the thermodynamics of small systems undergoing quantum mechanical evolutions. Key examples are provided by the Crooks and Jarzynski…

Recently, Jarzynski suggested a striking thermodynamic equation that relates free energy change of a system and work done on the system during arbitrary nonequilibrium processes, which has been believed to hold irrespective of detailed…

Statistical Mechanics · Physics 2016-08-31 Jaeyoung Sung

Using equilibrium fluctuations to understand the response of a physical system to an externally imposed perturbation is the basis for linear response theory, which is widely used to interpret experiments and shed light on microscopic…

Statistical Mechanics · Physics 2024-06-24 Jérémie Klinger , Grant M. Rotskoff

We present some aspects of the fidelity approach to phase transitions based on lower and upper bounds on the fidelity susceptibility that are expressed in terms of thermodynamic quantities. Both commutative and non commutative cases are…

Statistical Mechanics · Physics 2012-10-02 N. S. Tonchev , J. G. Brankov

Five previously unknown inequalities relating equilibrium free energy differences and non-equilibrium work fluctuations are derived, and lucid path to derivation of many similar inequalities is presented. These results are based upon…

Statistical Mechanics · Physics 2011-05-24 Alexander Davydov

The computation of free energy differences through an exponential weighting of out of equilibrium paths (known as the Jarzynski equality) is often used for transitions between states described by an external parameter $\lambda$ in the…

Statistical Mechanics · Physics 2015-06-25 Tony Lelievre , Mathias Rousset , Gabriel Stoltz

We derive a functional for the entropy contributed by any microscopic degrees of freedom as arising from their measurable pair correlations. Applicable both in and out of equilibrium, this functional yields the maximum entropy which a…

Statistical Mechanics · Physics 2023-02-17 Benjamin Sorkin , Joshua Ricouvier , Haim Diamant , Gil Ariel

Recently there has been growing interest in extending the thermodynamic method from static configurations to dynamical trajectories. In this approach, ensembles of trajectories are treated in an analogous manner to ensembles of…

Statistical Mechanics · Physics 2016-08-23 Robert M. Turner , Thomas Speck , Juan P. Garrahan

In equilibrium systems with short-ranged interactions, the relative stability of different thermodynamic states generally does not depend on system size (as long as this size is larger than the interaction range). Here, we use a large…

Statistical Mechanics · Physics 2013-05-30 Sorin Tanase-Nicola , David K. Lubensky

It is shown that the work fluctuations and work distribution functions are fundamentally different in systems with short-range versus long-range correlations. The two cases considered with long- range correlations are magnetic work…

Statistical Mechanics · Physics 2017-07-26 T. R. Kirkpatrick , J. K. Bhattacherjee , J. V. Sengers

We derive the nonequilibrium transient state work fluctuation theorem and also the Jarzynski equality for a classical harmonic oscillator linearly coupled to a harmonic heat bath, which is dragged by an external agent. Coupling with the…

Statistical Mechanics · Physics 2012-07-09 Rajarshi Chakrabarti

The characteristic function of the work performed by an external time-dependent force on a Hamiltonian quantum system is identified with the time-ordered correlation function of the exponentiated system's Hamiltonian. A similar expression…

Statistical Mechanics · Physics 2009-11-13 Peter Talkner , Eric Lutz , Peter Hanggi

We consider a single Josephson junction in the presence of time varying gate charge, and examine the nonequilibrium work done by the charge control in the framework of fluctuation theorems. We obtain the probability distribution functions…

Statistical Mechanics · Physics 2013-02-07 Su Do Yi , Beom Jun Kim , Juyeon Yi

The two-time measurement scheme is well studied in the context of quantum fluctuation theorem. However, it becomes infeasible when the random variable determined by a single measurement trajectory is associated with the von-Neumann entropy…

Quantum Physics · Physics 2023-04-20 Akira Sone , Naoki Yamamoto , Tharon Holdsworth , Prineha Narang

We study the motion of an overdamped colloidal particle in a time-dependent non-harmonic potential. We demonstrate the first law-like balance between applied work, exchanged heat, and internal energy on the level of a single trajectory. The…

Statistical Mechanics · Physics 2007-05-23 V. Blickle , T. Speck , L. Helden , U. Seifert , C. Bechinger

Diffusive motion in an externally driven potential is considered. It is shown that the distribution of work required to drive the system from an initial equilibrium state to another is Gaussian for slow but finite driving. Our result is…

Statistical Mechanics · Physics 2007-05-23 Thomas Speck , Udo Seifert