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The discovery of superconductivity in alkali-ammonia co-intercalated FeSe has generated intensive interest because of their highest Tc (~ 45 K) among iron-chalcogenide superconductors with bulk form. Here, we report the phase diagrams of…

Superconductivity · Physics 2014-12-10 Hechang Lei , Jiangang Guo , Fumitaka Hayashi , Hideo Hosono

The recent discovery of high temperature superconductivity in a layered iron arsenide has led to an intensive search to optimize the superconducting properties of iron-based superconductors by changing the chemical composition of the spacer…

Recently, a very rich phase diagram has been obtained for an iron-based superconductor Ca4Al2O6Fe2(As1-xPx)2. It has been revealed that nodeless (x=0) and nodal (x = 1) superconductivity are separated by an antiferromagnetic phase. Here we…

We investigated the magnetization and crystal structure of FeSe polycrystalline samples with various grain sizes. For the samples with large grains, a large magnetic critical current density Jc was observed. For the samples with small…

Superconductivity · Physics 2016-04-05 Hiroki Izawa , Yuji Tanaka , Yoshikazu Mizuguchi , Osuke Miura

Unconventional superconductivity in iron pnictides and chalcogenides has been suggested to be controlled by the interplay of low-energy antiferromagnetic spin fluctuations and the particular topology of the Fermi surface in these materials.…

Superconductivity · Physics 2017-01-09 Daniel Guterding , Harald O. Jeschke , I. I. Mazin , J. K. Glasbrenner , E. Bascones , Roser Valenti

We have investigated the influence of Fe-excess on the electrical transport and magnetism of Fe1+yTe0.5Se0.5 (y=0.04 and 0.09) single crystals. Both compositions exhibit resistively determined superconducting transitions (Tc) with an onset…

The second class of high-temperature superconductors (HTSCs), iron-based pnictides and chalcogenides, necessarily contain Fe$_2$$X_2$ ("$X$" refers to a pnictogen or a chalcogen element) layers, just like the first class of HTSCs which…

Superconductivity · Physics 2016-05-16 Hao Jiang , Yun-Lei Sun , Zhu-An Xu , Guang-Han Cao

Structure and composition of iron chalcogenides have a delicate relationship with magnetism and superconductivity. In this report we investigate the iron sulfide layered tetragonal phase (t-FeS), and compare with three-dimensional hexagonal…

Since the discovery of superconductivity at 26 K in oxy-pnictide LaFeAsO1-xFx, enormous interests have been stimulated in the field of condensed matter physics and material sciences. Among the many kind of structures in the iron pnictide…

Superconductivity · Physics 2012-07-06 Fei Han , Bing Shen , Zhen-Yu Wang , Hai-Hu Wen

The influence of hydrostatic pressure and ab-plane strain on the magnetic structure of FeTe is investigated from first principles. The results of calculations reveal a phase transition from antiferromagnetic double-stripe ordering at…

Superconductivity · Physics 2014-02-11 A. Ciechan , M. J. Winiarski , M. Samsel-Czekała

Structural investigations by means of transmission electron microscopy (TEM) on KFexSe2 with 1.5 \leq x \leq 1.8 have revealed a rich variety of microstructure phenomena, the KFe1.5Se2 crystal often shows a superstructure modulation along…

Superconductivity · Physics 2013-05-29 Z. Wang , Y. J. Song , H. L. Shi , Z. W. Wang , Z. Chen , H. F. Tian , G. F. Chen , J. G. Guo , H. X. Yang , J. Q. Li

We report the results of a systematic investigation of the phase diagram of the iron-based superconductor, Ba1-xKxFe2As2, from x = 0 to x = 1.0 using high resolution neutron and x-ray diffraction and magnetization measurements. The…

Superconductivity develops in metals upon the formation of a coherent macroscopic quantum state of electron pairs. Iron pnictides and chalcogenides are materials that have high superconducting transition temperatures. In this Review, we…

Superconductivity · Physics 2016-04-14 Qimiao Si , Rong Yu , Elihu Abrahams

A complete phase diagram and its corresponding physical properties are essential prerequisites to understand the underlying mechanism of iron based superconductivity. For the structurally simplest 11 (FeSeTe) system, earlier attempts using…

This article reviews recent experimental investigations on two binary Fe-chalcogenides: FeSe and Fe$_{1+y}$Te. The main focus is on synthesis, single crystal growth, chemical composition, as well as on the effect of excess iron on…

Superconductivity · Physics 2016-06-06 Sahana Rößler , Cevriye Koz , Steffen Wirth , Ulrich Schwarz

Much remains unknown of the microscopic origin of superconductivity when it materializes in atomically disordered systems as in amorphous alloys (1) or in crystals riddled with defects(2). A manifestation of this conundrum is envisaged in…

Superconductivity · Physics 2013-02-12 Despina Louca , Keeseong Park , Bing Li , Joerg Neuefeind , Jiaqiang Yan

The phenomenon of phase separation into antiferromagnetic (AFM) and superconducting (SC) or normal-state regions has great implication for the origin of high-temperature (high-Tc) superconductivity. However, the occurrence of an intrinsic…

We study the relationship between precipitate morphology and superconductivity in KxFe1.6+ySe2 single crystals grown by self-flux method. Scanning electron microscopy (SEM) measurements revealed that superconducting phase forms a network in…

Superconductivity · Physics 2012-10-09 Y. Liu , Q. Xing , K. W. Dennis , R. W. McCallum , T. A. Lograsso

In amorphous superconductors, superconducting and vortex pinning properties are strongly linked to the absence of long range order. Consequently, superconductivity and vortex phases can be studied to probe the underlying microstructure and…

Superconductivity · Physics 2015-05-13 J. Lefebvre , M. Hilke , Z. Altounian

In a superconductor electrons form pairs and electric transport becomes dissipation-less at low temperatures. Recently discovered iron based superconductors have the highest superconducting transition temperature next to copper oxides. In…

Materials Science · Physics 2014-12-02 Xianhui Chen , Pengcheng Dai , Donglai Feng , Tao Xiang , Fu-Chun Zhang