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An implementation of coupled-cluster (CC) theory to treat atoms and molecules in finite magnetic fields is presented. The main challenges stem from the magnetic-field dependence in the Hamiltonian, or, more precisely, the appearance of the…

Chemical Physics · Physics 2015-09-02 Stella Stopkowicz , Jürgen Gauss , Kai K. Lange , Erik I. Tellgren , Trygve Helgaker

The dynamics governed by a requantized collective Hamiltonian in the coupled Lipkin model is investigated in the time-dependent variational approach with squeezed state. It is pointed out that there is a possibility of the parametric…

Nuclear Theory · Physics 2007-05-23 Y. Tsue , J. da Providencia , A. Kuriyama , M. Yamamura

We study classical Hamiltonian systems in which the intrinsic proper time evolution parameter is related through a probability distribution to the physical time, which is assumed to be discrete. In this way, a physical clock with discrete…

Quantum Physics · Physics 2007-05-23 H. -T. Elze

Time-space noncommutativity leads to quantisation of time and energy nonconservation when time is conjugate to a compact spatial direction like a circle. In this context energy is conserved only modulo some fixed unit. Such a possibility…

High Energy Physics - Theory · Physics 2010-10-27 A. P. Balachandran , A. G. Martins , P. Teotonio-Sobrinho

The classical and the quantal problem of a particle interacting in one-dimension with an external time-dependent quadratic potential and a constant inverse square potential is studied from the Lie-algebraic point of view. The integrability…

Exactly Solvable and Integrable Systems · Physics 2009-10-31 Jayendra N. Bandyopadhyay , A. Lakshminarayan , Vijay B. Sheorey

We derive equations of motion for bivariational wave functions with orthogonal adaptive basis sets and specialize the formalism to the coupled cluster ansatz. The equations are related to the biorthogonal case in a transparent way, and…

Chemical Physics · Physics 2023-11-06 Mads Greisen Højlund , Alberto Zoccante , Ove Christiansen

We discuss the one-dimensional, general quadratic Hamiltonian and the bi-dimensional charged particle in time-dependent electromagnetic fields through the Lie algebraic approach. Such method consists in finding a set of generators that form…

Quantum Physics · Physics 2015-02-19 V. G. Ibarra-Sierra , J. C. Sandoval-Santana , J. L. Cardoso , A. Kunold

We discuss a coupled-cluster formalism for carrying out imaginary-time evolution from an arbitrary reference, and study the properties of the resulting evolution trajectories. The evolution converges to a solution of the standard…

Chemical Physics · Physics 2026-04-09 Yuhang Ai , Huanchen Zhai , Garnet Kin-Lic Chan

We generalize the diffusion-limited aggregation by issuing many randomly-walking particles, which stick to a cluster at the discrete time unit providing its growth. Using simple combinatorial arguments we determine probabilities of…

Statistical Mechanics · Physics 2017-05-24 Oleg Alekseev , Mark Mineev-Weinstein

An electrodynamical coupled cluster (CC) methodology starting from a covariant formalism and an equal time approximation, and finally based on the Dirac-Fock picture of the electron and positron fields and Coulomb gauge, is given here. The…

Atomic Physics · Physics 2019-04-30 Sambhu N. Datta

We provide a new perspective on non-Hermitian evolution in quantum mechanics by emphasizing the same method as in the Hermitian quantum evolution. We first give a precise description of the non unitary evolution, and collecting the basic…

Quantum Physics · Physics 2017-07-21 Mustapha Maamache

Introducing an active space approximation is inevitable for the quantum computations of chemical systems. However, this approximation ignores the electron correlations related to non-active orbitals. Here, we propose a computational method…

Quantum Physics · Physics 2024-06-06 Luca Erhart , Yuichiro Yoshida , Viktor Khinevich , Wataru Mizukami

In this article the time evolution operator of two interacting quantum oscillators, whose Hamiltonian is an element of the complex $\left\{ h(1) \oplus h(1) \right\} \uplus u(2)$ algebra, is analyzed using the Feynman time ordering operator…

Quantum Physics · Physics 2023-07-20 Nibaldo-Edmundo Alvarez-Moraga

In this paper we propose a systematic method to solve the inverse dynamical problem for a quantum system governed by the von Neumann equation: to find a class of Hamiltonians reproducing a prescribed time evolution of a pure or mixed state…

Quantum Physics · Physics 2013-07-09 J Bernatska , A Messina

The time-dependent equation-of-motion coupled cluster (TD-EOM-CC) and time-dependent coupled cluster (TDCC) methods are compared by simulating Rabi oscillations for different numbers of non-interacting atoms in a classical electromagnetic…

Chemical Physics · Physics 2023-10-02 Andreas S. Skeidsvoll , Henrik Koch

Compared with time independent Hamiltonians, the dynamics of generic quantum Hamiltonians $H(t)$ are complicated by the presence of time ordering in the evolution operator. In the context of digital quantum simulation, this difficulty…

Quantum Physics · Physics 2024-04-08 Jacob Watkins , Nathan Wiebe , Alessandro Roggero , Dean Lee

The past two decades have seen a revolution in ab initio calculations of nuclear properties. One key element has been the development of a rigorous effective interaction theory, applying unitary transformations to soften the nuclear…

We propose a new formulation of time-dependent coupled cluster with adaptive basis functions and division of the one-particle space into active and secondary subspaces. The formalism is fully bivariational in the sense of a real-valued…

Chemical Physics · Physics 2024-02-20 Mads Greisen Højlund , Ove Christiansen

We consider time-dependent perturbations which are relatively bounded with respect to the square root of an unperturbed Hamiltonian operator, and whose commutator with the latter is controlled by the full perturbed Hamiltonian. The…

Mathematical Physics · Physics 2022-06-07 Giovanna Marcelli

Time evolution of a perturbed thermal state is studied in a quantum-mechanical system with O(N) symmetry. In the limit of large N, time dependence of O(N)-singlet expectation values can be described by classical equations of motion in a…

Quantum Physics · Physics 2009-03-26 P. V. Buividovich