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Hydrogenation of graphene on the \alpha-quartz (0001) SiO_2 substrate is studied, considering different surface terminations in order to take into account the amorphic nature of the material. Our ab initio calculations show that the…

Mesoscale and Nanoscale Physics · Physics 2012-01-16 P. Havu , M. Ijäs , A. Harju

The speed of silicon-based transistors has reached an impasse in the recent decade, primarily due to scaling techniques and the short-channel effect. Conversely, graphene (a revolutionary new material possessing an atomic thickness) has…

Materials Science · Physics 2013-09-03 K. C. Yung , W. M. Wu , M. P. Pierpoint , F. V. Kusmartsev

Most recently, a brand new phosphorus allotrope called green phosphorus has been predicted, which has a direct band gap up to 2.4 eV, and its single-layer form termed green phosphorene shows high stability. Here the mechanical properties…

Materials Science · Physics 2018-06-18 Guang Yang , Tianxing Ma , Xihong Peng

In this letter we study the electronic structures and optical properties of partially and fully fluorinated graphene by a combination of abinitio G0W0 calculations and large-scale multi-orbital tight-binding simulations. We find that for…

Mesoscale and Nanoscale Physics · Physics 2015-02-25 Shengjun Yuan , Malte Rosner , Alexander Schulz , Tim O. Wehling , Mikhail I. Katsnelson

Hydrogenation has proven to be an effective tool to open the bandgap of graphene. In the present density functional study we demonstrate that single-side-hydrogenated graphene is a semiconductor with an indirect bandgap of 1.89 eV, in…

Materials Science · Physics 2011-03-01 Bhalchandra S. Pujari , Sergey Gusarov , Michael Brett , Andriy Kovalenko

The asymmetric properties of Janus two-dimensional materials commonly depend on chemical effects, such as different atoms, elements, material types, etc. Herein, based on carbon gene recombination strategy, we identify an intrinsic…

Materials Science · Physics 2023-09-12 Linfeng Yu , Jianhua Xu , Chen Shen , Hongbin Zhang , Xiong Zheng , Huiming Wang , Zhenzhen Qin , Guangzhao Qin

We have performed first-principles studies on adsorption patterns of hydrogen adatoms on uniaxially strained graphene. Our simulation reveals that the adsorption energy of adatoms are sensitive to the strain. Hydrogen adatoms on zigzag…

Mesoscale and Nanoscale Physics · Physics 2011-12-13 Daniel Cole , Li Yang

The widely used crystal structures for both heptazine-based and triazine-based two-dimensional (2D) graphitic carbon nitride (g-C$_3$N$_4$) are the flat P-6m2 configurations. However, the experimentally synthesized 2D g-C$_3$N$_4$ possess…

Materials Science · Physics 2021-02-03 Luneng zhao , Xizhi Shi , Jin Li , Tao Ouyang , Chunxiao Zhang , Chao Tang , Chaoyu He , Jianxin Zhong

Phosphorene, a 2D allotrope of phosphorus, is technologically very appealing because of its semiconducting properties and narrow band gap. Further reduction of the phosphorene dimensionality may spawn exotic properties of its electronic…

The growth, atomic structure, and electronic property of trilayer graphene (TLG) on Ru(0001) were studied by low temperature scanning tunneling microscopy and spectroscopy in combined with tight-binding approximation (TBA) calculations. TLG…

Materials Science · Physics 2026-04-14 Yande Que , Wende Xiao , Hui Chen , Dongfei Wang , Shixuan Du , Hong-Jun Gao

Several 2D carbon-based materials have been computationally designed in the last years due to the success achieved by graphene. Here, we propose a new 2D all-sp$^2$ carbon allotrope, named Irida-Graphene (IG), using a bottom-up approach. IG…

Two-dimensional (2D) carbon allotropes have received considerable attention due to their unique properties and potential applications in several fields, including electronics, catalysis, energy storage, and sensing. Following the…

Using evolutionary algorithm for crystal structure prediction, we present a new stable two-dimensional (2D) carbon allotrope composed of polymerized as-indacenes (PAI) in a zigzag pattern, namely PAI-graphene whose energy is lower than most…

Materials Science · Physics 2020-09-11 Xin Chen , Adrien Bouhon , Linyang Li , François M. Peeters , Biplab Sanyal

For centuries, cutting and folding the papers with special patterns have been used to build beautiful, flexible and complex three-dimensional structures. Inspired by the old idea of kirigami (paper cutting), and the outstanding properties…

Mesoscale and Nanoscale Physics · Physics 2017-11-03 Bohayra Mortazavi , Aurélien Lherbier , Zheyong Fan , Ari Harju , Timon Rabczuk , Jean-Christophe Charlier

Graphane is a two-dimensional system consisting of a single layer of fully saturated (sp$^3$ hybridization) carbon atoms. In an ideal graphane structure C-H bonds exhibit an alternating pattern (up and down with relation to the plane…

Materials Science · Physics 2009-10-23 Marcelo Z. S. Flores , Pedro A. S. Autreto , Sergio B. Legoas , Douglas S. Galvao

Graphene possesses a unique combination of physical properties including high carrier mobility and high current density it can sustain. In contrast to bulk metals, graphene does not completely screen the external electrostatic field. In…

Applied Physics · Physics 2024-10-03 Alexander Khitun

Straintronic devices made of carbon-based materials have been pushed up due to the graphene high mechanical flexibility and the possibility of interesting changes in transport properties. Properly designed strained systems have been…

Mesoscale and Nanoscale Physics · Physics 2018-05-02 V. Torres , D. Faria , A. Latgé

In this work, we propose a new auxetic (negative Poisson's ratio values) structure, based on a $\gamma$-graphyne structure, here named $A\gamma G$ $structure$. Graphynes are 2D carbon allotropes with phenylic rings connected by acetylenic…

The shift from fossil fuels to renewable energy sources is essential for reducing global carbon emissions and addressing climate change. Developing advanced materials for efficient hydrogen storage enables sustainable energy solutions in…

Hexagonal Boron Nitride substrates have been shown to dramatically improve the electric properties of graphene. Recently, it has been observed that when the two honeycomb crystals are close to perfect alignment, strong lattice distortions…

Mesoscale and Nanoscale Physics · Physics 2014-10-08 Pablo San-Jose , Ángel Gutiérrez , Mauricio Sturla , Francisco Guinea