Related papers: UV-driven chemistry in simulations of the interste…
Modern observations of the interstellar medium (ISM) in galaxies detect a variety of atomic and molecular species. The goal is to connect these observations to the astrochemical properties of the ISM. 3D hydro-chemical simulations attempt…
Transient microstructure in the diffuse interstellar medium has been observed towards galactic and extragalactic sources for decades, usually in lines of atoms and ions, and, more recently, in molecular lines. Evidently, there is a…
There is a robust polyatomic chemistry in diffuse, partially-molecular interstellar gas that is readily accessible in absorption at radio/mm/sub-mm wavelengths. Accurate column densities are derived owing to the weak internal excitation, so…
We present a semi-analytical description of the relative HD/H2 abundance in the diffuse interstellar medium. We found three asymptotics of the relative HD/H$_2$ abundance for different parts of the medium and their dependence on the…
We report the first ensemble results from the FUSE survey of molecular hydrogen in lines of sight with A_V $\gtrsim$ 1 mag. We have developed techniques for fitting computed profiles to the low-J lines of H2, and thus determining column…
We have constructed three-dimensional models for the equilibrium abundance of molecular hydrogen within diffuse interstellar clouds of arbitrary geometry that are illuminated by ultraviolet radiation. The position-dependent photo-…
Chemistry plays an important role in the interstellar medium (ISM), regulating heating and cooling of the gas, and determining abundances of molecular species that trace gas properties in observations. Although solving the time-dependent…
Molecular hydrogen being unobservable in cold molecular clouds, the column density measurements of molecular gas currently rely either on dust emission observation in the far-IR or on star counting. (Sub-)millimeter observations of numerous…
We have used archival far-ultraviolet spectra from observations made by HST/STIS and FUSE to determine the column densities and rotational excitation temperatures for CO and H2, respectively, along the lines of sight to 23 Galactic O and B…
Carbon monoxide (CO) is a poor tracer of H$_{2}$ in the diffuse interstellar medium (ISM), where most of the carbon is not incorporated into CO molecules unlike the situation at higher extinctions. We present a novel, indirect method to…
We present column density measurements of the HD molecule in the interstellar gas toward 17 Galactic stars. The values for the seven most heavily reddened sightlines, with E(B-V) = 0.38-0.72, are derived from observations with the Far…
We use 3D-PDR, a three-dimensional astrochemistry code for modeling photodissociation regions (PDRs), to post-process hydrodynamic simulations of turbulent, star-forming clouds. We focus on the transition from atomic to molecular gas, with…
While the best tracer of the molecular component and its dynamics in galaxies is the CO molecule, which excitation is revealed by its isotopic and (2-1)/(1-0) ratios, the denser gas is revealed by molecules such as HCN, HNC, HCO+ or CN,…
The presence of dust can strongly affect the chemical composition of the interstellar medium. We model the chemistry in photodissociation regions (PDRs) using both gas-phase and dust-phase chemical reactions. Our aim is to determine the…
Context. Mon R2 is the only ultracompact HII region (UCHII) where the associated photon-dominated region (PDR) can be resolved with Herschel. Due to its brightness and proximity, it is the best source to investigate the chemistry and…
Aims. We model a diffuse molecular cloud present along the line of sight to the star HD 102065. We compare our modeling with observations to test our understanding of physical conditions and chemistry in diffuse molecular clouds. Methods.…
We compare observations of HI from the Very Large Array (VLA) and the Arecibo Observatory and observations of HCO$^+$ from the Atacama Large Millimeter/submillimeter Array (ALMA) and the Northern Extended Millimeter Array (NOEMA) in the…
Molecular oxygen has been the subject of many observational searches as chemical models predicted it to be a reservoir of oxygen. Although it has been detected in two regions of the interstellar medium, its rarity is a challenge for…
We present a far-ultraviolet (PDR) and an X-ray dominated region (XDR) code. We include and discuss thermal and chemical processes that pertain to irradiated gas. An elaborate chemical network is used and a careful treatment of PAHs and H2…
We present a comparison between independent computer codes, modeling the physics and chemistry of interstellar photon dominated regions (PDRs). Our goal was to understand the mutual differences in the PDR codes and their effects on the…