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A generalization of the Density Functional Theory is proposed. The theory developed leads to single-particle equations of motion with a quasi-local mean-field operator, which contains a quasi-particle position-dependent effective mass and a…

Nuclear Theory · Physics 2009-11-07 V. B. Soubbotin , V. I. Tselyaev , X. Vinas

We introduce a Path Integral Monte Carlo (PIMC) approach that uses the angular momentum representation for the description of interacting rotor systems. Such a choice of representation allows the calculation of momentum properties without…

Chemical Physics · Physics 2025-10-22 Estêvão de Oliveira , Muhammad Shaeer Moeed , Pierre-Nicholas Roy

The ab initio simulation of charged interfaces in the framework of density functional theory (DFT) is heavily employed for the study of electrochemical energy conversion processes. The capacitance is the primary descriptor for the response…

Materials Science · Physics 2022-04-26 Tobias Binninger

The variational and diffusion quantum Monte Carlo methods are used to calculate the correlation energy of the paramagnetic three-dimensional homogeneous electron gas at intermediate to high density. Ground state energies in finite cells are…

Strongly Correlated Electrons · Physics 2023-03-29 Sam Azadi , N. D. Drummond , S. M. Vinko

The constrained-search formulation of Levy and Lieb provides a concrete mapping from N-representable densities to the space of N-particle wavefunctions and explicitly defines the universal functional of density functional theory. We…

Strongly Correlated Electrons · Physics 2022-10-19 C. D. Pemmaraju , Amol Deshmukh

We develop a semiclassical density functional theory in the context of quantum dots. Coulomb blockade conductance oscillations have been measured in several experiments using nanostructured quantum dots. The statistical properties of these…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Denis Ullmo , Tatsuro Nagano , Steven Tomsovic , Harold U. Baranger

Quantum Monte Carlo methods are used to calculate various ground state properties of charged bosons in two dimensions, throughout the whole density range where the fluid phase is stable. Wigner crystallization is predicted at $r_s\simeq…

Condensed Matter · Physics 2018-05-01 S. De Palo , S. Conti , S. Moroni

We use variational quantum Monte Carlo to calculate the density-functional exchange-correlation hole n_{xc}, the exchange-correlation energy density e_{xc}, and the total exchange-correlation energy E_{xc}, of several electron gas systems…

Materials Science · Physics 2009-10-31 Maziar Nekovee , W. M. C. Foulkes , R. J. Needs

We carry out highly accurate \emph{ab initio} path integral Monte Carlo (PIMC) simulations to directly estimate the free energy of various warm dense matter systems including the uniform electron gas and hydrogen without any nodal…

Quantum Gases · Physics 2024-07-02 Tobias Dornheim , Zhandos Moldabekov , Sebastian Schwalbe , Jan Vorberger

The Breit correction, the finite-light-speed correction for the Coulomb interaction of the electron-electron interaction in $ O \left( 1/ c^2 \right) $, is introduced to density functional theory (DFT) based on the non-relativistic…

Computational Physics · Physics 2020-10-20 Tomoya Naito , Ryosuke Akashi , Haozhao Liang , Shinji Tsuneyuki

In a recent Letter [T. Dornheim et al., Phys. Rev. Lett. 121, 255001 (2018)] we have presented the first ab initio results for the dynamic structure factor $S(\mathbf{q},\omega)$ of the uniform electron gas for conditions ranging from the…

Plasma Physics · Physics 2019-06-19 Simon Groth , Tobias Dornheim , Jan Vorberger

Some theorems on derivatives of the Coulomb density functional with respect to the coupling constant $\lambda$ are given. Consider an electron density $n_{GS}({\bf r})$ given by a ground state. A model Fermion system with the reduced…

Statistical Mechanics · Physics 2015-05-20 Koichi Kusakabe , Isao Maruyama

The ground state properties of a single-component one-dimensional Coulomb gas are investigated. We use Bose-Fermi mapping for the ground state wave function which permits to solve the Fermi sign problem in the following respects (i) the…

Quantum Gases · Physics 2014-03-31 G. E. Astrakharchik , M. D. Girardeau

A density-functional theory is developed based on the Maxwell--Schr\"odinger equation with an internal magnetic field in addition to the external electromagnetic potentials. The basic variables of this theory are the electron density and…

Chemical Physics · Physics 2018-01-17 Erik Tellgren

In the last few years we have been developing a Monte Carlo simulation method to cope with systems of many electrons and ions in the Born-Oppenheimer (BO) approximation, the Coupled Electron-Ion Monte Carlo Method (CEIMC). Electronic…

Computational Physics · Physics 2007-05-23 Carlo Pierleoni , David M. Ceperley

We develop a path integral approach to quantum field theory that is defined over the paths of the Le'vy flights possessing a fractal dimension $1<d_f<2$. In standard quantum field theory, the fractality of the Brownian trajectories lead to…

High Energy Physics - Theory · Physics 2024-11-18 Zheng-Wei Cheng , You-Kai Wang , Xia Wan

The practical success of density functional theory (DFT) is largely credited to the Kohn-Sham approach, which enables the exact calculation of the non-interacting electron kinetic energy via an auxiliary noninteracting system. Yet, the…

Computational Physics · Physics 2025-03-21 Sangita Majumdar , Zekun Shi , Giovanni Vignale

Conditional-probability density functional theory (CP-DFT) is a formally exact method for finding correlation energies from Kohn-Sham DFT without evaluating an explicit energy functional. We present details on how to generate accurate…

Chemical Physics · Physics 2022-05-04 Dennis Perchak , Ryan J. McCarty , Kieron Burke

An analysis shows that the ground state of the inhomogeneous system of interacting electrons in the static external field, which satisfies the thermodynamic limit, can be consistently described only using the Green function theory based on…

Statistical Mechanics · Physics 2014-09-02 V. B. Bobrov

In [Phys. Rev. Lett. 128, 013001 (2022)] a novel ground state method was proposed. It has been suggested that this $i$-DMFT would be a method within one-particle reduced density matrix functional theory (DMFT), capable of describing…

Quantum Physics · Physics 2022-02-14 Lexin Ding , Julia Liebert , Christian Schilling
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