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Amine terminated molecules show well behaved conductance in the scanning tunneling microscope break-junction experimental measurements. We performed density functional theory based electron transport calculations to explain the nature of…

Materials Science · Physics 2007-10-17 Zhenyu Li , D. S. Kosov

We present an atomistic theory of electronic transport through single organic molecules that reproduces the important features of the current-voltage characteristics observed in recent experiments. We trace these features to their origin in…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 J. Heurich , J. C. Cuevas , W. Wenzel , G. Schoen

Results of an experimental study of palladium nanojunctions in hydrogen environment are presented. Two new hydrogen-related atomic configurations are found, which have a conductances of ~0.5 and ~1 quantum unit (2e^2/h). Phonon spectrum…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Sz. Csonka , A. Halbritter , G. Mihaly , O. I. Shklyarevskii , S. Speller , H. van Kempen

The low conductance of nickel atomic junctions in the hydrogen environment is studied using the nonequilibrium Green's function theory combined with first-principles calculations. The Ni junction bridged by a $H_2$ molecule has a…

Mesoscale and Nanoscale Physics · Physics 2016-12-23 Shuaishuai Li , Yi-Qun Xie , Yibin Hu

A single molecule break junction device serves as a tunable model system for probing the many body Kondo state. The low-energy properties of this state are commonly described in terms of a Kondo model, where the response of the system to…

Strongly Correlated Electrons · Physics 2013-06-28 Gavin D. Scott , Douglas Natelson , Stefan Kirchner , Enrique Muñoz

Molecules of bisthiolterthiophene have been adsorbed on the two facing gold electrodes of a mechanically controllable break junction in order to form metal-molecule(s)-metal junctions. Current-voltage (I-V) characteristics have been…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 C. Kergueris , J. -P. Bourgoin , S. Palacin , D. Esteve , C. Urbina , M. Magoga , C. Joachim

Superconducting tunnel junctions are being developed for application as photon detectors in astronomy. We present the latest results on the development of very high quality, very low critical temperature junctions, fabricated out of pure Al…

Superconductivity · Physics 2009-11-10 G. Brammertz , P. Verhoeve , D. Martin , A. Peacock , R. Venn

The effect of anchoring group on the electrical conductance of a single molecule bridging two Au electrodes was studied using di-substituted (isocyanide (CN-), thiol (S-) or cyanide (NC-)) benzene. The conductance of a single…

Materials Science · Physics 2009-11-11 Manabu Kiguchi , Shinichi Miura , Kenji Hara , Masaya Sawamura , Kei Murakoshi

A current constrained approach is proposed to calculate negative differential conductance in molecular nano-junctions. A four-site junction is considered where a steady-state current is forced by inserting only the two central sites within…

Mesoscale and Nanoscale Physics · Physics 2016-11-26 Prakash Parida , Swapan K. Pati , Anna Painelli

This review presents recent results on the physics of electron transport in molecular devices. The review is organized as follows. A brief description of molecular junction (MJ) technology is first given followed by an introduction to the…

Mesoscale and Nanoscale Physics · Physics 2021-11-23 Dominique Vuillaume

Electronic conduction at the atomic scale can be described by Landauer's formalism. In single atom point contacts of noble metals like Au and Ag, there is just one channel open between both electrodes and the conductance is very close to…

We carry out experiments on single-molecule junctions at low temperatures, using the mechanically controlled break junction technique. Analyzing the results received with more than ten different molecules the nature of the first peak in the…

Mesoscale and Nanoscale Physics · Physics 2012-03-21 Daniel Secker , Stefan Wagner , Stefan Ballmann , Rainer Härtle , Michael Thoss , Heiko B. Weber

We investigate transport properties of molecular junctions under two types of bias--a short time pulse or an AC bias--by combining a solution for the Green functions in the time domain with electronic structure information coming from ab…

Mesoscale and Nanoscale Physics · Physics 2010-06-18 San-Huang Ke , Rui Liu , Weitao Yang , Harold U. Baranger

Combining density functional theory calculations for molecular electronic structure with a Green function method for electron transport, we calculate from first principles the molecular conductance of benzene connected to two Au leads…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 San-Huang Ke , Harold U. Baranger , Weitao Yang

This tutorial article presents a "bottom-up" view of electrical resistance starting from something really small, like a molecule, and then discussing the issues that arises as we move to bigger conductors. Remarkably, no serious quantum…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Supriyo Datta

We calculate the conductance through double junctions of the type M(inf.)-Sn-Mm-Sn-M(inf.) and triple junctions of the type M(inf.)-Sn-Mm-Sn-Mm-Sn-M(inf.), where M(inf.) are semi-infinite metallic electrodes, Sn are 'n' layers of…

Mesoscale and Nanoscale Physics · Physics 2008-10-03 J. Peralta-Ramos , A. M. Llois

We have carried out calculations of electron transport through a metal-molecule-metal junction with metal nanoclusters taking the part of electrodes. We show that negative differential resistance peaks could appear in the current-voltage…

Materials Science · Physics 2008-10-22 Natalya A. Zimbovskaya , Mark R. Pederson

We analyze the formation and evolution statistics of single molecule junctions bonded to gold electrodes using amine, methyl sulfide and dimethyl phosphine link groups by measuring conductance as a function of junction elongation. For each…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 M. Kamenetska , M. Koentopp , A. C. Whalley , Y. S. Park , M. L. Steigerwald , C. Nuckolls , M. S. Hybertsen , L. Venkataraman

Single atom junctions between superconducting niobium leads are produced using the Mechanically Controllable Break Junction technique. The current-voltage characteristics of these junctions are analysed using an exact formulation for a…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 B. Ludoph , N. van der Post , E. N. Bratus' , E. V. Bezuglyi , V. S. Shumeiko , G. Wendin , J. M. van Ruitenbeek

The anchoring of the molecule to an electrode is known to be a key factor in single-molecule spintronics experiments. Likewise, a relaxation down to the most stable geometry is a critical step in theoretical simulations of transport through…

Mesoscale and Nanoscale Physics · Physics 2019-06-18 Silvia Giménez-Santamarina , Salvador Cardona-Serra , Alejandro Gaita-Ariño