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We describe instrumentation for a high-frequency electron paramagnetic resonance (EPR) and pulsed electron-electron double resonance (PELDOR) spectroscopy. The instrumentation is operated in the frequency range of 107$-$120 GHz and…

Instrumentation and Detectors · Physics 2015-06-19 Franklin H. Cho , Viktor Stepanov , Susumu Takahashi

The successful use of picosecond-pulse free-electron-laser (FEL) radiation for the continuous-wave THz-range electron spin resonance (ESR) spectroscopy has been demonstrated. The combination of two linac-based FELs (covering the wavelength…

Electron paramagnetic resonance (EPR) is a valuable tool for physics, chemistry, biology and medicine, providing complementary spectroscopic information to NMR. It has long been known that EPR at high magnetic fields offers greater spectral…

Electron paramagnetic resonance spectroscopy (EPR) is among the most important analytical tools in physics, chemistry, and biology. The emergence of nitrogen-vacancy (NV) centers in diamond, serving as an atomic-sized magnetometer, has…

Quantum Physics · Physics 2020-06-01 Fei Kong , Pengju Zhao , Pei Yu , Zhuoyang Qin , Zhehua Huang , Zhecheng Wang , Mengqi Wang , Fazhan Shi , Jiangfeng Du

Electron paramagnetic resonance (EPR) can provide unique insight into the chemical structure and magnetic properties of dopants in oxide and semiconducting materials that are of interest for applications in electronics, catalysis, and…

Electron paramagnetic resonance (EPR) spectroscopy is an important technology in physics, chemistry, materials science, and biology. Sensitive detection with a small sample volume is a key objective in these areas, because it is crucial,…

The Electron Paramagnetic Spectroscopy (EPR) is the most direct and powerful method for the detection and identification of free radicals and other species with unpaired electrons. Statistics disorders are a common gynaecological disorder…

We describe a pulsed multi-frequency electron paramagnetic resonance spectrometer operating at several frequencies in the range of 110-336 GHz. The microwave source at all frequencies consists of a multiplier chain starting from a solid…

Quantum Physics · Physics 2008-12-01 Gavin W. Morley , Louis-Claude Brunel , Johan van Tol

Presented are magnetization measurements on a crystal of Fe8 single-molecule magnets using a Hall probe magnetometer. Irradiation with microwaves at frequencies of 92 and 110-120 GHz leads to the observation of electron paramagnetic…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 K. Petukhov , W. Wernsdorfer , A. -L. Barra

We describe a simple experimental method to detect electron paramagnetic resonance (EPR) in polycrystalline 2,2-diphenyl-1-picrylhydrazyl (DPPH) sample, the standard g-marker for EPR spectroscopy, without using a cavity resonator or a…

Materials Science · Physics 2021-04-23 Lee Yong Heng , Ushnish Chaudhuri , Ramanathan Mahendiran

We demonstrate electron spin polarization detection and electron paramagnetic resonance (EPR) spectroscopy using a direct current superconducting quantum interference device (dc-SQUID) magnetometer. Our target electron spin ensemble is…

Mesoscale and Nanoscale Physics · Physics 2024-06-24 Hiraku Toida , Yuichiro Matsuzaki , Kosuke Kakuyanagi , Xiaobo Zhu , William J. Munro , Kae Nemoto , Hiroshi Yamaguchi , Shiro Saito

The investigation of paramagnetic species (such as point defects, dopants, and impurities) in solid-state electronic devices is significant because of their effect on device performance. Conventionally, these species are detected and imaged…

Materials Science · Physics 2015-05-20 Itai Katz , Matthias Fehr , Alexander Schnegg , Klaus Lips , Aharon Blank

Detection of electron paramagnetic resonance (EPR) using a microwave cavity resonating at a fixed frequency (between 9 and 10 GHz) remains the most popular method until now. Here, we report a cavity-less technique which makes use of only an…

Applied Physics · Physics 2020-02-06 Ushnish Chaudhuri , R. Mahendiran

Electron spin resonance (ESR) pulsed dipolar spectroscopy (PDS) is used in protein 3D structure determination. However, the accuracy of the signal analysis depends heavily on the background correction process. In this work, we derive the…

Quantitative Methods · Quantitative Biology 2021-07-01 Aritro Sinha Roy

High-frequency electron paramagnetic resonance (EPR) studies of the antiferromagnetic Mn-$[3\times 3]$ molecular grid clearly reveal a breaking of the $\Delta S = 0$ selection rule, providing direct evidence for the mixing of spin…

Other Condensed Matter · Physics 2009-11-13 S. Datta , O. Waldmann , A. D. Kent , V. A. Milway , L. K. Thompson , S. Hill

Integrating femtosecond (fs) lasers to electron microscopies has enabled direct imaging of transient structures and morphologies of materials in real time and space, namely, ultrafast electron microscopy (UEM). Here we report the…

Rare-earth spin ensembles are a promising platform for microwave quantum memory applications due to their hyperfine transitions, which can exhibit exceptionally long coherence times when using an operation point with zero first-order Zeeman…

Echo-enabled harmonic generation free-electron lasers (EEHG FELs) are promising candidates to produce fully coherent soft x-ray pulses by virtue of efficient high harmonic frequency up-conversion from UV lasers. The ultimate spectral limit…

Angle-resolved photoemission spectroscopy (ARPES) is one of the most direct methods of studying the electronic structure of solids. By measuring the kinetic energy and angular distribution of the electrons photoemitted from a sample…

Strongly Correlated Electrons · Physics 2009-11-10 Andrea Damascelli

Zero-field splitting (ZFS) parameters are fundamentally tied to the geometries of metal ion complexes. Despite their critical importance for understanding the magnetism and spectroscopy of metal complexes, they are not routinely available…

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