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The charge-memory effect, bistability and switching between charged and neutral states of a molecular junction, as observed in recent STM experiments, is considered within a minimal polaron model. We show that in the case of strong…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Dmitry A. Ryndyk , Pino D'Amico , Gianaurelio Cuniberti , Klaus Richter

We analyze a single-level quantum system placed between metallic leads and strongly coupled to a localized vibrational mode, which models a singlemolecule junction or an STM setup. We consider a polaron model describing the interaction…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Pino D'Amico , Dmitry A. Ryndyk , Gianaurelio Cuniberti , Klaus Richter

We theoretically examine the effect of the coupling of the transport electrons to a vibrational mode of the molecule on the ac linear-response conductance of molecular junctions. Representing the molecule by a single electronic state, we…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 A. Ueda , O. Entin-Wohlman , A. Aharony

The interaction between electronic and vibrational degrees of freedom is an important mechanism in nonequilibrium charge transport through molecular nanojunctions. While adiabatic polaron-type coupling has been studied in great detail, new…

Mesoscale and Nanoscale Physics · Physics 2022-06-10 Christoph Kaspar , André Erpenbeck , Jakob Bätge , Christian Schinabeck , Michael Thoss

The single-spin memory effect is considered within a minimal polaron model describing a single-level quantum dot interacting with a vibron and weakly coupled to ferromagnetic leads. We show that in the case of strong electron-vibron and…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 Dmitry A. Ryndyk , Pino D'Amico , Klaus Richter

We investigate the transient nonequilibrium dynamics of a molecular junction biased by a finite voltage and strongly coupled to internal vibrational degrees of freedom. Using two different, numerical exact techniques, diagrammatic Monte…

Mesoscale and Nanoscale Physics · Physics 2012-10-05 Klaus Ferdinand Albrecht , Haobin Wang , Lothar Muehlbacher , Michael Thoss , Andreas Komnik

The interaction between electronic and vibrational degrees of freedom in single-molecule junctions may result from the dependence of the electronic energies or the electronic states of the molecular bridge on the nuclear displacement. The…

Mesoscale and Nanoscale Physics · Physics 2015-06-09 A. Erpenbeck , R. Härtle , M. Thoss

In a nanoscale molecular junction at finite bias voltage,the intra-molecular distribution of vibrational energy can strongly deviate from the thermal equilibrium distribution and specific vibrational modes can be selectively excited in a…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 Rainer Härtle , Roie Volkovich , Michael Thoss , Uri Peskin

Vibrational nonequilibrium effects in charge transport through single-molecule junctions are investigated. Focusing on molecular bridges with multiple electronic states, it is shown that electronic-vibrational coupling triggers a variety of…

Mesoscale and Nanoscale Physics · Physics 2011-03-15 R. Härtle , C. Benesch , M. Thoss

The coupling of the charge carriers passing through a molecule bridging two bulky conductors with local vibrational modes of the molecule, gives rise to distinct features in the electronic transport properties on one hand, and to…

Mesoscale and Nanoscale Physics · Physics 2017-02-01 A. Ueda , Y. Utsumi , Y. Tokura , O. Entin-Wohlman , A. Aharony

The relaxation of stochastic systems after sudden perturbations is constrained by speed limits and often reveals memory effects that hinder attempts to accelerate their dynamics. Here we demonstrate Kovacs-type nonmonotonic relaxation in…

Soft Condensed Matter · Physics 2026-03-16 Miguel Ibáñez , Raúl A. Rica-Alarcón , María L. Jiménez

For the study of molecular spin junctions, we take into account two types of couplings between the molecule and the metal leads: (i) electron transfer that gives rise to net current in the biased junction and (ii) energy transfer between…

Mesoscale and Nanoscale Physics · Physics 2009-04-23 M. Jouravlev , Kwang S. Kim

The treatment of the previous paper is extended to molecular wires. Specifically, the effect of electron-vibrational interactions on the electronic transport induced by femtosecond $\omega+2\omega$ laser fields along unbiased molecular…

Quantum Physics · Physics 2009-11-13 Ignacio Franco , Moshe Shapiro , Paul Brumer

A theoretical model of a single molecule coupled to many vibronic modes is presented. At low energies, transport is dominated by electron-vibron processes where transfer of an electron through the dot is accompanied by the…

Mesoscale and Nanoscale Physics · Physics 2011-08-19 Abdullah Yar , Andrea Donarini , Sonja Koller , Milena Grifoni

A theoretical model of a single molecule coupled to many vibronic modes is presented. At low energies, transport is dominated by electron-vibron processes where transfer of an electron through the dot is accompanied by the…

Mesoscale and Nanoscale Physics · Physics 2015-03-17 Abdullah Yar , Andrea Donarini , Sonja Koller , Milena Grifoni

The role of local electron-vibration and electron-electron interactions on the thermoelectric properties of molecular junctions is theoretically analyzed focusing on devices based on fullerene molecules. A self-consistent adiabatic approach…

Mesoscale and Nanoscale Physics · Physics 2019-08-08 C. A. Perroni , V. Cataudella

Current-induced bond rupture is a fundamental process in nanoelectronic architectures such as molecular junctions and in scanning tunneling microscopy measurements of molecules at surfaces. The understanding of the underlying mechanisms is…

Mesoscale and Nanoscale Physics · Physics 2023-07-26 Yaling Ke , Jan Dvořák , Martin Čížek , Raffaele Borrelli , Michael Thoss

We propose a model for a molecular junction with internal anharmonic torsional vibrations interacting with an electric current. The Wangsness-Bloch-Redfield master equation approach is used to determine the stationary reduced density matrix…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 Ivan A. Pshenichnyuk , Martin Čížek

Single-molecule magnets weakly coupled to two ferromagnetic leads act as memory devices in electronic circuits---their response depends on history, not just on the instantaneous applied voltage. We show that magnetic anisotropy introduces a…

Mesoscale and Nanoscale Physics · Physics 2012-09-24 Carsten Timm , Massimiliano Di Ventra

Vibrational modes of molecules are fundamental properties determined by intramolecular bonding, atomic masses, and molecular geometry, and often serve as important channels for dissipation in nanoscale processes. Although single-molecule…

Mesoscale and Nanoscale Physics · Physics 2014-03-06 Y. Li , P. Doak , L. Kronik , J. B. Neaton , D. Natelson
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