Related papers: Effects of strongly selective additives on volume …
This paper examines the response of electrolyte-saturated polymer gels, embedded with charged spherical inclusions, to a weak gradient of electrolyte concentration. These composites present a model system to study microscale electrokinetic…
We study the formation of a colloidal gel by means of Molecular Dynamics simulations of a model for colloidal suspensions. A slowing down with gel-like features is observed at low temperatures and low volume fractions, due to the formation…
We study phase separation and transient gelation in a mixture consisting of polydisperse colloids and non-adsorbing polymers, where the ratio of the average size of the polymer to that of the colloid is approximately 0.063. Unlike what has…
A theory of drop-wise addition polymerization is developed. Because of the linear growth of the reaction volume V, the system gives rise to a new type of distribution function for cyclic species that can be expressed by the sum of two…
Restricting the number of attractive physical "bonds" that can form between particles in a fluid suppresses the usual demixing phase transition to very low particle concentrations, allowing for the formation of open, percolated, and…
Several methods for measuring the compressive strength of strong particulate gels are available, including the centrifuge method, whereby the strength as a function of volume-fraction is obtained parametrically from the dependence of…
Porous gels -- gels with solvent-filled pores that are much larger than their mesh size -- are widely used in engineering and biomedical applications due to their tunable mechanics, high water content, and selective permeability. Among…
Many water soluble polymers are chemically modified versions of insoluble base materials such as cellulose. A Flory-Huggins model is solved to determine the effects of heterogeneity in modification on the solubility of such polymers. It is…
Motivated by the fine compositional control observed in membraneless droplet organelles in cells, we investigate how a sharp binding-unbinding transition can occur between multivalent client molecules and receptors embedded in a porous…
Polymers adopt extended coil and compact globule states according to the balance between entropy and interaction energies. The transition of a polymer between an extended coil state and compact globule state can be induced by changing…
We study the tunneling into the edge of the Luttinger liquid with periodically modulated concentration of electrons. It is shown that the modulation,by causing a gap in the spectrum of plasmons, leads to an additional anomaly in the density…
The present study investigates the effect of temperature-induced change of phase from face centred cubic solid to liquid on the size dependence of self diffusivity of solutes through detailed molecular dynamics simulations on binary…
The equilibrium structure and dynamics of a single polymer chain in a thermal solvent is by now well-understood in terms of scaling laws. Here we consider a polymer in a bacterial bath, i.e. in a solvent consisting of active particles which…
Polymer gels are comprised of a three-dimensional, cross-linked network that can typically withstand the mechanical deformation associated with both swelling and de-swelling. Thus, gels can be designed with smart behaviors that require both…
The presence of a tiny amount of polymers (a few parts per million) in a fluid dramatically reduces turbulent drag. For this reason, polymer additives have been proposed to be used in flood remediation: in an open channel at a fixed flow…
We report the effect of interstitial fluid on the extent of segregation by imaging the pile that results after bidisperse color-coded particles are poured into a silo. Segregation is sharply reduced and preferential clumping of small…
Effect of small additive molecules on the structural relaxation of polymer melts is investigated via molecular dynamics simulations. At a constant external pressure and a fixed number concentration of added molecules, the variation of…
Shell effects in the coordinate space can be seen with degenerate Fermi vapors in non-uniform trapping potentials. In particular, below the Fermi temperature, the density profile of a Fermi gas in a confining harmonic potential is…
We study a three-component fermionic fluid in an optical lattice in a regime of intermediate-to- strong interactions allowing for Raman processes connecting the different components, similar to those used to create artificial gauge fields…
Solutions of semiflexible polymers confined by repulsive planar walls are studied by density functional theory and Molecular Dynamics simulations, to clarify the competition between the chain alignment favored by the wall and the depletion…