Related papers: Possible High-Tc Superconductivity in LiMgN: A MgB…
The discovery of superconductor in magnesium diboride MgB2 with high Tc (39 K) has raised some challenging issues; whether this new superconductor resembles a high temperature cuprate superconductor(HTS) or a low temperature metallic…
The recent discovery of superconductivity at ~39 K in MgB2, by Nagamatsu et al. establishes this simple binary compound as having the highest bulk superconducting transition temperature, Tc, of any non-copper-oxide material. Much of the…
Over the past 14 years MgB2 has gone from a startling discovery to a promising, applied superconductor. In this article we present a brief overview of the synthesis and the basic superconducting properties of this remarkable compound. In…
Ternary silicides MI(MII0.5, Si0.5)2 (MI=Sr and Ba, MII=Al and Ga) were prepared by Ar arc melting. Powder X-ray diffraction indicates that they have the AlB2-type structure, in which Si and MII atoms are arranged in honeycomb layers and MI…
The boride compounds MB_x related to the magnesium-boron stacking layered material MgB2 are discussed in terms of the B-B layers in the borides analogous to the Cu-O ones in the cuprates. We propose a possibility of superconducting…
Boron in MgB_2 forms layers of honeycomb lattices with magnesium as a space filler. Band structure calculations indicate that Mg is substantially ionized, and the bands at the Fermi level derive mainly from B orbitals. Strong bonding with…
A polycrystalline sample of the MgB_2 superconductor was investigated by measurements of the electrical resistivity, the thermopower and the thermal conductivity in the temperature range between 1.8K and 300K in zero magnetic field. The…
High-density bulk materials of a newly discovered 40K intermetallic MgB2 superconductor were prepared by high pressure sintering. Superconducting transition with the onset temperature of 39K was confirmed by both magnetic and resistive…
Superconductivity was found for a rhenium boride Re3B at Tc=4.7 K and for ReB2 with Tc in the range from 4.5 to 6.3 K depending on the boron concentrations. Both compounds have the structure different from that of the simple layered…
The diboride materials MB2 (M = Mg, Be, Pb, etc.) are discussed on the basis of the 3D Josephson junction array (JJA) model due to Kawabata-Shenoy-Bishop, in terms of the B-B layers in the diborides analogous to the Cu-O ones in the…
Since the discovery of superconductivity in MgB2 (Tc ~ 39 K), the search for superconductivity in related materials with similar structures or ingredients has never stopped. Although about 100 binary borides have been explored, only few of…
Superconducting transition temperatures ($T_c$'s) of MgB$_2$, Mg$_{1-x}$Ca$_x$B$_2$, Mg$_{1-x}$Na$_x$B$_2$, and Mg$_{1-x}$Al$_x$B$_2$ are studied within the McMillan approximation using electronic and structural information obtained from…
Lithium borocarbide, LiBC, a member of the Z = 4.67 family of materials, is not a superconductor. Using ternary combinations of elements that give Z = 4.67 and the material specific characterization dataset (MSCD) scheme, we discover other…
We report synthesis, structure/micro-structure, resistivity under magnetic field [R(T)H], Raman spectra, thermoelectric power S(T), thermal conductivity K(T), and magnetization of ambient pressure argon annealed polycrystalline bulk samples…
Superconductivity in transition metal nitrides (TMNs) has been investigated for a long time, such as zirconium nitride (ZrN) with a superconducting transition temperature Tc of 10 K. Recently, a phase diagram has been revealed in ZrNx with…
The layered lithium borocarbide LiBC, isovalent with and structurally similar to the superconductor MgB2, is an insulator due to the modulation within the hexagonal layers (BC vs. B2). We show that hole-doping of LiBC results in Fermi…
Effects of magnetic impurity on the superconductivity has been investigated in Mg1-xMnB2. With increase of Mn concentration x, the lattice constant c (perpendicular to the boron sheet) decreases at a rate of -1.4 % (= dlnc/dx), while a…
We report the fabrication of MgB2 with bulk superconducting properties by conventional solid state methods at temperatures as low as 550 C. Mg deficiencies of the type Mg1-xB2 were tested. Tc was found to decrease by about 1K at large x,…
A new two-dimensional material { Mg2B4C2, belonging to the family of the conventional superconductor MgB2, is theoretically predicted to exhibit superconductivity with critical temperature Tc estimated in the 47-48 K range (predicted using…
Following the recent theoretical prediction of superconductivity in hole doped LiBC by Rosner et al [1], we have attempted to synthesise Li deficient LixBC (x = 1, 0.8, 0.6 and 0.4) and look for superconductivity in this system. Our…